全文获取类型
收费全文 | 2380篇 |
免费 | 29篇 |
国内免费 | 31篇 |
专业分类
安全科学 | 73篇 |
废物处理 | 86篇 |
环保管理 | 380篇 |
综合类 | 451篇 |
基础理论 | 492篇 |
环境理论 | 2篇 |
污染及防治 | 635篇 |
评价与监测 | 159篇 |
社会与环境 | 133篇 |
灾害及防治 | 29篇 |
出版年
2023年 | 23篇 |
2022年 | 22篇 |
2021年 | 36篇 |
2020年 | 30篇 |
2019年 | 29篇 |
2018年 | 62篇 |
2017年 | 63篇 |
2016年 | 77篇 |
2015年 | 81篇 |
2014年 | 103篇 |
2013年 | 125篇 |
2012年 | 105篇 |
2011年 | 150篇 |
2010年 | 130篇 |
2009年 | 125篇 |
2008年 | 127篇 |
2007年 | 128篇 |
2006年 | 118篇 |
2005年 | 76篇 |
2004年 | 96篇 |
2003年 | 71篇 |
2002年 | 80篇 |
2001年 | 76篇 |
2000年 | 39篇 |
1999年 | 22篇 |
1998年 | 28篇 |
1997年 | 33篇 |
1996年 | 30篇 |
1995年 | 41篇 |
1994年 | 34篇 |
1993年 | 15篇 |
1992年 | 17篇 |
1991年 | 32篇 |
1990年 | 13篇 |
1989年 | 23篇 |
1988年 | 10篇 |
1987年 | 7篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 9篇 |
1982年 | 18篇 |
1981年 | 11篇 |
1980年 | 5篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1970年 | 6篇 |
1969年 | 4篇 |
1966年 | 4篇 |
1965年 | 4篇 |
1960年 | 4篇 |
排序方式: 共有2440条查询结果,搜索用时 15 毫秒
71.
Fernandez C Monna F Labanowski J Loubet M van Oort F 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):1083-1091
The role of land use on fate of metals in soils is poorly understood. In this work, we studied the incorporation of lead in two neighboring soils with comparable pedogenesis but under long-term different agricultural management. Distributions of anthropogenic Pb were assessed from concentrations and isotopic compositions determined on bulk horizon samples, systematical 5-10 cm increment samples, and on 24-h EDTA extracts. Minor amounts of anthropogenic lead were detected until 1-m depth under permanent grassland, linked to high earthworm activity. In arable land, exogenous Pb predominantly accumulated at depths <60 cm. Although the proximity between the two sites ensured comparable exposition regarding atmospheric Pb deposition, the isotopic compositions clearly showed the influence of an unidentified component for the cultivated soil. This work highlights the need for exhaustive information on historical human activities in such anthropized agrosystems when fate of metal pollution is considered. 相似文献
72.
Newton M Cole EC Tinsley IJ 《Environmental science and pollution research international》2008,15(7):573-583
Background, aim, and scope Large-scale deforestation is occurring in subarctic North America following clearing by salvage logging or insect attack.
Numerous shrubs, herbs, and deciduous tree species tend to dominate areas on which stands of white spruce have grown. In the
absence of economically advantageous mechanical methods, several herbicides have value in efforts to reforest by planting
white spruce. Glyphosate, imazapyr, triclopyr, and hexazinone are all capable of selectively removing many competing species,
but there is concern about whether they would degrade naturally or persist owing to the frigid climate.
Materials and methods We established test plots with all four herbicides in upland and river bottom sites at 65°N and 58°N latitudes. The northern
site has extremely cold winters, with soils that freeze to a depth of 1–2 m, and precipitation of 275 mm/year. The southern
site has heavy rain and snowfall, amounting to 2,250 mm/year evenly distributed. Soil seldom freezes deeply. On each test
plot, one of the four herbicides was applied at twice the normal operational use rate to facilitate detection. They were applied
at the normal timing, with hexazinone, imazapyr, and triclopyr applied in June and glyphosate applied in fall. Soils were
sampled immediately after treatment and those samples used as references for dissipation data gathered over the next 11–14 months
from soil 0- to 15- and 15- to 45-cm depths.
