改性Ti/SnO2-Sb电极催化降解1,4-二氯苯废水试验研究

采用聚合物前驱体法制备了未掺杂、掺杂Cu、掺杂Bi、掺杂Ni的4种Ti/Sn O2-Sb电极,运用SEM和XRD分析电极表面形貌及结构,通过线性极化扫描、循环伏安等测试考察其电化学性能,同时进行1,4二氯苯(p-DCB)降解实验进一步探究电极的电催化氧化特性.SEM和XRD结果表明,掺杂金属可改善电极表面形貌,增大其比表面积;电化学测试表明,Ti/Sn O2-Sb电极的析氧电位并未因金属掺杂而有明显改变,掺杂金属后,Ti/Sn O2-Sb电极具有更优的电催化活性和稳定性.p-DCB降解实验表明,改性Ti/Sn O2-Sb电极对p-DCB的降解效率明显提高,其中Ti/Sn O2-Sb-Cu电极的电催化处理效果最优,电解2 h后p-DCB的去除率即达到87.6%,且p-DCB的降解反应遵循一级反应动力学规律.     

浙江省沿海地区农村房屋抗风情况调研

对浙江省沿海地区的农村房屋抗风情况进行了调研,总结了被破坏房屋的主要结构特点。在对现有房屋的统计中发现相对不富裕地区高达60%以上的房屋属于抗风能力差和较差的,而一些比较富裕且受过台风袭击有过惨痛教训地区的房屋抗风能力差和较差的仅在20%以下。进一步研究发现抗风能力较好的房屋大都是建造年代不久,多为混凝土现浇板屋盖,上部多为框架或砖混结构,而抗风能力较差和差的大都为建造年代已久,多为小青瓦屋面,上部结构多为砖木结构或构造措施较差的砖混结构。同时对当地村民传统的"砖头压瓦"防护措施进行理论验算,得出当风速超过台风界限风速时,屋面上的砖头将会飞起,该措施应该避免。     

汶川地震后砌体结构房屋震害调查分析

2008年5月12日汶川8.0级地震后,根据四川省什邡市5幢砌体结构房屋震害的现场检测记录,以案例形式比较了房屋不同的结构形式、墙体布局、层间刚度比、构造柱设置、悬挑阳台、变形缝和选址等概念设计因素对结构抗震性能的影响,分析了结构发生各种损坏的原因,并对砌体结构房屋抗震设计提出建议。     

沉井加桩复合基础水平动力响应特性

沉井加桩复合基础是一种结合沉井及群桩各自优点形成的新型跨江海桥梁深水基础型式。在复杂的江海环境下,基础将承受强风、波浪及地震等引起的水平动荷载作用,其水平动力特性研究是复合基础合理设计施工和推广应用的重要保证。基于动力Winkler模型分别提出了沉井加桩基础的频域非线性及时域非线性计算方法,并同有限元对比验证了简化方法的正确性。通过算例进一步分析了冲刷对沉井加桩基础动力特性的影响规律,结果表明,土体应力历史及土体非线性对复合基础动力阻抗、共振幅值及频率均有显著影响。     

Surface microlayer enrichment of volatile organic compounds and semi-volatile organic compounds in drinking water source

Enrichment of volatile organic compounds(VOC) and semi-volatility organic compounds(SVOC) in surface microlayer(SM) of three ddnking water sources were studied. The enrichment factor(EFs) were 0.67 to 13.37 and 0.16 to 136, respectively. The results showed some VOC and most SVOC could enrich in SM. Some EFs of SVOC was quite high. Suspension and temperature could affect EFs of SVOC, slim wind and water movement do not destroy enrichment of organic in SM.     

Effects of pesticides on soil biochemical characteristics of a paddy soil

IntroductionThemaintenanceofsoilfertilitydependsonthesizeandtheactivityofthesoilmicrobialbiomasswhichisoffundamentalimportanceinbiologicalcyclesofalmostallmajorplantnutrients(Robert,1992 ) .Thereisconsiderableinterestinstudyofsoilbiochemicalcharacteristic…     

Occurrence and volatility of several trace elements in pulverized coal boiler

The contents of eight trace elements(Mn, Cr, Pb, As, Se, Zn, Cd, Hg) in raw coal, bottom ash and fly ash were measured in a 220 t/h pulverized coal boiler. Factors affecting distribution of trace elements were investigated, including fly ash diameter, furnace temperature, oxygen content and trace elements‘ characters. One coefficient of Meij was also improved to more directly show element enrichment in combustion products. These elements may be classified into three groups according to their distribution: Group 1. Hg, which is very volatile. Group 2: Pb, Zn, Cd, which are partially volatile. Group 3: Mn, which is hardly volatile. Se may be located between groups 1 and 2. Cr has properties of both group ! and 3. In addition, the smaller diameter of fly ash, the more relative enrichment of trace elements (except Mn). The fly ash showed different adsorption mechanisms of trace elements and the volatilization of trace elements rises with furnace temperature. Relative enrichments of trace elements(except Mn and Cr) in fly ash are larger than that in bottom ash. Low oxygen content can not always improve the volatilization of trace elements. Pb is easier to form chloride than Cd during coal combustion. Trace elements should be classified in accordance with factors.     

Kinetics of aniline oxidation with chlorine dioxide

For the first time, kinetics of aniline oxidation with chlorine dioxide(ClO2) were investigated systematically by detecting concentration of aniline with HPLC at regular intervals. Results showed that the reaction was first-order both in ClO2 and in aniline, and the oxidation reaction could be described as second-order reaction. Stoichiometric factor η was experimentally determined to be 2.44. The second-order-reaction rate constant k was 0.11L/(mol.s)under condition of pH 6.86 and water temperature(Tw) 287K. Reaction activation energy was 72.31 kJ/mol, indicating that the reaction could take place under usual water treatment conditions. The reaction rate constants in acidic and alkali media were greater than that in neutral medium. Chlorite ion could slightly increase reaction rate in acidic medium. p-aminophenol and azobenzene were detected by GC-MS as intermediates.     

Does participative leadership enhance work performance by inducing empowerment or trust? The differential effects on managerial and non‐managerial subordinates

We examined whether participative leadership behavior is associated with improved work performance through a motivational process or an exchange‐based process. Based on data collected from 527 employees from a Fortune 500 company, we found that the link between superiors' participative leadership behaviors and subordinates' task performance and organizational citizenship behavior toward organizations (OCBO) was mediated by psychological empowerment (motivational mediator) for managerial subordinates. Yet, for non‐managerial subordinates such as supporting and front‐line employees, the impact of participative leadership on task performance and OCBO was mediated by trust‐in‐supervisor (exchange‐based mediator). Implications for theories and practices are discussed. Copyright © 2009 John Wiley & Sons, Ltd.     

应急财产征用补偿若干问题探讨

突发事件应对工作,是关系国家经济社会发展全局和人民群众生命财产安全的大事,是全面贯彻落实科学发展观、构建社会主义和谐社会的重要内容。《中华人民共和国突发事件应对法》为处置突发事件提供了法律依据,标志着应急管理工作步入法制化轨道。为了增强突发事件的应对能力,