Surface chemistry of a pine-oil cleaner and other terpene mixtures with ozone on vinyl flooring tiles

Indoor environments are dynamic reactors where consumer products (such as cleaning agents, deodorants, and air fresheners) emit volatile organic compounds (VOCs) that can subsequently interact with indoor oxidants such as ozone (O₃), hydroxyl radicals, and nitrate radicals. Typically, consumer products consist of mixtures of VOCs and semi-VOCs which can react in the gas-phase or on surfaces with these oxidants to generate a variety of oxygenated products. In this study, the reaction of a pine-oil cleaner (POC) with O₃ (100 ppb) on a urethane-coated vinyl flooring tile was investigated at 5% and 50% relative humidity. These results were compared to previous α-terpineol + O₃ reactions on glass and vinyl surfaces. Additionally, other terpene and terpene alcohol mixtures were formulated to understand the emission profiles as seen in the POC data. Results showed that the α-terpineol + O₃ reaction products were the prominent species that were also observed in the POC/O₃ surface experiments. Furthermore, α-terpineol + O₃ reactions generate the largest fraction of oxygenated products even in equal mixtures of other terpene alcohols. This finding suggests that the judicial choice of terpene alcohols for inclusion in product formulations may be useful in reducing oxidation product emissions.     

The definition of species richness used by species sensitivity distributions approximates observed effects of salinity on stream macroinvertebrates

The risk of chemicals for ecological communities is often forecast with species sensitivity distributions (SSDs) which are used to predict the concentration which will protect p% of species (PC_p value). However, at the PC_p value, species richness in nature would not necessary be p% less than at uncontaminated sites. The definition of species richness inherent to SSDs (contaminant category richness) contrasts with species richness typically measured in most field studies (point richness). We determine, for salinity in eastern Australia, whether these definitions of stream macroinvertebrate species richness are commensurable. There were strong relationships (r² ≥ 0.87) between mean point species, family and Ephemeroptera, Trichoptera and Plecoptera species richness and their respective contamination category richness. Despite differences in the definition of richness used by SSDs and field biomonitoring, their results in terms of relative species loss from salinity in south-east Australia are similar. We conclude that in our system both definitions are commensurable.     

Enhanced removal of heavy metals in primary treatment using coagulation and flocculation.

The goal of this study was to determine the removal efficiencies of chromium, copper, lead, nickel, and zinc from raw wastewater by chemically enhanced primary treatment (CEPT) and to attain a total suspended solids removal goal of 80%. Operating parameters and chemical doses were optimized by bench-scale tests. Locally obtained raw wastewater samples were spiked with heavy metal solutions to obtain representative concentrations of metals in wastewater. Jar tests were conducted to compare the metals removal efficiencies of the chemical treatment options using ferric chloride, alum, and anionic polymer. The results obtained were compared with those from other studies. It was concluded that CEPT using ferric chloride and anionic polymer is more effective than CEPT using alum for metals removal. The CEPT dosing of 40 mg/L ferric chloride and 0.5 mg/L polymer enhanced heavy metals removal efficiencies by over 200% for chromium, copper, zinc, and nickel and 475% for lead, compared with traditional primary treatment. Efficient metals capture during CEPT can result in increased allowable headworks loadings or lower metal levels in the outfall.     

Use of SWAT to Estimate Spatial Scaling of Phosphorus Export Coefficients and Load Reductions Due to Agricultural BMPS

Phosphorus export coefficients (kg/ha/yr) from selected land covers, also called phosphorus yields, tend to get smaller as contributing areas get larger because some of the phosphorus mobilized on local fields gets trapped during transport to regional watershed outlets. Phosphorus traps include floodplains, wetlands, and lakes, which can then become impaired by eutrophication. The Sunrise River watershed in east central Minnesota, United States, has numerous lakes impaired by excess phosphorus. The Sunrise is tributary to the St. Croix River, whose much larger watershed is terminated by Lake St. Croix, also impaired by excess phosphorus. To support management of these impairments at both local and regional scales, a Soil and Water Assessment Tool (SWAT) model of the Sunrise watershed was constructed to estimate load reductions due to selected best management practices (BMPs) and to determine how phosphorus export coefficients scaled with contributing area. In this study, agricultural BMPs, including vegetated filter strips, grassed waterways, and reduction of soil‐phosphorus concentrations reduced phosphorus loads by 4‐20%, with similar percentage reductions at field and watershed spatial scales. Phosphorus export coefficients from cropland in rotation with corn, soybeans, and alfalfa decreased as a negative power function of contributing area, from an average of 2.12 kg/ha/yr at the upland field scale (~0.6 km²) to 0.63 kg/ha/yr at the major river basin scale (20,000 km²). Editor's note : This paper is part of the featured series on SWAT Applications for Emerging Hydrologic and Water Quality Challenges. See the February 2017 issue for the introduction and background to the series.     

