Faecal sterols as sewage markers in the Langat River, Malaysia: Integration of biomarker and multivariate statistical approaches

The Langat River in Malaysia has been experiencing anthropogenic input from urban, rural and industrial activities for many years. Sewage contamination, possibly originating from the greater than three million inhabitants of the Langat River Basin, were examined. Sediment samples from 22 stations (SL01-SL22) along the Langat River were collected, extracted and analysed by GC-MS. Six different sterols were identified and quantified. The highest sterol concentration was found at station SL02 (618.29 ng/g dry weight), which situated in the Balak River whereas the other sediment samples ranged between 11.60 and 446.52 ng/g dry weight. Sterol ratios were used to identify sources, occurrence and partitioning of faecal matter in sediments and majority of the ratios clearly demonstrated that sewage contamination was occurring at most stations in the Langat River. A multivariate statistical analysis was used in conjunction with a combination of biomarkers to better understand the data that clearly separated the compounds. Most sediments of the Langat River were found to contain low to mid-range sewage contamination with some containing `significant' levels of contamination. This is the first report on sewage pollution in the Langat River based on a combination of biomarker and multivariate statistical approaches that will establish a new standard for sewage detection using faecal sterols.     

Identification of naphthalene metabolism by white rot fungus Armillaria sp. F022

Armillaria sp. F022, a white rot fungus isolated from tropical rain forest (Samarinda, Indonesia) was used to biodegrade naphthalene in cultured medium. Transformation of naphthalene by Armillaria sp. F022 which is able to use naphthalene, a two ring-polycyclic aromatic hydrocarbon (PAH) as a source of carbon and energy was investigated. The metabolic pathway was elucidated by identifying metabolites, biotransformation studies and monitoring enzyme activities in cell-free extracts. The identification of metabolites suggests that Armillaria sp. F022 initiates its attack on naphthalene by dioxygenation at its C-1 and C-4 positions to give 1,4-naphthoquinone. The intermediate 2-hydroxybenzaldehyde and salicylic acid, and the characteristic of the meta-cleavage of the resulting diol were identified in the long-term incubation. A part from typical metabolites of naphthalene degradation known from mesophiles, benzoic acid was identified as the next intermediate for the naphthalene pathway of this Armillaria sp. F022. Neither phthalic acid, catechol and cis,cis-muconic acid metabolites were detected in culture extracts. Several enzymes (manganese peroxidase, lignin peroxidase, laccase, 1,2-dioxygenase and 2,3-dioxygenase) produced by Armillaria sp. F022 were detected during the incubation.     

Impact of climate change on cereal production: evidence from lower-middle-income countries

Environmental Science and Pollution Research - This study empirically examines the impact of climate change on cereal production in selected lower-middle-income countries with a balanced panel...     

Pesticide risk assessment: A study on inhalation and dermal exposure to 2,4-D and paraquat among Malaysian paddy farmers

A cross-section analytical study was conducted to evaluate the risk of pesticide exposure to those applying the Class II pesticides 2,4-D and paraquat in the paddy-growing areas of Kerian, Perak, Malaysia. It investigated the influence of weather on exposure as well as documented health problems commonly related to pesticide exposure. Potential inhalation and dermal exposure for 140 paddy farmers (handlers of pesticides) were assessed. Results showed that while temperature and humidity affected exposure, windspeed had the strongest impact on pesticide exposure via inhalation. However, the degree of exposure to both herbicides via inhalation was below the permissible exposure limits set by United States National Institute of Occupational Safety and Health (NIOSH). Dermal Exposure Assessment Method (DREAM) readings showed that dermal exposure with manual spraying ranged from moderate to high. With motorized sprayers, however, the level of dermal exposure ranged from low to moderate. Dermal exposure was significantly negatively correlated with the usage of protective clothing. Various types of deleterious health effects were detected among users of manual knapsack sprayers. Long-term spraying activities were positively correlated with increasing levels of the gamma-glutamyl transpeptidase (GGT) liver enzyme. The type of spraying equipment, usage of proper protective clothing and adherence to correct spraying practices were found to be the most important factors influencing the degree of pesticide exposure among those applying pesticides.     

