炼焦过程排放挥发性有机物的排放特征和组成分布研究

为控制炼焦排放以及为预防城市大气污染提供可靠的污染源数据支持,利用不锈钢采样罐和全自动预浓缩/GC/MS系统,研究了58-Ⅱ型和JN43-80型焦炉在装煤时刻和炼焦过程(包括装煤时刻)中挥发有机物(VOCs)的排放特征及其组成分布,分析了焦化行业排放VOCs的反应活性。研究发现,在装煤时刻和炼焦过程中,58-Ⅱ型焦炉产生的总挥发性有机物(TVOCs)浓度分别为7022μg/m~3和6266μg/m~3;JN43-80型焦炉产生的TVOCs浓度分别为4185μg/m~3和3298μg/m~3。装煤时刻产生的TVOCs浓度明显高于炼焦过程产生的。炼焦过程无组织排放的VOCs包含烯烃、烷烃、芳香烃、卤代烃以及少量的醛和酮,其中乙烯、乙烷、丙烯、苯、甲苯等为主要成分。这些产生的VOCs反应活性各不相同,活性最大的是烯烃类物质,其活性占TVOCs反应活性比重为(86.2±2.1)%;其次是芳香烃类物质,其活性比重为(9.2±3.1)%;反应活性最大的5个物种分别是丙烯、乙烯、1,3-丁二烯、1-丁烯以及苯乙烯。     

Occurrence and distribution of organochlorine pesticides - lindane, p,p'-DDT, and heptachlor epoxide - in surface water of China

Persistent organochlorine pesticides pollutants (OCPs) have been reported to occur at relatively high concentrations in some Chinese waters. In order to map the distribution of organochlorine pesticides in the surface water throughout China, samples were collected from over 600 sites in seven major river basins and three main internal rivers drainage areas during 2003 and 2004. The surface water samples were analyzed for the representative organochlorine pesticides contaminants including lindane (gamma-HCH), p,p'-DDT and heptachlor epoxide. In general, the most frequently detected compound was lindane, being detected in 83.9% of samples (mean=31.3 ng/l; range <0.17-860 ng/l), and the highest concentration was present in the Yellow River basin. p,p'-DDT was detected in 63.1% of the samples collected (mean=14.6 ng/l; range <0.14-368 ng/l) with the highest concentration present in the Huaihe River basin. Heptachlor epoxide was detected in only 9.3% of water samples (range <0.11-10 ng/l). Measured concentrations for the three compounds were low and rarely exceed the environment quality standard for surface water of China. Lindane was more frequently detected at much higher concentrations in the rivers of northern China compared with those of southern China. The sites with higher concentration of lindane and p,p'-DDT mainly occurred in the Yellow River and Huaihe River basins, so the results of this investigation indicate that the organochlorine pesticide contamination of Yellow River and Huaihe River basins should be of particular concern relative to the other basins. When compared with other regions of the world, it appears that the Chinese surface water is moderately polluted by lindane and p,p'-DDT.     

A Methodology Framework for Regional Land-use Change Studies based on Landsat TM images: A Case Study in Northeast China