Results Dissipation rates did not follow first-order rates because freezing conditions slowed most microbial activity. All products
dissipated to close to or below detection limits within the time of the study. Dissipation from vegetation was substantially
more rapid and depended on the nature of the plants treated as well as the product used. While soil residues dissipated more
slowly than in temperate regions, they did display consistent dissipation patterns during above-freezing conditions and also
the influence of microbial activity. Mobility was very limited with all products but hexazinone.
Discussion These products dissipate during summer in high latitudes much as they would in temperate climates. Winter changes are small,
but are not unlike some changes reported elsewhere under freezing conditions. Unlike many other studies, soil water did not
influence dissipation heavily, but the high latitude and semi-arid climate also did not create severely droughty soils. Residues
in plants were much higher than those in soils, but denatured the vegetation quickly, leading to unsuitability for forage
in any case.
Conclusions Low toxicity of these products and their metabolites combined with consistent dissipation and low mobility suggest that toxic
hazard of their use at high latitudes need not be a matter of serious concern to humans, terrestrial wildlife, or aquatic
systems. They are safe for use in management and rehabilitation of boreal forests when used properly.
Recommendations and perspectives Dissipation at rates approaching those in warmer climates offer a hypothesis that microflora native to high latitudes may
be adapted to destruction of such molecules at lower temperatures than may be indicated by experiments with microflora adapted
to warmer climates. Residues pose no observable risk to wildlife or humans in the area of use when products are applied properly.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available for authorized users. 相似文献
73.
Levels of perfluorochemicals in water samples from Catalonia,Spain: is drinking water a significant contribution to human exposure? 总被引:2,自引:0,他引:2
Ericson I Nadal M van Bavel B Lindström G Domingo JL 《Environmental science and pollution research international》2008,15(7):614-619
Background, aim, and scope In recent years, due to a high persistence, biomagnification in food webs, presence in remote regions, and potential toxicity,
perfluorochemicals (PFCs) have generated a considerable interest. The present study was aimed to determine the levels of perfluorooctane
sulfonate (PFOS), perfluorooctanoic acid (PFOA), and other PFCs in drinking water (tap and bottled) and river water samples
from Tarragona Province (Catalonia, Spain).
Materials and methods Municipal drinking (tap) water samples were collected from the four most populated towns in the Tarragona Province, whereas
samples of bottled waters were purchased from supermarkets. River water samples were collected from the Ebro (two samples),
Cortiella, and Francolí Rivers. After pretreatment, PFC analyses were performed by HPLC-MS. Quantification was done using
the internal standard method, with recoveries between 68% and 118%.
Results In tap water, PFOS and PFOA levels ranged between 0.39 and 0.87 ng/L (0.78 and 1.74 pmol/L) and between 0.32 and 6.28 ng/L
(0.77 and 15.2 pmol/L), respectively. PFHpA, PFHxS, and PFNA were also other detected PFCs. PFC levels were notably lower
in bottled water, where PFOS could not be detected in any sample. Moreover, PFHpA, PFHxS, PFOA, PFNA, PFOS, PFOSA, and PFDA
could be detected in the river water samples. PFOS and PFOA concentrations were between <0.24 and 5.88 ng/L (<0.48 and 11.8 pmol/L)
and between <0.22 and 24.9 ng/L (<0.53 and 60.1 pmol/L), respectively.
Discussion Assuming a human water consumption of 2 L per day, the daily intake of PFOS and PFOA by the population of the area under evaluation
was calculated (0.78–1.74 and 12.6 ng, respectively). It was found that drinking water might be a source of exposure to PFCs
as important as the dietary intake of these pollutants.
Conclusions The contribution of drinking water (tap and bottled) to the human daily intake of various PFCs has been compared for the first
time with data from dietary intake of these PFCs. It was noted that in certain cases, drinking water can be a source of exposure
to PFCs as important as the dietary intake of these pollutants although the current concentrations were similar or lower than
those reported in the literature for surface water samples from a number of regions and countries.
Recommendations and perspectives Further studies should be carried out in order to increase the knowledge of the role of drinking water in human exposure to
PFCs. 相似文献
74.
