Airborne Emissions of Mercury from Municipal Solid Waste. II: Potential Losses of Airborne Mercury before Landfill

Abstract

Waste distribution and compaction at the working face of municipal waste landfills releases mercury vapor (Hg⁰) to the atmosphere, as does the flaring of landfill gas. Waste storage and processing before its addition to the landfill also has the potential to release Hg⁰ to the air if it is initially present or formed by chemical reduction of Hg^II to Hg⁰ within collected waste. We measured the release of Hg vapor to the atmosphere during dumpster and transfer station activities and waste storage before landfilling at a municipal landfill operation in central Florida. We also quantified the potential contribution of specific Hg-bearing wastes, including mercury (Hg) thermometers and fluorescent bulbs, and searched for primary Hg sources in sorted wastes at three different landfills. Surprisingly large fluxes were estimated for Hg losses at transfer facilities (～100 mg/hr) and from dumpsters in the field (～30 mg/hr for 1,000 dumpsters), suggesting that Hg emissions occurring before landfilling may constitute a significant fraction of the total emission from the disposal/landfill cycle and a need for more measurements on these sources. Reducing conditions of landfill burial were obviously not needed to generate strong Hg⁰ signals, indicating that much of the Hg was already present in a metallic (Hg⁰) form. Attempts to identify specific Hg sources in excavated and sorted waste indicated few readily identifiable sources; because of effective mixing and diffusion of Hg⁰, the entire waste mass acts as a source. Broken fluorescent bulbs and thermometers in dumpsters emitted Hg⁰ at 10 to >100 μg/hr and continued to act as near constant sources for several days.     

Climate, icing, and wild arctic reindeer: past relationships and future prospects

Across the Arctic, heavy rain-on-snow (ROS) is an "extreme" climatic event that is expected to become increasingly frequent with global warming. This has potentially large ecosystem implications through changes in snowpack properties and ground-icing, which can block the access to herbivores' winter food and thereby suppress their population growth rates. However, the supporting empirical evidence for this is still limited. We monitored late winter snowpack properties to examine the causes and consequences of ground-icing in a Svalbard reindeer (Rangifer tarandus platyrhynchus) metapopulation. In this high-arctic area, heavy ROS occurred annually, and ground-ice covered from 25% to 96% of low-altitude habitat in the sampling period (2000-2010). The extent of ground-icing increased with the annual number of days with heavy ROS (> or = 10 mm) and had a strong negative effect on reindeer population growth rates. Our results have important implications as a downscaled climate projection (2021-2050) suggests a substantial future increase in ROS and icing. The present study is the first to demonstrate empirically that warmer and wetter winter climate influences large herbivore population dynamics by generating ice-locked pastures. This may serve as an early warning of the importance of changes in winter climate and extreme weather events in arctic ecosystems.     

Recycling of synthetic waste wig fiber in the production of cement-adobe for building envelope: physio-hydric properties

Environmental Science and Pollution Research - Waste wigs are often disposed off in their volume on landfills, thus constituting a nuisance to the environment. Recycling these wigs in masonry...     

Infill McMansions: Style and the psychophysics of size

The number and size of infill oversized houses, or McMansions, has increased in the U.S. and the world. To maintain desirable neighborhood appearances, communities should know what constitutes “too big.” This paper reports six studies that used color simulations of blocks of houses to examine compatibility and visual appeal in relation to attributes of the infill house and its context. Following psychophysical findings, the relative size of the infill house should have larger effects on response than its actual size. The studies confirmed that the infill ratio had more weight than size for perceived compatibility. Compatibility did not always translate into visual appeal. For visual appeal, infill style had larger effects than did size or size ratio, height had larger effects than width, and, for larger sizes and ratios, infill ratio had larger effects than actual size. To maintain visual quality in relation to infill houses, communities should first seek an architecturally compatible style, and then try to control its relative size (the infill façade area). Tests of responses to real infill houses can show how well these findings generalize.     

