Determining the equilibrium partitioning coefficients of volatile organic compounds at an air-water interface

The single equilibration technique (SET) was adopted to determine the partitioning coefficients (pc) at an air-water interface for volatile organic compounds (VOCs), including ethanol, iso-propanol (IPA), iso-butanol (IBA), methyl ethyl ketone (MEK) and toluene, all extensively used in industrial processes. Standard SET procedures were established. The liquid concentrations (CL) of tested VOCs ranged from 10 to 125 mg l(-1) for alcohols and MEK, and from 0.5 to 20 mg l(-1) for toluene. The temperatures (Tw) of aqueous VOC solutions were maintained at 27, 32, 38 and 42 degrees C to determine the gaseous concentrations at equilibrium (Cg*) and pc of VOCs, using the formula pc=(Cg*/CL). Results reveal that the pc values of all tested components increase slowly with Tw given a constant CL, and that the pc of alcohols and MEK fall as CL increases at a constant Tw. In contrast, the pc of toluene is not significantly impacted by a variation in CL at a constant Tw. However, the effect of CL concentration has seldom been discussed. The heats of liquid and gaseous phase transfer (DeltaHtr) of VOC, and the highly linear regression (with squared correlation coefficients, R2, from 0.901 to 0.999) between lnCg* and Tw(-1) are also evaluated. The experimental results and the VOC mass transfer characteristics are helpful for evaluating the emission of VOC from the water surface of wastewater treatment facilities.     

云南蛇纹岩发育土壤与植被中重金属含量的分析

对云南蛇纹岩发育土壤进行了植物和土壤的重金属含量调查和分析.结果表明,Ni、Co为土壤中的主要污染金属,在土壤中的含量范围分别为565~4844mg/kg和69~481mg/kg,Cu、Zn含量则在正常范围内;土壤中Ni、Co生物可利用态的含量均较低.统计分析显示,土壤中Ni、Co含量之间存在显著正相关(R=0.794,P<0.01).调查蛇纹岩发育土壤上隶属21科的42种高等植物,并分析其重金属含量,发现植物体内Ni、Co含量也存在显著相关,可能受到土壤因素的影响所致.调查并未发现Ni、Co的超累积植物,但发现此区域存在较多的Ni、Co耐性植物,对Ni矿废弃地的植被重建有一定的研究意义.图1表6参8     

Regenerative thermal oxidation of airborne N, N-dimethylformamide and its associated nitrogen oxides formation characteristics

In this study, a two-bed electrically heated regenerative thermal oxidizer (RTO) was used to test the thermal destruction and oxides of nitrogen (NOx) formation characteristics in burning airstreams that contain either N, N-dimethylformamide or dimethylformamide (DMF) mixed with methyl ethyl ketone (MEK). The RTO contained two 0.152 m x 0.14 m x 1 m (L x W times] H) beds, both packed with gravel particles with an average diameter of approximately 0.0111 m and a height of up to 1 m with a void fraction of 0.42 in the packed section. The thermal recovery efficiency (TRE) and the gas pressure drop over the beds were also studied. Experimental results reveal that, with a valve shifting time (ts) of 1.5 min, a superficial gas velocity (Ug) of 0.39 m/sec (evaluated at an influent air temperature of around 30 degrees C) and preset maximum destruction temperatures (Ts) of 750-950 degrees C, no NOx was present in the effluent gas from the RTO when it was loaded with DMF-free air. When only DMF was present in the influent air, the average destruction efficiencies exceeded 96%, and increased with the influent DMF concentration from 300 to 750 mg/N x m3. The "NOx-N formation/DMF-N destruction" mass ratios were in the range 0.76-1.05, and decreased as the influent DMF concentration increased within the experimental range. When both DMF and MEK were present in the influent gas, the NO, formation ratio was almost the same and the DMF destruction efficiency increased with the influent MEK/DMF ratio from 150/300 to 4500/300 (mg/mg) and in the preset temperature range. The NOx formation ratios were in the range 0.75-0.96. The TRE decreased as Ug increased but was invariant with Ts. The Ergun equation was found to suffice in the estimation of the pressure drop when the gas flowed over the packing beds.     

