Quantitative gap analysis for the West Coast of Florida based on experts’ opinion

The primary objective of this study was to identify gaps in coastal and marine data available through the Gulf Geospatial Assessment of Marine Ecosystems (GAME) project for the west coast of Florida. A survey was designed and sent to more than 2,000 experts working with coastal and ocean issues in the Gulf of Mexico to elicit their opinions. The survey asked the experts to rank 12 data categories and score the relevance of four qualifiers (spatial resolution, temporal resolution, age of data, and level of detail) using a discrete choice approach. The statistical interpretation of experts?? responses allowed assigning a relative value to each available data set, based upon their qualifiers. The results were then displayed in a Geographic Information System to visually show how the total value for all data categories or for a specific data category varies spatially and to identify data gaps. It was found that the total data set value is generally higher within Tampa Bay and along the coast. Areas with low total value show a lack of data sets that have qualifiers falling within the ideal range, as per experts?? opinions. The gap maps created for this project are useful to identify priority areas where money should be invested for future data collection.     

Siting MSW landfill using weighted linear combination and analytical hierarchy process (AHP) methodology in GIS environment (case study: Karaj)

Selection of landfill site is a complex process and needs many diverse criteria. The purpose of this paper is to evaluate the suitability of the studied site as landfill for MSW in Karaj. Using weighted linear combination (WLC) method and spatial cluster analysis (SCA), suitable sites for allocation of landfill for a 20-year period were identified. For analyzing spatial auto-correlation of the land suitability map layer (LSML), Maron’s I was used. Finally, using the analytical hierarchy process (AHP), the most preferred alternative for the landfill siting was identified. Main advantages of AHP are: relative ease of handling multiple criteria, easy to understand and effective handling of both qualitative and quantitative data.As a result, 6% of the study area is suitable for landfill siting and third alternative was identified as the most preferred for siting MSW landfill by AHP.The ranking of alternatives were obtained only by applying the WLC approach showed different results from the AHP. The WLC should be used only for the identification of alternatives and the AHP is used for prioritization. We suggest the employed procedure for other similar regions.     

Production and Purification of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Degrading Enzyme from Streptomyces sp. AF-111

A poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) degrading bacterial strain designated as AF-111 was isolated from sewage sludge sample. The bacterium was identified by 16S rRNA gene sequencing. The results revealed that strain AF-111 showed 99 % similarity with Streptomyces althioticus strain NRRL B-3981 and designated as Streptomyces sp. strain AF-111. An extracellular PHBV depolymerase enzyme was produced under optimized conditions and purified through ammonium sulphate fractionation and column chromatography. The enzyme was purified to homogeneity, indicated by sodium dodecyl sulfate–polyacrylamide gel electrophoresis and molecular weight was found to be approximately 51 kDa. Effect of temperature, pH, metal ions and inhibitors on the PHBV depolymerase activity was determined. The enzyme was stable at wide range of temperature (35–55 °C) and pH (6–8). PHBV depolymerase was stable in the presence of different metal ions except iron and zinc which had inhibitory effect on depolymerase activity. Both ethylenediamine teteracetic acid and phenylmethyl sulphonyl fluoride strongly inhibited enzyme activity which indicates that this enzyme belongs to the serine hydrolase family like other polyhydroxyalkanoate depolymerases. The results show that a depolymerase from strain AF-111 can effectively degrade PHBV, therefore, it can be applied in the process of biochemical monomer recycling.     

