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11.
Shim WJ Yim UH Kim NS Hong SH Oh JR Jeon JK Okamura H 《Environmental pollution (Barking, Essex : 1987)》2005,133(3):489-499
Triphenyltin (TPT) and tributyltin (TBT) concentrations were determined in two starfish species (Asteria pectinifera and Asterias amurensis), bivalves (Crassostrea gigas or Mytilus edulis), and seawater samples from sites around the coasts of Korea. Both TPT and TBT concentrations in starfish ranged from 8 to 1560 ng/g and from <2 to 797 ng/g as Sn on a dry weight basis, respectively. TPT concentration accounted for 75.4% and 86.4% of total phenyltin concentration in A. pectinifera and A. amurensis, respectively, while monobutyltin, a degradation product of TBT, accounted for 86.3% and 57.2% of total butyltin, respectively. Triphenyltin concentrations in A. pectinifera were significantly correlated to water and bivalve TPT concentrations, which implies that dietary uptake of TPT from contaminated prey as well as direct uptake from surrounding water contribute to TPT body residues in the starfish. Starfish could be target organisms for monitoring TPT compound in the marine environment, due to their high accumulation and low degradation capacity towards TPT. 相似文献
12.
The potential impacts driven by climate variability and urbanization in the Boise River Watershed (BRW), located in southwestern Idaho, are evaluated. The outcomes from Global Circulation Models (GCMs) and land use and land cover (LULC) analysis have been incorporated into a hydrological and environmental modeling framework to characterize how climate variability and urbanization can affect the local hydrology and environment at the BRW. The combined impacts of future climate and LULC change are also evaluated relative to the historical baseline conditions. For modeling exercises, Hydrological Simulation Program‐Fortran (HSPF) is used in parallel computing and statistical techniques, including spatial downscaling and bias correlation, are employed to evaluate climate consequences derived from GCMs as well. The implications of climate variability and land use change driven by urbanization are then observed to evaluate how these overall global challenges can affect water quantity and quality conditions at the BRW. The results show the combined impacts of both climate change and urbanization can lead to more seasonal variability of streamflow (from ?27.5% to 12.5%) and water quality, including sediment (from ?36.5% to 49.3%), nitrogen (from ?24% to 124.2%), and phosphorus (from ?13.3% to 21.2%) during summer and early fall over the next several decades. 相似文献
13.
Sun Hwa Hong Sun Ah Choi Myung-Hyun Lee Bo Ra Min Cheolho Yoon Hyeon Yoon Kyung-Suk Cho 《Environmental geochemistry and health》2011,33(1):41-47
The effects of arsenic (As) species, such as As(III), As(V) and dimethylarsinic acid (DMA), on the accumulation of As in cucumber (Cucumis sativus), as well as on its growth in a soil mesocosm were evaluated. When Cucumis sativus was cultivated in soils contaminated with 20 and 50 mg/kg of As(III), As(V) or DMA for 40 days, the growth was markedly inhibited by the inorganic As (As(III) and As(V)) rather than the organic As (DMA). Irrespective of the As species, the As concentrations accumulated in Cucumis sativus increased with increasing As concentration in the soil. The As bioaccumulation factors from soil into the tissue of Cucumis sativus were 17.5–35.4, 29.3–42.7 and 17.6–25.7 for As(III), As(V) and DMA, respectively. In addition, the As translocation factors from the roots to shoots were 0.025–0.031, 0.018–0.032 and 0.014–0.026 for As(III), As(V) and DMA, respectively. In conclusion, Cucumis sativus mainly accumulated As in its roots rather than its shoots and easily accumulated inorganic rather than organic As from the soil into its tissue. 相似文献
14.