Synthesis and anti-microbial activity of hydroxylammonium ionic liquids

Eight hydroxylammonium-based room temperature ionic liquids (ILs) have been synthesized by acid-base neutralization of ethanolamines with organic acids. The ILs were characterized by infrared and nuclear magnetic resonance spectroscopies and elemental analysis. Their anti-microbial activities were determined using the well-diffusion method. All eight ILs were toxic to Staphylococcus aureus, while 2-hydroxyethylammonium lactate and 2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium acetate showed high anti-microbial activity against a wide range of human pathogens.     

Drying of salted silver jewfish in a hybrid solar drying system and under open sun: Modeling and performance analyses

This study investigated the thin-layer drying kinetics of salted silver jewfish in a hybrid solar drying system and under open sun. Ten drying models were compared with experimental data of salted silver jewfish drying. A new model was introduced, which is an offset linear logarithmic (offset modified Page model). The fit quality of the models was evaluated using the coefficient of determination (R²), root mean square error (RMSE), and sum of squared absolute error (SSAE). The result showed that Midilli et al. model and new model were comparable with two or three-term exponential drying models. This study also analyzed energy and exergy during solar drying of salted silver jewfish. Energy analysis throughout the solar drying process was estimated on the basis of the first law of thermodynamics, whereas exergy analysis during solar drying was determined on the basis of the second law of thermodynamics. At an average solar radiation of 540 W/m² and a mass flow rate of 0.0778 kg/sec, the collector efficiency and drying system efficiency were about 41% and 23%, respectively. Specific energy consumption was 2.92 kWh/kg. Moreover, the exergy efficiency during solar drying process ranged from 17% to 44%, with an average value of 31%. The values of improvement potential varied between 106 and 436 W, with an average of 236 W.     

Performance of oil palm kernel shell gasification using a medium-scale downdraft gasifier

This article focused on the performance of oil palm kernel shell (PKS) gasification using a medium-scale downdraft gasifier with a feedstock capacity of 500 kg at a temperature range of 399–700°C and at a feed rate of 177 kg/h. This article is important for evaluating the reliability of PKS gasification for commercial power generation activities from biomass. The process performance was evaluated based on the syngas calorific value (CV), syngas flow rate, and its cold gas efficiency (CGE). The syngas flow rates and CVs were measured using a gas flow meter and a gas analyzer in real time. The data obtained were then analyzed to evaluate the performance of the process. The results showed that the CGE of the process was moderately high (51%) at 681°C, with a high syngas CV (4.45–4.89 MJ/Nm³) which was ideal for gas engine applications. The PKS gasification performance increased when the reactor temperature increased. Projections were made for the CGE and the syngas CV for the PKS gasification with increased reactor temperatures and it was found that these values could be increased up to 80% and 5.2 MJ/Nm^3, respectively at a reactor temperature of 900°C. In addition, the estimated power that could be generated was about 600 kW_e at a maximum operation of 500 kg/h of feed rate. Based on the analysis, a medium-scale PKS gasification is observed to be a promising process for power generation from biomass due to the favorable performance of the process.     

Source apportionment of surfactants in marine aerosols at different locations along the Malacca Straits

This study aims to determine the source apportionment of surfactants in marine aerosols at two selected stations along the Malacca Straits. The aerosol samples were collected using a high volume sampler equipped with an impactor to separate coarse- and fine-mode aerosols. The concentrations of surfactants, as methylene blue active substance and disulphine blue active substance, were analysed using colorimetric method. Ion chromatography was employed to determine the ionic compositions. Principal component analysis combined with multiple linear regression was used to identify and quantify the sources of atmospheric surfactants. The results showed that the surfactants in tropical coastal environments are actively generated from natural and anthropogenic origins. Sea spray (generated from sea-surface microlayers) was found to be a major contributor to surfactants in both aerosol sizes. Meanwhile, the anthropogenic sources (motor vehicles/biomass burning) were predominant contributors to atmospheric surfactants in fine-mode aerosols.