Abstract

Land-use change is an important aspect of global environment change. It is, in a sense, the direct result of human activities influencing our physical environment. This paper analyzed the land- use change in Northeast China during 1985–2000 based on Landsat TM images. It divides Northeast China into five land-use zones based on the dynamic degree model of land-use: woodland/grassland-arable land conversion zone, dry land-paddy field conversion zone; urban expansion zone, interlocked zone of farming and pasturing and reclamation and abandon zone. The findings include the obvious increase of cropland area, paddy field and dry land increased by 75 and 276 thousand hm² respectively; urban areas expanded rapidly, areas of town and rural residence increased by 76.8 thousand hm²; areas of forests and grassland decreased sharply with the amounts of 1399 and 1521 thousand hm² respectively; areas of water body and unused land increased by 148 and 514 thousand hm² respectively. This paper also discusses the driving forces in each land-use dynamic zone and finds that some key biophysical factors affect conspicuously the conversion of different land-use types. The relation between land-use conversion and DEM, accumulated temperature (≤10°C) and precipitation was analyzed and represented. The land-use changes In Northeast China resulted from the changing macro social and economic factors and local physical elements. Rapid population growth and management changes can explain the shaping of woodland/grassland-cropland conversion zone. The conversion from dry land to paddy field in the dry land-paddy field conversion zone, apart from the change of physical elements promoting the expansion of paddy field, results from two reasons: one is that the implementation of market economy in China has given farmers the right to decide what and how they plant their crops, the other factor is originated partially from the change of the dietary habit along with the social and economic development. The conversion from paddy field to dry land is caused primarily by the shortfall of irrigation water, which in turn is caused by poor water allocation managed by local governments. The shaping of the reclamation and abandon zone is partially due to the lack of environment protection consciousness among pioneer settlers. The reason for the conversion from grassland to cropland is the relatively higher profits of farming than that of pasturing in the interlocked zone of farming and pasturing. In Northeast China, the rapid expansion of built-up areas results from two factors: the existence of a small number of towns and the huge potential for expansion of the existing towns and cities. The urban land expanded mainly in areas with a gentle topographic relief and low population density.     

Spatial-temporal analysis of wetland landscape pattern under the influence of artificial dykes in the Yellow River delta

The influence of anthropogenic activities,especially artificial dykes,on the coastal wetland landscape is now considered as a serious problem to the coastal ecosystem.It is important and necessary to analyze changes of coastal landscape pattern under the influence of artificial dykes for the protection and management of coastal wetland.Our study aimed to reveal the quantitative characteristics of the coastal wetland landscape and its spatial-temporal dynamics under the influence of artificial dykes in the Yellow River delta(YRD).It was analyzed by the methods of the statistical analysis of landscape structure,five selected landscape indices and the changes of spatial centroids of three typical wetland types,including reed marshes,tidal fiats and aquaculture-salt fields.The results showed that:(1)Reduction of wetland area,especially the degradation of natural wetlands,had been the principal problem since the dykes were constructed in the YRD.The dykes created conditions for the development of artificial wetlands.However,the new born artificial wetlands were still less than the vanished natural wetlands.(2)Compared with the open area,the building of artificial dykes significantly speeded up the changes of landscape patterns and the aggravation of the landscape fragmentation in the closed area.(3)The changes of area-weighted centroids of three typical wetland landscapes were greatly affected by dykes,and the movement of the centroid of the aquaculture-salt field was very sensitive to the dykes constructed in the corresponding period.     

国内石油企业实施低碳经济发展的模式探讨

"两型"社会的建设为低碳经济的发展、实施提出了明确的方向,也为企业的可持续发展指明了道路。文章在分析借鉴国际大石油公司低碳发展实践经验的基础上,对我国低碳经济发展现状、石油企业面对低碳发展环境的机遇和挑战进行了系统分析,并对我国石油企业低碳发展的总体思路、模式设计提出了建议。     

Biofuel development, food security and the use of marginal land in China

With concerns of energy shortages, China, like the United States, European Union, and other countries, is promoting the development of biofuels. However, China also faces high future demand for food and feed, and so its bioenergy program must try to strike a balance between food and fuel. The goals of this paper are to provide an overview of China's current bioethanol program, identify the potential for using marginal lands for feedstock production, and measure the likely impacts of China's bioethanol development on the nation's future food self-sufficiency. Our results indicate that the potential to use marginal land for bioethanol feedstock production is limited. Applying a modeling approach based on highly disaggregated data by region, our analysis shows that the target of 10 million t of bioethanol by 2020 seems to be a prudent target, causing no major disturbances in China's food security. But the expansion of bioethanol may increase environmental pressures due to the higher levels of fertilizer use. This study shows also that if China were able to cultivate 45% of its required bioethanol feedstock on new marginal land, it would further limit negative effects of the bioethanol program on the domestic and international economy, but at the expense of having to apply another 750 thousand t of fertilizer.     