Hong SH Choi SA Lee MH Min BR Yoon C Yoon H Cho KS 《Environmental geochemistry and health》2011,33(Z1):41-47
The effects of arsenic (As) species, such as As(III), As(V) and dimethylarsinic acid (DMA), on the accumulation of As in cucumber (Cucumis sativus), as well as on its growth in a soil mesocosm were evaluated. When Cucumis sativus was cultivated in soils contaminated with 20 and 50 mg/kg of As(III), As(V) or DMA for 40 days, the growth was markedly inhibited by the inorganic As (As(III) and As(V)) rather than the organic As (DMA). Irrespective of the As species, the As concentrations accumulated in Cucumis sativus increased with increasing As concentration in the soil. The As bioaccumulation factors from soil into the tissue of Cucumis sativus were 17.5-35.4, 29.3-42.7 and 17.6-25.7 for As(III), As(V) and DMA, respectively. In addition, the As translocation factors from the roots to shoots were 0.025-0.031, 0.018-0.032 and 0.014-0.026 for As(III), As(V) and DMA, respectively. In conclusion, Cucumis sativus mainly accumulated As in its roots rather than its shoots and easily accumulated inorganic rather than organic As from the soil into its tissue. 相似文献
15.
In studies assessing sorption of hydrophobic organic compounds (HOCs) in natural systems, the choice of an appropriate reference black carbon, which can represent environmental black carbon (BC), is essential. This study compared isotherms of two commonly available and distinct reference BCs (n-hexane soot (BCRM) and diesel particulate matter (SRM 2975)) and a natural sediment from a source with little black carbon (Lake Hartwell, SC) using 3,3',4-trichlorobiphenyl (IUPAC #35) as a model sorbate. There was greater sorptivity for PCB-35 by BCRM than by SRM 2975. The observed differences in sorption between the two reference black carbons for PCB-35 may be ascribed to the different chemical characteristics of the black carbons. Differences in pore volume distribution at <16A pore width are less likely to be responsible for the observed differences in sorption. The elemental analysis confirmed that BCRM was a pure n-hexane soot because only C, H and O were measured. In contrast, SRM 2975 also contained N and S and a higher O% than BCRM. Compared to the low BC sediment, the two reference BCs had greater pore volume distributions, surface areas, total pore volumes and sorption. The observed nF (i.e., Freundlich exponent) values for PCB indicated greater linearity of the isotherms for the natural sediment than for the reference black carbons. For designing studies of sorption of HOCs in natural systems, in particular, when PCBs are contaminants of concern, results of this study can aid selection of the appropriate reference BCs. 相似文献
16.
Bal Raj Deshwal Si Hyun Lee Jong Hyeon Jung Byung Hyun Shon Hyung Keun Lee 《环境科学学报(英文版)》2008,20(1):33-38
The study on the removal of NOx from simulated flue gas has been carded out in a lab-scale bubbling reactor using acidic solutions of sodium chlorite. Experiments were performed at various pH values and inlet NO concentrations in the absence or presence of SO2 gas at 45℃. The effect of SO2 on NO oxidation and NO2 absorption was critically examined. The oxidative ability of sodium chlorite was investigated at different pH values and it was found to be a better oxidant at a pH less than 4. In acidic medium, sodium chlorite decomposed into C102 gas, which is believed to participate in NO oxidation as well as in NO2 absorption. A plausible NOx removal mechanism using acidic sodium chlorite solution has been postulated. A maximum NOx removal efficiency of about 81% has been achieved. 相似文献
17.
