土壤中单甲脒挥发的研究

在实验室模拟条件下初步研究了农药单甲脒从本身纯物质及土壤表面的挥发行为．实验表明，挥发通量的对数与温度的倒数呈线性关系；单甲脒从有机质含量低的土壤中挥发较其从有机质含量较高的土壤中挥发要快；在一定范围内，土壤中单甲脒的挥发通量随着土壤中农药的浓度增加、温度的上升和风速的增加而增加；土壤水分的增加最初促进单甲脒挥发，继续增加则可能使挥发减慢．     

北极冰化学元素含量及其分布

报道了北极冰主要化学元素的浓度分布及其变化，在测定的３１种成分中，高于仪器检测限的１０种元素Ｂ，Ｍｇ，Ｖ，Ａｓ，Ｒｂ，ＳＤｒ，Ｃａ，Ｋ，Ｓ，Ｎａ的硬度被用来统计分析。结果表明，同一地区，元素浓度相对稳定，不同地区浓度有较大差异。元素浓度与纬度关系的相关分析显示，随纬度增加，各元素显降低。     

NDA-100大孔树脂对水溶液中水杨酸的吸附行为研究

通过静态吸附试验，研究了NDA－100大孔树脂对水溶液中水杨酸的吸附动力学及热力学特性，结果表明吸附符合一级动力吸附方程，颗粒内扩散过程是影响吸附速率的主要控制步骤，吸附符合Langmuir和Freundlich等温吸附方程，吸附为放热的物理吸附过程。     

Biogenic VOCs emission inventory development of temperate grassland vegetation in Xilin River basin, Inner Mongolia, China

Given the key role of biogenic volatile organic compounds(VOCs) to tropospheric chemistry and regional air quality, it is important to generate accurateVOCs emission inventories. However, only a less fraction of plant species, in temperate grassland of Inner Mongolia, has been characterized by quantitative measurements. A taxonomic methodology, which assigns VOCs measurements to unmeasured species, is an applicable and inexpensive alternation for extensive VOCs emission survey, although data are needed for additional plant families and genera to further validate the taxonomic approach in grassland vegetation. In this experiment, VOCs emission rates of 178 plant species were measured with a portable photoionization detector( PID). The results showed the most of genera and some families have consistent feature of their VOCs emission, especially for isoprene, and provide the basic premise of taxonomic methodology to develop VOCs emission inventories for temperate grassland. Then, the taxonomic methodology was introduced into assigning emission rate to other 96 species, which no measured emission rates available here. A systematical emission inventory of temperate grassland vegetation in Inner Mongolia was provided and further evidence that taxonomy relationship can serve as a useful guide for generalizing the emissions behavior of many, but not all, plant families and genera to grassland vegetation.     

汽车污染与控制探讨

通过阐述汽车污染的原理，提出了汽车的防污途径有控制汽车尾气污染的方法。     

温度对氨法脱硫率影响的实验研究

对使用氨（NH3）脱除烟气中气态污染物的技术进行了分析和总结，认为氨洗涤法洗涤净化烟气是一种很有前景的方法，并就温度对SO2脱除率的影响进行了实验研究。实验研究结果显示，当温度超过54℃时，NH3对SO2仍有很高的脱除率。并根据实验结果建议，在实际氨法脱硫工程中，脱硫过程温度宜控制在60℃以下或在80℃以上。     

An approach to the fluctuation mechanism of ecotone

In this paper,the relationship among land productivity,population pressure and the fluctuation mechanism of ecotone is analyzed,taking coumties and banners of southeast Inner Mongolia plateau as an example,which is the most fragile part in the farming and husbandry interleaving belt of north China due to its severe desertification degree and low level of economic development.The Cv for the total output value of agriculture decreases from southeast to northwest,with the same rule as which the overloading population cumulated distributes,and both indicators have close relation with the high linear coefficient of 0.83.These reveal the fluctuation mechanism for ecotone:fluctuation of the level of economic development is a scientific and practical measure both to weakness degree and to instability of ecotone,because it is a synthesized response to the variation of climate as well as irrational land uses,which reinforce and magnify the fluctuation.In detail,the heavier the population overloading,the severer the grassland reclamation,the stronger the dependence of regional productivity on rainfall,the lower the level of economic development,the rougher the fluctuation of ecotone,but the weaker the PRED system.     

元素地球化学不活动组分判别——以库布苏金矿中矿带研究为例

本文从探讨元素不活动组分的原理出发 ,利用Gresens(196 7)质量平衡方程及Brimhall等 (1987)提出的元素不活动组分ΔX -fv 图解 ,对复杂热液成矿体系的元素不活动组分进行了深入探讨。指出了复杂体系内部各个子体系间元素不活动组分及体积变化上的差异。并结合实际 ,对库布苏金矿中矿带元素不活动组分进行了研究。同时对一些矿床地质现象的形成及成矿物质来源从元素地球化学角度进行了解释和判断。     

区域(城市)水体中主要有机毒物的筛选

本研究发展了区域(或城市)水体中主要有毒化学品的筛选方法。 在城市下游采集大体积水样,用CH_2Cl_2洗脱,再用有机溶剂萃取,用硅胶柱把有机物分成许多馏分,馏分最终变为水溶液。每个馏分中有机物浓度比原水大1000倍。用这种馏分水溶液进行溞的急性毒性试验和Ames试验。只对毒性大的馏分进行色谱/质谱/数据系统的鉴定和定量分析,然后根据各个化合物的急性毒性、降解难易和“三致”物质的资料及原水样中有机物的浓度资料,就可筛选出一个区域(城市)水体中的主要有毒化学品。     

离子对烷基化法在2,4-D和2,4,5-T残留分析中的应用

有机阴离子可以和长碳链的季胺盐阳离子结合生成可溶于高介电常数有机溶剂的离子对.在此溶剂中,它可以和某些卤代烃发生复分解反应,生成季铵盐阳离子的卤化物及有机阴离子的相应烷基化物,故称离子对烷基化反应.此反应条件温和,转化率高,被广泛地应用于酸性及其它含活泼氢的有机化合物的烷基衍生物合成中.在这类有机物的分析中也得到应用.但尚未见应用于农药及其降解物残留分析中的报道. 2,4-D,2,4,5-T是典型的酸性有机农药,广泛用作农田除草剂.在二者的残留分析中,通常用CH_2N_2、BF_3CH_3OH、(CH_3)_2SO_4将它们烷基化,然后用气相色谱加以分析.近几年也有人用多卤素取代醇的BCl_3络合物或五氟苄基溴化物同Na_2CO_3作为