高炉瓦斯泥综合利用技术述评

瓦斯泥是高炉副产物,因其中富含锌,直接用于烧结会增加高炉锌负荷。在分析了瓦斯泥的矿物特征的基础上,综述了选矿法、化学浸出法、直接还原法等几种瓦斯泥有价成分的回收利用方法。选矿法根据碳、锌、铁的性质及赋存状态的差异分离各物质,具有工艺简单、成本低的优点,但分离不彻底、回收率低;化学浸出法使锌进入溶液而其他矿物不溶或微溶,分离效果较好,但处理量小,后续处理难度大;直接还原法是在高温下使瓦斯泥中的金属还原,锌蒸发后进入烟气,最终可得到含氧化锌较高的烟尘和含金属铁的脱锌瓦斯泥,该法适应性强、处理量大、分离效果好,是目前应用较为广泛的瓦斯泥处理方法,但其设备投资大。     

基于网格划分的宜兴市区滨水区可达性评价

城市滨水区可达性不仅仅是空间距离的阻隔,还包括人们对滨水空间的需求及滨水区自身对公众的吸引力。依据潜能模型的概念,选取人口密度、滨水区综合质量和以土地利用表达的交通作为评价因子,借助ArcGIS93软件,建立了基于网格划分的滨水区可达性计算模型。该模型通过对研究区域进行等距网格划分以及定量计算网格内的人口密度、最小阻力成本和滨水区综合质量来进行滨水区可达性的定量评价。运用该模型评价了宜兴市中心城区居民至各滨水区的可达性水平,发现各滨水区平均可达性水平存在明显差异,最高的是团氿,最低的是蠡河;对每个滨水区而言,可达性从空间上均呈现出以滨水区为中心由内向外递减的趋势。评价结果可为城市滨水区合理建设格局的制定和居民享用滨水区的公平性提供决策参考     

基于MODIS的渍害田和正常农田遥感特性对比研究

渍害田在我国南方地区分布广泛,严重影响农业生产。以四湖流域洪湖地区为实验区,基于渍害田的物理及生态特性来探讨渍害田遥感识别特性。利用2002～2011年MODIS产品,辅以土壤图、土地覆被数据,对比分析了正常农田及渍害田在反照率、增强型植被指数（EVI）、地表夜温、地表温差和表观热惯量的时相差异;并结合相关研究成果加以解释和验证。结果表明：一年中大部分时段,正常农田的反照率、EVI、地表温差都大于渍害田,而地表夜温、表观热惯量都低于渍害田;各指标的多年平均值也具有类似差别;渍害田的EVI在6、7月份比正常农田高, 可能是由于渍害田在雨、热、肥条件同时良好时比正常农田生长的更快。研究结果可为进一步准确识别渍害田空间分布及其动态变化     

空冷机组运行初期如何降低汽水系统的硅含量

为了保证对空冷发电机组的水汽系统在机组运行初期硅含量监督指标的控制,对影响水汽中SiO₂含量的因素进行分析,提出洗硅的有效方法和措施。应用结果表明:采用洗硅、投运前冲洗、合理的凝结水精处理以及调节pH值等控制手段,可有效改善并解决水汽系统硅含量长期超标的问题,保证机组合格的水汽品质。     

Detection of tritium sorption on four soil materials

In order to measure groundwater age and design nuclear waste disposal sites, it is important to understand the sorption behavior of tritium on soils. In this study, batch tests were carried out using four soils from China: silty clays from An County and Jiangyou County in Sichuan Province, both of which could be considered candidate sites for Very Low Level Waste disposal; silty sand from Beijing; and loess from Yuci County in Shanxi Province, a typical Chinese loess region. The experimental results indicated that in these soil media, the distribution coefficient of tritium is slightly influenced by adsorption time, water/solid ratio, initial tritium specific activity, pH, and the content of humic and fulvic acids. The average distribution coefficient from all of these influencing factors was about 0.1-0.2 mL/g for the four types of soil samples. This relatively modest sorption of tritium in soils needs to be considered in fate and transport studies of tritium in the environment.     