Strategies for the municipal waste management system to take advantage of carbon trading under competing policies: The role of energy from waste in Sydney

Climate change is a driving force behind some recent environmental legislation around the world. Greenhouse gas emission reduction targets have been set in many industrialised countries. A change in current practices of almost all greenhouse-emitting industrial sectors is unavoidable, if the set targets is to be achieved. Although, waste disposal contributes around 3% of the total greenhouse gas emissions in Australia (mainly due to fugitive methane emissions from landfills), the carbon credit and trading scheme set to start in 2010 presents significant challenges and opportunities to municipal solid waste practitioners. Technological advances in waste management, if adopted properly, allow the municipal solid waste sector to act as carbon sink, hence earning tradable carbon credits. However, due to the complexity of the system and its inherent uncertainties, optimizing it for carbon credits may worsen its performance under other criteria. We use an integrated, stochastic multi-criteria decision-making tool that we developed earlier to analyse the carbon credit potential of Sydney municipal solid waste under eleven possible future strategies. We find that the changing legislative environment is likely to make current practices highly non-optimal and increase pressures for a change of waste management strategy.     

Sorption of strontium on bentonite

Sorption of Sr on bentonite was studied using the batch technique. Distribution coefficients (K_d) were determined as a function of contact time, pH, sorbent and sorbate concentration and temperature. The data were interpreted in terms of Freundlich, Langmuir and Dubinin-Radushkevich isotherms. Thermodynamic parameters for the sorption system were determined at three different temperatures. The positive value of the heat of sorption, ΔH° = 30.62 kJ/mol at 298 K, shows that the sorption of strontium on bentonite is endothermic. The negative value of the free energy of sorption, ΔG° = −10.69 kJ/mol at 298 K, shows the spontaneity of the reaction. ΔG° becomes more negative with increasing temperature, which shows that the sorption process is more favorable at higher temperatures. The mean free energy for sorption, E 9 kJ/mol, suggests that ion exchange is the predominant mode of sorption in the Sr concentration range studied, i.e. 0.01 – 0.3 mol/dm³. The presence of complementary cations depresses the sorption of strontium on bentonite in the order Ca²⁺>Mg²⁺>K⁺>Na⁺. Some organic complexing agents and natural ligands also affect the sorption of strontium. The desorption studies with ground water at low strontium loadings on bentonite show that about 90% of Sr is irreversibly sorbed on the bentonite.     

APPLICATION OF AN ENVIRONMENTAL AND ECONOMIC MODELING SYSTEM FOR WATERSHED ASSESSMENTS1

ABSTRACT: A National Pilot Project (NPP) on Livestock and the Environment was initiated in 1992 to help provide solutions to environmental problems associated with livestock production. A major development of the NPP was the Comprehensive Economic and Environmental Optimization Tool‐Livestock and Poultry (CEEOT‐LP), an integrated modeling system designed to produce economic and environmental indicators for alternative policy scenarios applied to intensive livestock production watersheds. The system consists of a farm‐level economic model (FEM) and two environmental models: the field‐scale APEX model and the watershed‐level SWAT model. To date, CEEOT‐LP has been applied to two watersheds in Texas and one in Iowa. Predicted reductions in P losses for two P‐based manure application rate scenarios, relative to baseline conditions, ranged from ?4 to ?54 percent across the three watersheds; however, N loss impacts ranged from a decrease of 34 percent to an increase of 79 percent. For five other alternative scenarios that were simulated for only one watershed, N and P loss impacts ranged between a reduction of 78 percent to an increase of 20 percent. Aggregate watershed‐level economic impacts of the seven scenarios spanned a spectrum of a 27 percent decrease to a 25 percent increase in profit, relative to the baseline.     

Effect of manganese on the concentration of amino acids in different regions of the rat brain

The present study was designed to determine if chronic exposure of weanlings and adult rats to Mn produces significant alterations in amino acid concentrations in different regions of the rat brain. Weanling (30 day old) and adult (90 day old) male rats were exposed to 10 and 20 mg Mn/kg body weight per day, by gavage, for 30 days. Forty-eight hours after the last dose, animals were sacrificed by decapitation and brains were dissected into different regions to determine the concentration of amino acids by HPLC/EC. A dose dependent decrease in body weight gain was found in the adult, but not in the weanling rats. Significant increases occurred in concentrations of aspartate, glutamate, glutamine, taurine and gamma-aminobutyric acid (GABA) in the cerebellum of the adult rats dosed with 20 mg/kg per day, Mn. A significant decrease in the concentration of glutamine was observed in caudate nucleus and hippocampus of weanling rats dosed with 10 mg/kg, Mn. These data suggest that chronic Mn exposure can produce a decrease in body weight gain in adult rats and alterations in amino acids in different regions of weanling and adult rat brains.     