Boomerangs versus Javelins: How Polarization Constrains Communication on Climate Change

Political communicators work under the assumption that information provision, such as framing, may influence audiences and elicit some desired attitudinal or behavioral shift. However, some political issues, such as climate change, have become polarized along party lines, with partisans seemingly impervious to disconfirming information. On these highly polarized issues, can framing sway partisans to moderate their positions, or are partisans so motivated in their issue stances that framing fails? Using a variety of vignettes, and Republican climate change skepticism as a case, this article reports an experiment of how partisans respond to counter-attitudinal framing on a sharply polarized issue. Results indicate that Republicans are resistant to frames that encourage support of governmental action or personal engagement against climate change. There is strong evidence of motivated skepticism, given widespread backfire (or ‘boomerang’) effects and decreased attitudinal ambivalence following exposure to framing, suggesting that issue polarization may severely constrain attempts at communication.     

Simultaneous DOAS and mist-chamber IC measurements of HONO in Houston,TX

Nitrous acid is an important component of nighttime N-oxide chemistry, and provides a significant source of both OH and NO in polluted urban air masses shortly after sunrise. Several recent studies have called for new sources of HONO to account for daytime levels much higher than are consistent with current understanding. However, measurement of HONO is problematic, with most in-situ techniques reporting higher values than simultaneous optical measurements by long-path DOAS, especially during daytime. The discrepancy has been attributed to positive interference in the in-situ techniques, negative interference in DOAS retrievals, the difficulty of comparing the different air masses sampled by the methods, or combinations of these.During August and September 2006, HONO mixing ratios from collocated long-path DOAS and automated mist-chamber/ion chromatograph (MC/IC) systems ranged from several ppbv during morning rush hour to daytime minima near 100 pptv. Agreement between the two techniques was excellent across this entire range during many days, showing that both instruments accurately measured HONO during this campaign. A small bias towards higher LP-DOAS observations at night can be attributed to slow vertical mixing leading to pronounced HONO profiles. A positive daytime bias of the MC/IC instrument during several days in late August/early September was correlated with photochemically produced compounds such as ozone, HNO₃ and HCHO, but not with NO₂, NO_x, HO₂NO₂, or the NO₂ photolysis rate. While an interferant could not be identified organic nitrites appear a possible explanation for our observations.     

Respiratory Responses of Exercising Asthmatic Volunteers Exposed to Sulfuric Acid Aerosol

Young asthmatic adult volunteers (N = 27) were exposed in an environmental chamber to sulfuric acid aerosol at concentrations near 0, 122, 242, and 410 μg/m³, in purified background air at 22° C and 50 percent relative humidity. The polydisperse aerosol had a mass median aerodynamic diameter near 0.6 μm. Exposures occurred in random order at one-week intervals. Each lasted 1 h, during which subjects exercised (mean ventilation 42 L/min) and rested during alternate 10-min periods. Specific airway resistance and forced expiratory function were measured pre-exposure, after the initial exercise, and at end-exposure. Bronchial reactivity was determined by challenge with cold air immediately post-exposure. Symptoms were monitored during exposure for one week afterward. Exercise-induced bronchospasm was observed under all conditions. Physiologic and symptom changes possibly attributable to sulfuric acid exposure were small and not statistically significant. Our largely negative results contrast with positive findings elsewhere at lower acid doses. Possible explanations include different clinical characteristics of subjects and different routes of breathing.     

Visual preferences of elderly public housing residents: Residential street scenes

Multiple regression predictors related judged visual attributes of housing exteriors to evaluative responses by elderly persons living in public housing in two different cities. In one city, the safety and composite preference evaluations of the 30 neighborhoods portrayed in photographs were found inversely related to both the dilapidation and diversity of the street scenes. In the other city the same evaluations were found related to the dullness and openness of the street scenes. In both cases, the responses predicted by the multiple regression equations for the sample in one city showed significant correlations with the obtained evaluative responses by the sample in the other city. However, the equations with dilapidation and diversity were the better predictors.