北京市人口老龄化的时空变化特征

人口老龄化现已成为当今主要的人口问题之一,并引起越来越多的关注,人口老龄化进程与老年人口空间分布特征研究是未来人口问题研究的一个重要分支.本文基于ESDA全局和局部空间自相关分析,利用北京市第四次和第五次人口普查数据以及1995和2005年1％人口抽样调查数据,对北京市县域尺度老龄人口分布总体和局部空间差异的变化趋势、特征进行了初步探索.结果表明,北京市老龄人口空间分布各区县差异较大,且呈现出明显的圈层结构特征,中心四城区老龄人口比重较高,近郊区老龄人口比重较全市平均水平低,远郊区老年人口比重又有所回升;同时,北京地区老年人口各区县的空间分布差异随着时间的推移而不断扩大,中心老城区呈现不断增强的集聚趋势,而远郊区的老年人口扩散效应明显大于集聚效应.     

关于减排技术途径和政策的探讨

通过对发达国家先进的节能减排技术和政策,以及我国现阶段所采取的减排技术政策的分析,通过对我国重点行业二氧化硫和化学需氧量的减排技术现状对策研究,对适合我国减排的技术途径和配套政策进行探讨。     

三峡工程蓄水运用期库区干流水质分析

分析了三峡库区蓄水前后（1998～2009年）干流水质的变化及原因。结果表明,同蓄水前相比,蓄水后库区干流水质变好,库区干流断面月度达标率均值由蓄水前的623%变为蓄水后的783%,库区干流超标污染物主要为高锰酸盐指数、总磷、铅等。蓄水后水质时空分布出现新的特点,近坝水体悬浮物、浑样高锰酸盐指数、总磷、铅等可吸附污染物浓度显著降低。蓄水后年内悬浮物及浑样高锰酸盐指数、总磷和铅浓度仍然是丰水期＞平、枯水期,但近坝水体不同水期间浓度差别比蓄水前明显减小。蓄水后,库区干流浑样高锰酸盐指数、总磷、铅浓度整体上表现为从库尾至库首沿程下降,尤以丰水期沿程下降最为突出。浑样高锰酸盐指数、总磷、铅浓度以上变化特征主要缘于库区水位抬高后,流速减小导致的澄清作用,即高锰酸盐指数所代表污染物、磷、铅等随泥沙发生了不同程度的沉降。蓄水前后清样高锰酸盐指数和总磷未发生明显变化,156 m蓄水后至今,清样铅浓度明显低于蓄水前。     

Characterization of peroxyacetyl nitrate (PAN) under different PM2.5 concentration in wintertime at a North China rural site

As a secondary pollutant of photochemical pollution, peroxyacetyl nitrate(PAN) has attracted a close attention. A four-month campaign was conducted at a rural site in North China Plain(NCP) including the measurement of PAN, O₃, NO_x, PM_2.5, oxygenated volatile organic compounds(OVOCs), photolysis rate constants of NO₂ and O₃ and meteorological parameters to investigate the wintertime characterization of photochemistry from November 2018 to Fe...     

Flotability and flotation separation of polymer materials modulated by wetting agents

The surface free energy, surface tension and contact angles were performed to investigate the properties of wetting agents. Adsorption of wetting agents changes wetting behavior of polymer resins. Flotability of polymer materials modulated by wetting agents was studied, and wetting agents change significantly flotability of polymer materials. The flotability decreases with increasing the concentration of wetting agents, and the wetting ability is lignin sulfonate (LS) > tannic acid (TA) > methylcellulose (MC) > triton X-100 (TX-100) (from strong to weak). There is significant difference in the flotability between polymer resins and plastics due to the presence of additives in the plastics. Flotation separation of two-component and multicomponent plastics was conducted based on the flotability modulated by wetting agents. The two-component mixtures can be efficiently separated using proper wetting agent through simple flotation flowsheet. The multicomponent plastic mixtures can be separated efficiently through multi-stage flotation using TA and LS as wetting agents, and the purity of separated component was above 94%, and the recovery was more than 93%.