For an effective decomposition and removal of organic halogenated compounds, a packed-bed non-thermal plasma reactor with
in situ absorption of the resulting halogenated products by alkaline sorbent incorporated was proposed. In the plasma reactor,
α-Al
2O
3 particles of 1 and 3 mm (mean particle diameter) were packed as solid dielectric medium to enhance the plasma power density
in the reactor. Further, alkaline sorbent of Ca(OH)
2 was doped onto the surface of α-Al
2O
3 particles, in order to remove halogenated products by in situ absorption with Ca(OH)
2. A high-voltage and high-frequency pulsed power of −15 to 15 kV and 1 kHz was applied to the wire electrode of the plasma
reactor by means of a DC power source. In the present study, as the sample of an organic halogenated compound that is most
popularly used, we selected dichloromethane (CH
2Cl
2), and 500 ppm of the initial concentration of CH
2Cl
2 was fed into the reactor accompanied by air at a fixed flow rate of 500 × 10
−6 m
3 min
−1 at room temperature. As a result, it was recognized that the amount of CH
2Cl
2 decomposed by non-thermal plasma in an α-Al
2O
3 particle bed increased with an increase in plasma input power. The ratio of decomposition of CH
2Cl
2 was almost 100% at 13 kV of electric power and 1 kHz frequency, and CO
2, CH
3Cl, COCl
2, HCl, and Cl
2 were observed as the major reaction products. On the other hand, when CH
2Cl
2 was introduced into the plasma reactor where α-Al
2O
3 particles doped with Ca(OH)
2 were packed, the ratio of decomposition of CH
2Cl
2 became higher, compared to the case that α-Al
2O
3 particles were not doped with Ca(OH)
2. Moreover, there were no halogenated by-product gases detected in the outlet gas from the reactor. As the solid reaction
products, CaClOH and Ca(ClO)
2·4H
2O were detected on Ca(OH)
2 by X-ray diffraction. From these findings, it was recognized that CH
2Cl
2 was decomposed more effectively without producing unwanted harmful halogenated by-products in the proposed non-thermal plasma
reactor where α-Al
2O
3 particles doped with Ca(OH)
2 sorbent were packed.
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