Mapping probability of fire occurrence in San Jacinto Mountains,California, USA

An ecological data base for the San Jacinto Mountains, California, USA, was used to construct a probability model of wildland fire occurrence. The model incorporates both environmental and human factors, including vegetation, temperature, precipitation, human structures, and transportation. Spatial autocorrelation was examined for both fire activity and vegetation to determine the specification of neighborhood effects in the model. Parameters were estimated using stepwise logistic regressions. Among the explanatory variables, the variable that represents the neighborhood effects of spatial processes is shown to be of great importance in the distribution of wildland fires. An important implication of this result is that the management of wildland fires must take into consideration neighborhood effects in addition to environmental and human factors. The distribution of fire occurrence probability is more accurately mapped when the model incorporates the spatial term of neighborhood effects. The map of fire occurrence probability is useful for designing large-scale management strategies of wildfire prevention.     

Optimizing Liquid Effluent Monitoring at a Large Nuclear Complex

Effluent monitoring typically requires a large number of analytes and samples during the initial or startup phase of a facility. Once a baseline is established, the analyte list and sampling frequency may be reduced. Although there is a large body of literature relevant to the initial design, few, if any, published papers exist on updating established effluent monitoring programs. This paper statistically evaluates four years of baseline data to optimize the liquid effluent monitoring efficiency of a centralized waste treatment and disposal facility at a large defense nuclear complex. Specific objectives were to: (1) assess temporal variability in analyte concentrations, (2) determine operational factors contributing to waste stream variability, (3) assess the probability of exceeding permit limits, and (4) streamline the sampling and analysis regime. Results indicated that the probability of exceeding permit limits was one in a million under normal facility operating conditions, sampling frequency could be reduced, and several analytes could be eliminated. Furthermore, indicators such as gross alpha and gross beta measurements could be used in lieu of more expensive specific isotopic analyses (radium, cesium-137, and strontium-90) for routine monitoring. Study results were used by the state regulatory agency to modify monitoring requirements for a new discharge permit, resulting in an annual cost savings of US $223,000. This case study demonstrates that statistical evaluation of effluent contaminant variability coupled with process knowledge can help plant managers and regulators streamline analyte lists and sampling frequencies based on detection history and environmental risk.     

Modeling the width and placement of riparian vegetated buffer strips: a case study on the Chi-Jia-Wang stream,Taiwan

Improper agricultural activities seriously affect water quality. It is very important to control agricultural nonpoint source pollution along the Chi-Jia-Wang Stream to protect the habitat of land-locked salmon (Oncorhynchus masou formosanus), one of the endangered species in Taiwan. Riparian vegetative buffer strips are used to intercept wastewater, surface runoff and groundwater flow to reduce pesticide, nutrient and other organic pollutants before they enter the stream. This study estimates the suitable width for vegetated buffer strips in the riparian zone along the stream using a geographic information system and an index model. The groundwater in the study area is easily contaminated by pollutants due to the high hydraulic conductivity in the riparian zone of the Chi-Jia-Wang Stream. After comparing simulations on selected 46 kinds of selected pesticides, the maximum safety depth of Fenarimol was estimated. A wider Fenarimol vegetated strip is needed as a buffer zone to ensure pollution control effectiveness. Simulation results can provide a preliminary evaluation for the soil or groundwater pollution caused by pesticides, but the actual influences require onsite data verification.     

APPLICATION OF TABU SEARCH TO GROUND WATER PARAMETER ZONATION1

ABSTRACT: The spatial distribution of hydrogeologic parameter is an important issue in ground water simulation. One of the methods is to divide an area into several zones such that parameters are assumed to be constant within zone. The purpose of this study is to apply Tabu Search (TS) to find the best zonation of parameters that can result in the best ground water simulation. The initial zonation can be determined as the Thiessen method, and then zonation is optimized by T.S. The mean square error between simulated and observed hydraulic heads was used as the objective function. A designed confined aquifer with known zonation was used as an example to test the proposed method. Results indicated that Tabu Search can locate the optimal zonation successfully and avoid being trapped by local optimal zonations. Besides this, four other arbitrary initial zonations can be directed to the optimal zonation by TS, which proves the robustness of the proposed method. The method proposed in this study is feasible and expected to work well in the field problems with sufficient sampling of concerned parameters.     