ROH Mark S DE BENEDETTI Laura JOUNG Young Hee LEE Nam Sook 《应用与环境生物学报》2007,13(2):145-151
Germplasm collection is important to preserve and maximize genetic diversity for germplasm conservation. Tsuga dumosa ( D. Don) Eichler in Engler & Prantl. and T. chinensis var. forrestii (Downie) Silba germplasm was collected from three localities in China: Mt. Yulong, Wenfeng Temple and Mt. Dishiergu, Yunnan Province. Accessions were identified based on morphological characters and RAPD markers. The shapes of the apices and margins of needles were examined, and the length and width of needles, cones and seeds from accessions of mature plants were used to compare the morphological differences and to identify the germplasm. Molecular markers generated by randomly amplified polymorphic DNA (RAPD) were also used to characterize the taxa. Although the clustering based on RAPD markers was inconsistent with the morphological characters of the needles, based on the overall morphological characters and on RAPD markers, the accessions from Mt. Yulong and Wenfeng Temple were identified as T. chinertsis var. forrestii, and those from Mt. Dishiergu identified as T. dumosa. Taxonomic identification of the accessions was made based on morphology and by RAPD markers concurred. The results indicate that the shapes of the apices and margins of needles particularly from young plants could not be used as a possible key to identify T. dumosa and T. chinertsis var. forrestii. Fig 6, Tab 3, Ref24 相似文献
18.
The morphological changes of Poly(tetramethylene succinate) single crystal lamellae by hydrolysis are investigated, using TEM, WAXD and SAXS. And the morphology of PTMS spherulites was also observed by optical microscopy after treatments as well as single crystal lamellae. The edge region of single crystal lamella can be most easily affected in the initial stage of hydrolysis. As the hydrolysis time increases, the lamellae are separated into small fragments which may be started from the uneven or irregular parts of the surface. The WAXD results showed that crystallinity were increased with increasing of treatment time. The lamellar thickness decreased at the initial stage of hydrolysis and increased again. There were cracks on the surface of spherulites after hydrolysis and the direction of cracks were tangential direction of spherulites. This result was thought to be from the uniformity of molecular arrangement in the crystallographic unit cell. 相似文献
19.
Kim KY Ko HJ Kim HT Kim YS Roh YM Lee CM Kim CN 《Environmental monitoring and assessment》2007,133(1-3):255-266
This on-site survey study was performed to determine the concentrations and emissions of aerial contaminants in the different
types of swine houses in Korea and then to present beneficial information available for Korean pig producers to manage optimal
air quality in swine house. The swine houses investigated in this research were selected based on three criteria; manure removal
system, ventilation mode and growth stage of swine. Mean concentrations of aerial pollutants in swine houses were 8 ppm for
ammonia, 300 ppb for hydrogen sulfide, 2 mg m−3 for total dust, 0.6 mg m−3 for respirable dust, 4 log(cfu m−3) for total airborne bacteria and 3 log(cfu m−3) for total airborne fungi, respectively. Mean emissions based on pig (liveweight; 75 kg) and area (m2) were 250 and 340 mg h−1 for ammonia, 40 and 50 mg h−1 for hydrogen sulfide, 40 and 50 mg h−1 for total dust, 10 and 15 mg h−1 for respirable dust, 1.0 and 1.3 log(cfu) h−1 for total airborne bacteria and 0.7 and 1.0 log(cfu) h−1 for total airborne fungi, respectively. In general concentrations and emissions of gases were relatively higher in the swine
houses managed with deep-pit manure system with slats and mechanical ventilation mode than the different swine housing types
whereas those of particulates and bioaerosol were highest in the naturally ventilated swine houses with deep-litter bed system. 相似文献
20.
Air quality in underground spaces has seldom been evaluated in Korea. Accordingly, the current study recently evaluated asbestos exposure among Seoul metropolitan subway workers during the renovation of the subway's air-conditioning system. To identify possible routes of asbestos exposure, suspected sources, including gaskets, ceiling boards, ceiling materials, and dust settled inside ducts, were all sampled. Personal air samples were also taken to evaluate any asbestos exposure during the renovation. The asbestos fibers found in the samples were analyzed using a transmission electron microscope (TEM) equipped with an energy dispersive X-ray analyzer (EDX). Twelve out of eighteen bulk samples contained asbestos, the majority of which was chrysotile fibers. Asbestos was detected in 9 out of 72 personal air samples and the level ranged from 0.003 to 0.02 fibers/cm(3). While asbestos levels were below Korean occupational limit of 2 fibers/cm(3), they were still detectable and therefore further monitoring would be appropriate. 相似文献