沈阳市农村生活污水处理设施有机废弃物归趋

采用实地观察法、文献调查法对沈阳市农村生活污水处理设施基本状况进行研究分析。结果显示:沈阳市已建成农村生活污水处理设施297处,有机废弃物产生量(干重)约为:剩余污泥637 t/a、湿地植物废弃物169 t/a。     

Nanoencapsulation of hexavalent chromium with nanoscale zero-valent iron: High resolution chemical mapping of the passivation layer

Solid phase reactions of Cr(Ⅵ) with Fe(0) were investigated with spherical-aberration-corrected scanning transmission electron microscopy(Cs-STEM) integrated with X-ray energy-dispersive spectroscopy(XEDS). Near-atomic resolution elemental mappings of Cr(Ⅵ)–Fe(0) reactions were acquired. Experimental results show that rate and extent of Cr(Ⅵ) encapsulation are strongly dependent on the initial concentration of Cr(Ⅵ) in solution. Low Cr loading in nZⅥ(1.0 wt%) promotes the electrochemical oxidation and continuous corrosion of n ZⅥ while high Cr loading(1.0 wt%) can quickly shut down the Cr uptake. With the progress of iron oxidation and dissolution, elements of Cr and O counter-diffuse into the nanoparticles and accumulate in the core region at low levels of Cr(Ⅵ)(e.g., 10 mg/L). Whereas the reacted n ZⅥ is quickly coated with a newly-formed layer of 2–4 nm in the presence of concentrated Cr(Ⅵ)(e.g., 100 mg/L). The passivation structure is stable over a wide range of pH unless pH is low enough to dissolve the passivation layer. X-ray photoelectron spectroscopy(XPS) depth profiling reconfirms that the composition of the newly-formed surface layer consists of Fe(Ⅲ)–Cr(Ⅲ)(oxy)hydroxides with Cr(Ⅵ) adsorbed on the outside surface. The insoluble and insulating Fe(Ⅲ)–Cr(Ⅲ)(oxy)hydroxide layer can completely cover the n ZⅥ surface above the critical Cr loading and shield the electron transfer. Thus, the fast passivation of nZⅥ in high Cr(Ⅵ) solution is detrimental to the performance of nZⅥ for Cr(Ⅵ) treatment and remediation.     

Relationship between physicochemical properties and dewaterability of hydrothermal sludge derived from different source

Sewage sludge (SS) and deinking sludge (DS) were used to comparatively study the hydrothermal dewatering of sludge with different components. For a better overview, an insight into the relationship between physicochemical properties and dewaterability of hydrothermal sludge was provided. Results found that not all kinds of sludge were suitably conditioned by hydrothermal treatment (HT) in term of the elevation of dewaterability. Higher hydrothermal temperature tended to enhance the dewaterability of SS rather than DS, which was supported by the variation of their physicochemical properties (including water distribution, bonding energy, extracellular polymeric substance (EPS), particles size, acid functional groups and zeta potential in this study). In addition, the changes in surface morphology suggested that the reverse effect of HT on sludge dewaterability was mainly due to their dewatering behavior. For SS, the destruction of EPS structure leaded to the release of bound water, thereby strengthening sludge dewatering. Conversely, “Bridging effect” generated by lignocellulose in DS was beneficial for sludge dewatering; however, the increasing hydrothermal temperature degraded part of lignocellulose and weakened “bridging effect”, finally resulting in worse dewaterability of DS.     

重庆九龙坡城区和城郊大气污染物浓度特征研究

为了解重庆市九龙坡区城区和城郊大气污染物浓度特征,分析了城区和城郊国控空气站点2014年3月~2015年2月典型污染物的浓度变化。结果表明,除O_3表现出夏高冬低的季节变化趋势外,其它污染物均表现出冬高夏低的季节变化趋势。PM_(2.5)污染最严重,城区和郊区日均值超标率分别为31.4%和33.4%。城区和城郊的PM_(2.5)浓度之间没有显著性差异(p0.05),城郊O_3浓度显著高于城区(p0.01),NO_2、SO_2、CO和PM_(10)则是城区显著高于城郊(p0.01)。     

小流域综合治理新设计研究——猪沼果模式

近年来,小流域综合治理的主旨思想改变了,其工作重心在于巩固和发展治理开发的成果,提升综合治理的科技含量,增加治理带来的经济效益。于是将小流域的治理与生产联系起来成为了当前科研人员的研究方向。文章对目前部分地区大力推广的"猪-沼-果"模式在小流域治理方面的概念、发展及综合效益等方面做了一些综述。总的来说,猪沼果模式能够增加农村的能源,增加农民收入,并保护绿植,促进小流域治理。     

环境保护因素对落后地区旅游开发的促进作用研究

为了提高落后地区旅游开发的质量,分别从低碳环保旅游以及生态旅游两方面,研究环保因素对落后地区旅游开发的促进作用。提出低碳环保旅游,并分析低碳环保对落后地区旅游业可持续发展的意义,在落后地区旅游开发中实施低碳饮食、低碳住宿、低碳交通以及低碳能源的旅游开发模式。对中国落后地区生态旅游现状和意义实施研究,分析生态旅游对落后地区旅游开发的促进作用。最终给出了落后地区实现生态旅游开发的建议,构建落后地区低碳环保的新型生态旅游模式,实现落后地区旅游的可持续发展。     

基于医疗大数据的空气污染类疾病信息分析研究

世界卫生组织表示,空气污染为造成全球疾病负担的一项重要因素,能够导致心血管疾病、呼吸系统疾病等各种疾病的发生,空气污染问题已经成为公共卫生领域关注的重点问题,对基于医疗大数据的空气污染类疾病信息进行分析。利用半参数广义相加的泊松回归模型,在控制时间、长期趋势、气象因素等一些复杂条件的基础上,对2012年1月1日至2016年12月31日,某市空气中SO2、PM10和NO2等一些主要空气污染物的监测浓度值与呼吸系统疾病(肺炎以及支气管炎与哮喘)住院人数的相关性进行研究,研究结果表明,空气颗粒物PM10对患病率的影响相对于气态污染物SO2、NO2更为严重。     

盐酸萘乙二胺比色法测定大气中硝基苯、苯胺浓度的改进

本文探讨了盐酸萘乙二胺比色方法测定大气中硝基苯、苯胺浓度的最佳反应条件,如酸度、试剂加入量、反应温度、反应时间等。简化了过滤、洗涤操作,精密度高、显色稳定。     

COD快速分析高氯废水的实验研究

对水中氯离子含量超过10000mg／L时进行除氯的预处理，保证了分析数据的真实、准确、可靠。     

火焰原子吸收分光光度法测定鱼内脏及河流底泥中的铜

采用火焰原子吸收分光光度法测定鱼内脏及河流底泥中的铜。鱼内脏经组织捣碎机捣成匀浆后，加硝酸消解；底泥则经氢氟酸和高氯酸消化。该方法具有灵敏度高，精密度和回收率较好等特点。