Characterization of spent nickel–metal hydride batteries and a preliminary economic evaluation of the recovery processes

Valuable metal materials can be recovered from spent nickel–metal hydride (NiMH) batteries. However, little attention has been paid to the metal compositions of individual components of NiMH batteries, although this is important for the selection of the appropriate recycling process. In this study, NiMH batteries were manually disassembled to identify the components and to characterize the metals in each of these. A preliminary economic analysis was also conducted to evaluate the recovery of valuable metals from spent NiMH batteries using thermal melting versus simple mechanical separation. The results of this study show that metallic components account for more than 60% of battery weight. The contents of Ni, Fe, Co, and rare earth elements (REEs) (i.e., valuable metals of interest for recovery) in a single battery were 17.9%, 15.4%, 4.41%, and 17.3%, respectively. Most of the Fe was in the battery components of the steel cathode collector, cathode cap, and anode metal grid, while Ni (>90%) and Co (>90%) were mainly in the electrode active materials (anode and cathode metal powders). About 1.88 g of REEs (Ce, La, and Y) could be obtained from one spent NiMH battery. The estimated profits from recovering valuable metals from spent NiMH batteries by using thermal melting and mechanical processes are 2,329 and 2,531 USD/ton, respectively, when including a subsidy of 1,710 USD/ton. The findings of this study are very useful for further research related to technical and economic evaluations of the recovery of valuable metals from spent NiMH batteries. Implications: The spent nickel–metal hydride (NiMH) batteries were manually disassembled and their components were identified. The metals account for more than 60% of battery weight, when Ni, Fe, Co, and rare earth elements (REEs) were 17.9%, 15.4%, 4.41%, and 17.3%, respectively, in a single battery. The estimated profits of recovering valuable metals from NiMH batteries by using thermal melting and mechanical processing are 2,329 and 2,531 USD/ton, respectively, when including a subsidy of 1,710 USD/ton. These findings are very useful to develop or select the recovery methods of valuable metals from spent NiMH batteries.     

A Study of Sustainable Material Management Approach in Taiwan

Sustainable material management (SMM) has been initiated by the Organization for Economic Cooperation and Development (OECD) in 2005. SMM is an approach to promote resource conservation, reducing negative environmental impacts and preserving the natural capital of material and the balance of economic efficiency and social equity. Life cycle assessment and material flow analysis have been widely used to estimate the environmental impacts for resource consumption, but economic development has not been taken into account. Before 1984, improper garbage disposal was not an important issue in Taiwan. But over the past three decades, the Taiwan Government has accomplished not only waste disposal but also resource recycling, which are conducive to the essence of SMM. This study is the first research project to develop a SMM conceptual model for policy and strategy in Taiwan. SMM is the suitable waste management concept for the next era. This study reviewed the policy and strategy that has been applied in Taiwan’s waste management, and compares the efficiency of waste management policy in Taiwan with the concept of SMM. A case study of the waste flow will be used to prove that the sustainable material policy can be a suitable management system to achieve sustainable development. This study will open a new chapter of research on global SMM for Taiwan.     

Infant exposure to polychlorinated dibenzo-p-dioxins, dibenzofurans and biphenyls (PCDD/Fs, PCBs)--correlation between prenatal and postnatal exposure

Polychlorinated dibenzo-p-dioxins, dibenzofurans (PCDD/Fs) and polychlorinated biphenyls (PCBs) are recognized environmental endocrine disruptors, which are environmentally persistent and may bio-accumulate in human bodies. Pregnant and nursing women may pass these pollutants to their babies both trans-placentally and lactationally. We measured and examined correlations of the levels of PCDD/Fs and PCBs in perinatal venous serum, placenta, umbilical-cord serum (representing prenatal exposure), and breast milk (postnatal exposure). Subjects included pregnant women without clinical complication between the ages of 25 and 35, who delivered their babies during 2000.12.01 and 2001.11.30 in central Taiwan. A total of 20 participants were randomly selected from those provided the four biological specimens for analysis of 17 PCDD/Fs, and 12 dioxin-like PCBs and six indicator PCBs using high-resolution gas chromatography/high-resolution mass spectrometry. Higher PCDD/F levels were found in placenta (10.3 TEq-pg/g lipid) and venous serum (9.1 TEq-pg/g lipid) compared to those in breast milk (7.6 TEq-pg/g lipid). Pearson and Spearman correlation analyses showed well association of PCDD/F and PCB levels between different specimens. The total dioxin/PCB level in milk, venous and cord serum can be well predicted by that in placenta through regression functions. This first study of multi-specimen correlation further established rather consistent ratios of these chemical concentrations in various specimens relative to those in venous serum.