Climate Variability and Environmental Stress in the Sudan-Sahel Zone of West Africa

Environmental change in the Sudan-Sahel region of West Africa (SSWA) has been much debated since the droughts of the 1970s. In this article we assess climate variability and environmental stress in the region. Households in Senegal, Mali, Burkina Faso, Niger, and Nigeria were asked about climatic changes and their perceptions were compared across north–south and west–east rainfall gradients. More than 80% of all households found that rainfall had decreased, especially in the wettest areas. Increases in wind speeds and temperature were perceived by an overall 60–80% of households. Contrary to household perceptions, observed rainfall patterns showed an increasing trend over the past 20 years. However, August rainfall declined, and could therefore potentially explain the contrasting negative household perceptions of rainfall trends. Most households reported degradation of soils, water resources, vegetation, and fauna, but more so in the 500–900 mm zones. Adaptation measures to counter environmental degradation included use of manure, reforestation, soil and water conservation, and protection of fauna and vegetation. The results raise concerns for future environmental management in the region, especially in the 500–900 mm zones and the western part of SSWA.     

An integrated assessment of seawater intrusion in a small tropical island using geophysical,geochemical, and geostatistical techniques

In this study, geophysics, geochemistry, and geostatistical techniques were integrated to assess seawater intrusion in Kapas Island due to its geological complexity and multiple contamination sources. Five resistivity profiles were measured using an electric resistivity technique. The results reveal very low resistivity <1 Ωm, suggesting either marine clay deposit or seawater intrusion or both along the majority of the resistivity images. As a result, geochemistry was further employed to verify the resistivity evidence. The Chadha and Stiff diagrams classify the island groundwater into Ca-HCO₃, Ca-Na-HCO₃, Na-HCO₃, and Na-Cl water types, with Ca-HCO₃ as the dominant. The Mg²⁺/Mg²⁺+Ca²⁺, HCO₃ ^?/anion, Cl^?/HCO₃ ^?, Na⁺/Cl^?, and SO₄ ^2?/Cl^? ratios show that some sampling sites are affected by seawater intrusion; these sampling sites fall within the same areas that show low-resistivity values. The resulting ratios and resistivity values were then used in the geographical information system (GIS) environment to create the geostatistical map of individual indicators. These maps were then overlaid to create the final map showing seawater-affected areas. The final map successfully delineates the area that is actually undergoing seawater intrusion. The proposed technique is not area specific, and hence, it can work in any place with similar completed characteristics or under the influence of multiple contaminants so as to distinguish the area that is truly affected by any targeted pollutants from the rest. This information would provide managers and policy makers with the knowledge of the current situation and will serve as a guide and standard in water research for sustainable management plan.     

Occurrence of 1,1′-dimethyl-4,4′-bipyridinium (Paraquat) in irrigated soil of the Lake Chad Basin,Niger

Increased use of agrochemical products to improve yields for irrigated crops in sub-Saharan Africa has been accompanied by a significant increase in the risk of environmental contamination. Detailed examples of the fate of pesticides after initial spreading on crop fields are scarce in tropical regions, where safe practices and related health risks are poorly understood by smallholder farmers. In the semi-arid environment of the Lake Chad Basin, SE Niger, both intrinsic properties of pesticides and extrinsic factors such as soil and climate helped to characterize processes leading to an accumulation of pesticides in soils. Analysis by HPLC-UV of a 6 m deep soil profile showed the presence of Paraquat at concentrations from 953?±?102 μg kg^?1 to 3083?±?175 μg kg^?1 at depths between 0.80 and 2.75 m below the land surface. Soil analysis revealed that up to approximately 15 % of the total soil matrix consists of smectites, a clay mineral capable of retaining cationic pesticides such as Paraquat, and a very low content of organic matter (<0.15 wt.% TOC). Paraquat could be stored and not bioavailable in a clayey barrier at approximately 2-m depth and therefore does not represent an immediate risk for populations or environment in this form. However, if the Paraquat application rate remains constant, the clayey barrier could reach a saturation limit within 150–200 years and 180–220 years if we consider a DT50 in soil of ~1,000 days (FAO). Consequently, it could lead to a deeper infiltration and so a pollution of groundwater. Such a scenario can represent a health risk for drinking water and for the Lake Chad, which is a major resource for this densely populated region of semi-arid Africa. Further analyses should focus on deeper layers and groundwater Paraquat contents to validate or invalidate the hypothesis of storage in this clay-rich layer.     