In areas of war and armed conflict it is difficult to get trustworthy and coherent information. Civil society and human rights groups often face problems of dealing with fragmented witness reports, disinformation of war propaganda, and difficult direct access to these areas. Turkish Kurdistan was used as a case study of armed conflict to evaluate the potential use of satellite images for verification of witness reports collected by human rights groups. The Turkish army was reported to be burning forests, fields and villages as a strategy in the conflict against guerrilla uprising. This paper concludes that satellite images are useful to validate witness reports of forest fires. Even though the use of this technology for human rights groups will depend on some feasibility factors such as prices, access and expertise, the images proved to be key for analysis of spatial aspects of conflict and valuable for reconstructing a more trustworthy picture. 相似文献
75.
Forty-six bacterial cultures, including one culture collection strain, thirty from the rhizosphere of Alyssum murale and fifteen from Ni-rich soil, were tested for their ability to tolerate arsenate, cadmium, chromium, zinc, mercury, lead, cobalt, copper, and nickel in their growth medium. The resistance patterns, expressed as minimum inhibitory concentrations, for all cultures to the nine different metal ions were surveyed by using the agar dilution method. A large number of the cultures were resistant to Ni (100%), Pb (100%), Zn (100%), Cu (98%), and Co (93%). However, 82, 71, 58 and 47% were sensitive to As, Hg, Cd and Cr(VI), respectively. All cultures had multiple metal-resistant, with heptametal resistance as the major pattern (28.8%). Five of the cultures (about of 11.2% of the total), specifically Arthrobacter rhombi AY509239, Clavibacter xyli AY509235, Microbacterium arabinogalactanolyticum AY509226, Rhizobium mongolense AY509209 and Variovorax paradoxus AY512828 were tolerant to nine different metals. The polymerase chain reaction in combination with DNA sequence analysis was used to investigate the genetic mechanism responsible for the metal resistance in some of these gram-positive and gram-negative bacteria that were, highly resistant to Hg, Zn, Cr and Ni. The czc, chr, ncc and mer genes that are responsible for resistance to Zn, Cr, Ni and Hg, respectively, were shown to be present in these bacteria by using PCR. In the case of, M. arabinogalactanolyticum AY509226 these genes were shown to have high homology to the czcD, chrB, nccA, and mer genes of Ralstonia metallidurans CH34. Therefore, Hg, Zn, Cr and Ni resistance genes are widely distributed in both gram-positive and gram-negative isolates obtained from A. murale rhizosphere and Ni-rich soils. 相似文献
76.
Amphibian metamorphosis assays are used to evaluate potential effects of endocrine disrupting compounds on the thyroid hormone axis. In this study, Xenopus laevis tadpoles are kept in a solution of 0.2% thiourea (TU) to arrest and synchronise them in their development. The advantage of this synchronized amphibian metamorphosis assays is that synchronised tadpoles are available at any time to start metamorphosis experiments, and experimental groups are much more homogenous at the start of experimental exposure compared with groups selected from an untreated pool of animals. The water volume per animal was kept constant throughout the experimental period to overcome the influence of declining numbers of animals per aquarium due to metamorphosis and mortality on the density dependent development of the remaining tadpoles. Clophen A50 (a technical PCB mixture), the single congener 3,3',4,4'-tetrachlorobiphenyl (PCB 77) and apolar sediment extracts that were previously tested positive in the T-Screen, an in vitro proliferation assay for thyroid hormone disruption, were tested in the Synchronized Amphibian Metamorphosis Assay. Endpoints studied were mortality, malformations, body weight, and percentage of metamorphosed froglets at the end of the 60-day experimental period, percentage of tadpoles in different developmental stages, and developmental stage-dependent awarded penalty points. Dietary exposure to Clophen A50 (0.2-50mg/kg food) resulted in a significant increased percentage of tadpoles that did not pass metamorphosis at concentrations higher than 2mg/kg food. Time until metamorphosis in those animals that were able to metamorphose after the 60-days experimental period was significantly decreased. Dietary exposure to PCB 77, a congener that can be readily metabolised, did not result in significant effects in any exposure group (2-500 microg/kg food). Apolar sediment extracts from two of the three sites that are contaminated with a wide variety of chemicals significantly decreased the percentage of metamorphosed animals and significantly increased the number of tadpoles that remained in early and late metamorphic stages. These effects already occurred when the extracts where diluted more than 1000 times (on an organic carbon base) compared to environmental concentrations. The rank of potency was comparable to results obtained with the T-screen. This suggests the presence of thyroid hormone disrupting compounds in the aquatic environment and possible effects of such compounds on animal development in the wild. 相似文献
77.