Investigation the effect of adding graphene oxide into diesel/higher alcohols blends on a diesel engine performance

ABSTRACT

This article aims to study the influence of the addition of graphene oxide nanoparticles (GO) to diesel/higher alcohols blends on the combustion, emission, and exergy parameters of a CI engine under various engine loads. The higher alcohols mainly n-butanol, n-heptanol, and n-octanol are blended with diesel at a volume fraction of 50%. Then, the 25 and 50 mg/L concentrations of GO are dispersed into diesel/higher alcohols blends using an ultrasonicator. The GO structures are examined using TEM, TGA, XRD and FTIR. The findings show that there is a reduction in p_max. and HRR when adding higher alcohols with diesel fuel. Regarding engine emission, there is a significant improvement in emissions formation with adding higher alcohols. The addition of GO into diesel/higher alcohols blends improves the brake thermal efficiency by 15%. Moreover, the p_max. and HRR are both enhanced by 4%. The CO, UHC and smoke formation are reduced considerably by 40%, 50 and 20%, respectively, while NO_x level is increased by 30% with adding GO. Finally, adding high percentages of n-butanol, n-heptanol, and n-octanol with diesel fuel with the presence of GO has the potential to achieve ultra-low CO, UHC, and smoke formation meanwhile keeping high thermal efficiency level.     

Seasonal variations of aerosol residence time in the lower atmospheric boundary layer

During a one year period, from Jan. 2002 up to Dec. 2002, approximately 130 air samples were analyzed to determine the atmospheric air activity concentrations of short- and long-lived (222Rn) decay products 214Pb and 210Pb. The samples were taken by using a single-filter technique and gamma-spectrometry was applied to determine the activity concentrations. A seasonal fluctuation in the concentration of 214Pb and 210Pb in surface air was observed. The activity concentrations of both radionuclides were observed to be relatively higher during the winter/autumn season than in spring/summer season. The mean activity concentration of 214Pb and 210Pb within the whole year was found to be 1.4+/-0.27 Bq m(-3) and 1.2+/-0.15 mBq m(-3), respectively. Different 210Pb:214Pb activity ratios during the year varied between 1.78 x 10(-4) and 1.6 x 10(-3) with a mean value of 8.9 x 10(-4) +/- 7.6 x 10(-5). From the ratio between the activity concentrations of the radon decay products 214Pb and 210Pb a mean residence time (MRT) of aerosol particles in the atmosphere of about 10.5+/-0.91 d could be estimated. The seasonal variation pattern shows relatively higher values of MRT in spring/summer season than in winter/autumn season. The MRT data together with relative humidity (RH), air temperature (T) and wind speed (WS), were used for a comprehensive regression analysis of its seasonal variation in the atmospheric air.     

WASTE WATER DISPOSAL THROUGH A COASTAL AQUIFER1

ABSTRACT: Feasibility of disposing treated sewage in wells sunk into a partially confined coastal limestone aquifer at Waimanalo in the island of Oahu was investigated using an electric analog model. Electric analog modeling was preferred over digital modeling because of ease with which tides could be generated at the ocean boundary in the form of sinusoidal waves. The results of model operation showed that high permeability, low storativity, and the presence of ocean render the Waimanalo aquifer highly suitable for the disposal of waste water in deep wells. Since the quality of water in the aquifer is already unsuitable for municipal, industrial, or agricultural use, waste water injection will not result in any loss of fresh water supply source to the island. It is also believed that the cost of waste water disposal through the aquifer will be considerably less than that through an ocean outfall. During model development it was discovered that electric analog models can help prepare certain graphs which can be useful for aquifer analysis without any further use of the model.