Solubilization of mixed polycyclic aromatic hydrocarbons through a rhamnolipid biosurfactant

The solubilization of phenanthrene (PHE) and pyrene (PYR) by rhamnolipid biosurfactant was systematically investigated. The solubilities of both polycyclic aromatic hydrocarbons (PAHs) were increased linearly with the biosurfactant concentration at above critical micelle concentration. A competitive effect was observed between PHE and PYR. The solubility of PHE in a mixed system was lower than that in a single PAH system, whereas the solubility of PYR in a mixed system was enhanced. This is because the hydrophobicity of PYR is higher than that of PHE, so PYR is favored in the competitive solubilization. The combined effect of biosurfactant and dissolved organic matter (DOM) on PAH solubilization was also examined. Two kinds of DOM (derived from soil and from compost) were used. There was an obvious enhancement of solubility for PHE and PYR in systems with concurrence of DOM and biosurfacrant compared with systems with only DOM or biosurfactant; however, the enhancement in the mixed system was less than their additive. This could be explained as the formation of a DOM-biosurfactant complex. In addition, the solubility enhancement of PAHs in a compost-DOM system was higher than that in a soil-DOM system. This could be explained as functional group differences of two DOM types.     

Modeling the Impacts of Cetacean-Focused Tourism in Taiwan: Observations from Cetacean Watching Boats: 2002–2005

Cetacean-focused tourism in Taiwan has grown rapidly since 1997. This development, measured in terms of both number of tour boats and visitors, has resulted in many resource management challenges stemming from the absence of regulation and scientific data. To fill this void in empirical evidence, we used 464 sighting records from 2002 to 2005 to model the impact of cetacean-focused tourism. Cox proportional hazard analysis indicated cetacean avoidance responses to cetacean watching boats were strongly associated with pod size, mother–calf pairs, and cetacean-vessel distances. Mother–calf pairs abandoned their avoidance tactic by 55% compared to noncalf groups when tour boats approached. Second, the hazard ratio of abundance was 0.996, suggesting that the odds of encountering avoidance responses by the cetaceans decreased by 42% for every 100-member increase in the cetacean pod size. Last, distances maintained by boats from the cetaceans was positively related to avoidance responses (i.e., less avoidance behavior with closer interaction). Based on our findings, we have the following recommendations: (a) limit vessels from approaching mothers with calves, (b) limit vessels from approaching small groups of cetaceans, (c) reduced avoidance behavior to boat traffic may be a red flag for potential long-term disturbance, and (d) apply the “precautionary principle” based on the best scientific information available in cetacean-based tourism in Taiwan. These recommendations will help contribute to the sustainable development of cetacean-focused tourism in Taiwan.     

Formulation of criteria for pollution control on cement products produced from solid wastes in China

The process of producing cement products from solid waste can increase the level of pollutants in the cement products. Therefore, it is very important to establish a pollution control standard for cement products to protect the environment and human health. This paper presents acceptance limits for the availability of heavy metals in cement products which have been produced from solid wastes and explains how the limits have been calculated. The approach and method used to formulate these criteria were based on EN 12920. The typical exposure scenarios used in this paper involve concrete being used for drinking water supply pipelines and concrete pavements and are based on an analysis of typical applications of cement in China, and the potential for contact with water. The parameters of a tank test which was based on NEN 7375 were set in accordance with the environmental conditions of typical scenarios in China. Mechanisms controlling the release of heavy metals in concrete and a model for that release were obtained using the leaching test. Finally, based on acceptance criteria for drinking water and groundwater quality in China, limit values for the availability of heavy metals in concrete were calculated.     

沙漠油田开发生态环境保护的实践

文章阐述了地处沙漠腹地的石西油田在开发建设过程中开展环境保护工作的具体做法,从加强组织领导、制定并不断完善环保规章制度、加大科技投入等方面分析总结了在沙漠油田中开展环境保护的管理经验,通过加强井场作业、油气集输、建设用地管理、植物种植管理方面的措施,阐述了在沙漠油田开发建设中创建绿色油气田活动所取得的成绩。