Spalinger SM von Braun MC Petrosyan V von Lindern IH 《Environmental monitoring and assessment》2007,130(1-3):57-72
House dust has been identified as a major exposure medium for lead (Pb) in children. High levels of Pb in soil and house dust
have been recorded at the Bunker Hill Superfund Site (BHSS) in northern Idaho, an historic mining and smelting district. Soil
and dust remediation at the site was required; however, regional background soil and dust Pb levels had not been well characterized.
The objective of this survey was to determine background house dust Pb levels and to compare those levels with concentrations,
and dust and Pb loading rates measured at the BHSS. Soil and house dust samples were collected in five towns demographically
similar to the BHSS but unaffected by the mining industry. The background concentrations and loading rates were significantly
lower than those observed at the site. House age was a significant factor affecting background soil and house dust Pb concentrations
and loading rates. 相似文献
78.
Yates K Davies I Webster L Pollard P Lawton L Moffat C 《Journal of environmental monitoring : JEM》2007,9(10):1116-1121
Silicone rubber sheeting can be used as a passive sampling device for hydrophobic organic contaminants in the environment to determine the available concentrations in water and sediments. Reliable sampler-water partition coefficients are required to determine the sampling rates and the dissolved contaminant concentrations in water and in sediment pore water. Log partition coefficients (logK(sr,w)) for silicone rubber-water have been estimated for 32 polycyclic aromatic hydrocarbons (PAHs), 2 deuterated PAH analogues and 32 chlorobiphenyls (CBs) using the cosolvent method, with methanol as cosolvent. Strong linear relationships were found with literature values for the corresponding log octanol-water partition coefficients (logK(ow)) for both CBs and PAHs, confirming that partitioning into the silicone rubber is strongly determined by the hydrophobicity of the compounds, which suggests logK(ow) is a good predictor of logK(sr,w) and that absorption is the main mechanism for accumulation of analytes into the silicone rubber polymer. 相似文献
79.
Most of the world's children live in resource-poor countries where people are at a relatively high risk of exposure to catastrophic situations arising from conflict and natural disasters.(6) Given the potential social, psychological and psychiatric consequences of exposure to disaster, mental health and psychosocial support programmes are increasingly part of humanitarian aid. A minimum standard on mental and social aspects of health is included in the recently revised Humanitarian Charter and Minimum Standards in Disaster Response (Sphere Handbook) (Sphere Project, 2004). Most recommendations for mental health and psychosocial interventions in guidance documents are based on expert opinion rather than research. Consequently, interventions are being implemented without full understanding of their potential benefit or harm. This paper offers a child-focused review of the evidence for each of the interventions described as indicators for the Sphere standard on mental and social aspects of health. It suggests some, but limited, support for each of them. However, the evidence base needs substantial strengthening. 相似文献
80.
Urbatzka R van Cauwenberge A Maggioni S Viganò L Mandich A Benfenati E Lutz I Kloas W 《Chemosphere》2007,67(6):1080-1087
The river Lambro is the most polluted tributary of the river Po in North Italy and was chosen as a representative water course discharging industrialized areas. Water and sediment samples of the river Lambro were investigated regarding the presence of endocrine disrupting compounds. A combined procedure was used consisting of solid-phase extraction and HPLC based fractionation of samples, of screening for (anti)androgenic activity using the yeast androgen screen (YAS) and of chemical analysis using HPLC-MS/MS and GC-MS. Androgenic and antiandrogenic activities were found in specific fractions of the water and sediment while the total extracts showed antiandrogenic activity only. The chemical analysis of the fractions and total extracts with antiandrogenic activities revealed the presence of compounds with suspected antiandrogenic potency such as bisphenol A, iprodione, nonylphenol, p,p'-DDE and tert-octylphenol but other unknown compounds contributed mainly to the observed antiandrogenic activities. The antiandrogenic load of the river Lambro ranged between 1.34 and 17.1 microM flutamide-equivalents and may pose a risk to aquatic environments. Future screenings for EDC in the environment that have the potential to interfere with reproduction of aquatic organisms should be extended to different modes of actions including (anti)androgenic ones. 相似文献