Hydrologic Landscape Classification to Estimate Bristol Bay,Alaska Watershed Hydrology

Hydrologic landscapes (HLs) have proven to be a useful tool for broad scale assessment and classification of landscapes across the United States as they help organize larger geographical areas into areas of similar hydrologic characteristics. We developed a HL classification for the Bristol Bay watershed of southwest Alaska that incorporates indices of annual climate and seasonality, terrain, geology, and the influences of large lakes and glaciers. A HL classification is particularly useful in this large watershed because of its hydrologic and landscape variability, important salmon fishery, variety of environmental and potential anthropogenic stressors, and lack of widespread hydrologic data. Following creation of Bristol Bay basin‐wide HL classes, we compared the HL distributions within watersheds grouped by two calculated runoff parameters derived from available long‐term streamflow records and found HL distributions within these groups provided predictive insight on hydrologic behavior. Using these developed runoff groups, we estimated expected hydrologic behavior in watersheds across the larger Bristol Bay watershed that lacked gauged streamflow records. The HL approach provides a scientific basis for estimating the first‐order hydrologic behavior of watersheds and landscapes that lack detailed hydrologic information.     

Evaluation of unmitigated options for municipal waste disposal site in Tehran,Iran using an integrated assessment approach

It can be difficult for assessors and decision-makers to compare different options for a project, and thus come to a reasoned and objective decision concerning the impacts and its sustainability at the local level. Therefore, using integrated assessment becomes crucially important for evaluating proposed different options. In this paper, we apply the Rapid Integrated Sustainability Assessment Method (RISAM) to evaluate the proposed unmitigated options for a municipal waste disposal site in Tehran, Iran. The results obtained showed that all of the alternative unmitigated options to the current method of open dumping were indicated as being consistent with very weak sustainability. The RISAM method demonstrated offers potential considerable benefits with respect to improved efficiency, reduced need for resources, and improved consistency and transparency in evaluation and reporting.     

Using a Multi-Component Indicator Toward Reducing Phytoplankton Bloom Occurrences in the Swan River Estuary

The Swan River estuary is an icon of the city of Perth, Western Australia, running through the city centre and dividing the northern from the southern part of the city. However, frequent phytoplankton blooms have been observed in the estuary as a result of eutrophication. The Index of Sustainable Functionality (ISF), a composite index able to indicate for sustainable health of the estuary, was applied, taking into account the hydrology and highly seasonal nature of the estuary to inform the management of the estuary, towards the aim of reducing bloom occurrences. The study period was from the beginning of intensive monitoring in 1995 to mid-2009. The results emphasize the importance of physical controls on the ecology of the estuary. No significant trend in the estuary's low functionality was found, indicating that despite extensive restoration efforts, the frequency of algal bloom occurrences has remained relatively stationary and other mitigating factors have maintained an annual average ISF value at around 70 % functionality. We identified that the low flow season consistently performs the worst, with (high) temperature found as the most dominant variable for phytoplankton growth and bloom. Thus in managing the estuary, vigilance is required during periods of high temperature and low flow. Focusing on the risk of phytoplankton bloom, a nutrient reduction program that is in place is a long term solution due to high concentrations in the estuary. Other management measures need to be considered and adopted to effectively reduce the occurrences of future phytoplankton blooms.     

Aseptic hydroponics to assess rhamnolipid-Cd and rhamnolipid-Zn bioavailability for sunflower (<Emphasis Type="Italic">Helianthus annuus</Emphasis>): a phytoextraction mechanism study

The availability of cadmium (Cd) and zinc (Zn) to sunflower (Helianthus annuus) was investigated in rhamnolipid- and ethylenediaminetetraacetic acid (EDTA)-buffered solutions in order to evaluate the influence of aqueous speciation of the metals on their uptake by the plant, in relation to predictions of uptake by the free ion activity model (FIAM). Free metal ion activity was estimated using the chemical equilibrium program MINTEQ or measured by Donnan dialysis. The uptake of Cd followed the FIAM for the EDTA-buffered solution at EDTA concentrations below 0.4 μM; for the rhamnolipid-buffered solution, the uptake of both metals in roots was not markedly affected by increasing rhamnolipid concentrations in solution. This suggests rhamnolipid enhanced metal accumulation in plant roots (per unit free metal in solution) possibly through formation and uptake of lipophilic complexes. The addition of normal Ca concentrations (low millimetre range) to the rhamnolipid uptake solutions reduced Cd accumulation in shoots by inhibiting Cd translocation, whereas it significantly increased Zn accumulation in shoots. This study confirms that although rhamnolipid could enhance accumulation of Cd in plants roots at low Ca supply, it is not suitable for Cd phytoextraction in contaminated soil environments where Ca concentrations in soil solution are orders of magnitude greater than those of Cd.