Biosorption of Cu(II) and Zn(II) onto a lignocellulosic substrate extracted from wheat bran

We studied the removal of copper and zinc ions from aqueous solutions using a lignocellulosic substrate obtained by an acido-basic treatment of wheat bran. The sorption capacity of this material was investigated through batch and column experiments. Batch experimental results showed that the retention capacity of the lignocellulosic substrate was 0.20×10^–3 mol g^–1 at pH 4.5 for copper(II) and 0.24×10^–3 mol g^–1 at pH 6.5 for zinc(II). Column experiments showed a reduced sorption capacity for both ions compared to batch experiments. Batch and column data were analysed using the Langmuir equation in order to determine the affinity constant and the binding capacity of the sorbent and to compare both retention processes.     

The use of magnetic resonance imaging in the prediction of birthweight

Extremes of fetal growth can increase adverse pregnancy outcomes, and this is equally applicable to single and multiple gestations. Traditionally, these cases have been identified using simple two-dimensional ultrasound which is quite limited by its low precision. Magnetic resonance imaging (MRI) has now been used for many years in obstetrics, mainly as an adjunct to ultrasound for congenital abnormalities and increasingly as part of the post-mortem examination. However, MRI can also be used to accurately assess fetal weight as first demonstrated by Baker et al in 1994, using body volumes rather than standard biometric measurements. This publication was followed by several others, all of which confirmed the superiority of MRI; however, despite this initial promise, the technique has never been successfully integrated into clinical practice. In this review, we provide an overview of the literature, detail the various techniques and formulas currently available, discuss the applicability to specific high-risk groups and present our vision for the future of MRI within clinical obstetrics.     

EFFECTS OF THE TOPOGRAPHIC INDEX DISTRIBUTION ON PREDICTED RUNOFF USING GRASS1

ABSTRACT: The effects of digital elevation model resolutions and contour lengths on the distribution of the topographic index, a fundamental parameter for the hydrologic model, TOPMODEL, and their influence on the predicted peak flows are investigated in this paper. A small agricultural catchment (3.38 km²) is used to determine the catchment response modeled by TOPMODEL for three rainfall events.     

Herbaceous Covers to Control Tree Invasion in Rights-of-Way: Ecological Concepts and Applications

In northeastern America, thousands of kilometers of utility rights-of-way (ROWs) have to be managed to prevent the establishment of a tall vegetation cover that does not comply with safety and maintenance regulations. Recent decades have seen the emergence of ecologically based vegetation control strategies to reduce environmental impacts as well as maintenance costs. One such strategy is to take advantage of competitive herbaceous covers to limit tree invasion. This approach, however, as well as its fundamental underlying principles, has been little scrutinized. In this article, (1) we present the main ecological concepts supporting the use of a herbaceous cover to limit tree invasion, emphasizing naturally forested ecosystems of northeastern America. They include reported evidence of stable plant communities and an overview of potential underlying mechanisms of inhibition. (2) We then review field applications, specifically testing the ability of seeded herbaceous covers to control tree invasion in ROWs. (3) We discuss unresolved issues relevant to management and research. The available evidence suggests that seeding herbaceous covers in ROWs can help control tree invasion, but many issues still limit broad-scale applications. The various interactions that govern plant community dynamics are far from being fully understood, so selecting species still largely depends on an empirical approach. Patterns of resistance to tree invasion must be investigated over a wide range of spatial, historical, and environmental contexts to determine effective management and seeding practices that will lead to broad-scale applications. We suggest establishing communities rather than single dominant species and using as much as possible native species to limit risks of invasion.Published online     

Sorption of selenium anionic species on apatites and iron oxides from aqueous solutions

The sorption of selenite and selenate ions from aqueous solutions was investigated on hydroxyapatite, fluorapatite, goethite and hematite, in order to simulate the behavior of radioactive selenium in natural or artificial sorbing media. Correlation studies with acido-basic properties and solubility of the solids were also performed. The sorption is pH dependant, but these solids are very efficient for retaining selenite at pH values generally encountered in natural waters, with however higher K(d) values for oxides than apatites. Selenate ions are much less sorbed than selenite. Several methods such as electron microscopy and spectroscopic techniques were used to identify the sorption mechanisms. In the case of hydroxyapatite, sorption proceeds by substitution of phosphate groups in the lattice of the apatite crystal in the superficial layers of the solid. In the case of goethite and hematite, sorption can be interpreted and modeled by a surface complexation process, but there is a discrepancy between sorption site densities for selenite and for protons.     

Hedgerows and hedgerow networks in landscape ecology

Hedgerows originated and coexist with agriculture. Their internal structure and species diversity vary widely with origin (planted, spontaneous, or remnant), farming practices in adjacent fields, and the refined art of hedgerow management. Most hedgerow species are forest-edge species, and apparently none is limited to hedgerows. Wide hedgerows composed of trees and shrubs appear to function as corridors for movement of many plants and animals across a landscape. The reduction of crop loss, by dampening pest population fluctuations with hedgerow predators, remains a hypothesis for study.Field microclimate downwind of a hedgerow is modified about 16 times the hedgerow height (h) for evaporation, and approximately 28 h for wind speed. A turbulent wind pattern with harsher microclimate is present at 6–8 h if a second hedgerow is nearby downwind. Zones of higher crop productivity at 3- to 6-h downwind, and 2- to 6-h upwind of a second hedgerow may be expected. Overall, we expect little short-term difference in farm-field production with or without hedgerows.Evidence suggests that hedgerow networks, and especially their mesh size (of fields), exert a major control on many major landscape fluxes. Such fluxes include animal populations, wind speed, evapotranspiration and soil desiccation, soil erosion and nutrient runoff, species movement along network lines, and movement of field species across the network. In a relatively short period, the hedgerow ecosystem, with no unique species, has attained a metastable equilibrium, which is regulated by enormous human inputs.More than 20 economic roles of hedgerows are pinpointed. The roles, providing resources and protection of resources, are poorly known quantitatively. We conclude that hedgerows perform diverse functions for society and the farmer that are both economically and ecologically significant.     

RUNOFF AND SEDIMENT RESPONSES TO CONSERVATION PRACTICES: LOESS PLATEAU OF CHINA1

ABSTRACT: Soil erosion is the most significant threat to land productivity and environmental quality on the Loess Plateau of China. The annual total sediment load of the Yellow River is 1.6 billion tons, with about 90 percent coming from soil erosion from the Loess Plateau. To reduce soil erosion from the Loess Plateau, conservation practices, including tree planting, ridge construction between fields and around gullies, terrace and ditch construction perpendicular to the main slope, and dam construction are being implemented. An evaluation of these conservation practices is required before they are implemented at the large scale. The objective of this study is to evaluate the effectiveness of conservation practices to control runoff and sediment yield from paired watersheds in the hilly gully region of the Loess Plateau. The advantage of the paired watershed approach is its sensibility in detecting differences in runoff and sediment transport by monitoring both watersheds during two periods, an initial period with no conservation practices and a treatment period with only one watershed subjected to conservation practices. Implementation of the conservation practices resulted in (1) cumulative runoff and sediment yield that were, respectively, 25 and 38 percent less from the treatment watershed than from the control, (2) a decrease in the number of rainfall events producing runoff and sediment transport (94 in the control versus 63 in treatment), and (3) a reduction in the maximum discharge and maximum suspended sediment concentration.