Injury by Sulfur Dioxide,Hydrogen Fluoride,and Chlorine As Observed and Reflected On Vegetation in the Field

Plants were examined at three different locations in the eastern part of the United States to determine whether damage from air pollution had occurred. This paper discusses sulfur dioxide damage in the metropolitan New York City area; hydrogen fluoride damage near a glass fiber manufacturing plant in the midwest; and hydrochloric acid mist and chlorine damage from a manufacturing operation in an eastern state. The symptoms that developed in vegetation were often found to be similar. Chemical and microscopical analyses were helpful in diagnosing the toxicants.     

Improvement of Physico-Mechanical Properties of Photo-Cured Chitosan Films with Ethylene Glycol Dimethacrylate and (2-Hydroxyethyl) Methacrylate

Chitosan, a natural polymer, was prepared by deacetylation of chitin which was obtained from dried prawn shell and was characterized. Thin chitosan film of chitosan was prepared by casting method from 0.2 % chitosan in 2 % acetic acid solution. Five formulations were developed with ethylene glycol dimethacrylate and (2-hydroxyethyl) methacrylate along with photo-initiator, Darocur-1664 (4 %). The chitosan film was soaked in the formulations at different soaking times and irradiated under UV-radiation at different intensities for the improvement of its physical and mechanical properties. The cured chitosan films were then subjected to various mechano-chemical tests like tensile strength, elongation at break, polymer loading, water absorption and gel content. The formulation containing 30 % ethylene glycol dimethacrylate and 66 % (2-hydroxyethyl) methacrylate showed the best performance at the 30th UV pass of UV-radiation for 3 min soaking time.     

Flooding and the interannual variability of hydrologic quantities in the Missouri River basin

The six mainstem reservoirs in the Missouri River basin (MRB) are managed mainly to prevent flooding from snowmelt and heavy rainfall, a goal for which the interannual variabilities of precipitation ($P$), evapotranspiration ($\mathit{ET}$), and surface air temperature ($T_{\mathrm{air}}$) are vitally important. We tested the hypothesis that under the expected higher variability owing to global climate change, the months with the highest contributions to the interannual variability of $P$, $\mathit{ET}$, and $T_{\mathrm{air}}$ in the MRB will remain unchanged and quantified likely temporal trends in these quantities. Using high-resolution, downscaled Coupled Model Intercomparison Project Phase 5 multi-model ensemble data sets, we compared the multi-year ratio of monthly and annual interannual variability and temporal trends in $P$, $\mathit{ET}$, and $T_{\mathrm{air}}$ during 2011–2020 with three future decades. Results showed that the 6 months with the highest interannual variability in $P$ and $\mathit{ET}$ (April–September) are the same in all four decades. However, for $T_{\mathrm{air}}$, only 4 months (December–March) retain their status as highly variable throughout the four decades; September and October variability is exceeded by the variability in other months. This implies that, compared to $P$ and $\mathit{ET}$, the cyclical change in the probabilities of $T_{\mathrm{air}}$ in the MRB is less stable under future global climate change. This finding can be used to consider the need to alter existing strategies for reservoir release while minimizing the likelihood of aggravating flooding below the reservoirs.     

Monitoring of effluent DOM biodegradation using fluorescence, UV and DOC measurements

The potential of effluent DOM to undergo microbial degradation was assessed in batch experiments. Effluent samples from Haifa wastewater treatment plant and Qishon reservoir (Greater Haifa wastewater reclamation complex, Israel) were incubated either with effluent or soil microorganisms for a period of 2-4 months and were characterized by dissolved organic carbon contents (DOC), UV(254) absorbance and by fluorescence excitation-emission matrices. Three main fluorescence peaks were identified that can be attributed to humic/fulvic components and "protein-like" structures. During biodegradation, specific fluorescences (F/DOC) of the three peaks were increased at various extents, suggesting selective degradation of non-fluorescing constituents. In some cases increase in the effluent fluorescence (F) was observed thus proposing (i) the formation of new fluorescing material associated with DOM biodegradation and/or (ii) degradation of certain organic components capable of quenching DOM fluorescence. Based on the ratio between fluorescence intensity and UV(254), different biodegradation dynamics for fluorescent DOM constituents as compared with other UV-absorbing molecules was delineated. Overall, about 50% of the total DOM was found to be readily degradable such that residual resistant DOC levels were between 8 and 10 mg l(-1). Enhanced levels of residual DOM in effluent-irrigated soils may contribute to the DOM pool capable of carrying pollutants to groundwater.