Optimisation of zeolite LTA synthesis from alum sludge and the influence of the sludge source

Generation of alum sludge (AS) at drinking water treatment plants represents an environmental liability and adds to the cost of water purification. Consequently, this study explored the feasibility of using low and high carbon containing alum sludge from two water treatment plants to synthesize zeolite LTA. The hypothesis was that zeolite LTA synthesis was dependant upon alum sludge source and that a range of strategies may be required to optimize zeolite crystallinity. Zeolite characteristics such as morphology, phase composition, crystallinity, and particle size distribution were recorded. “One pot” hydrothermal synthesis of precursor gel with molar composition 4.2Na₂O:Al₂O₃:1.2SiO₂:168H₂O at 80°C for 3 hr resulted in 25 and 46 wt.% zeolite LTA from high and low carbonaceous sludge, respectively. Prior to hydrothermal reaction stage it was discovered that ageing of the gel, addition of zeolite LTA seeds, ultrasonic treatment and calcination all promoted zeolite LTA formation. Calcination of the alum sludge at 700°C for 2 hr before hydrothermal synthesis resulted in particle size reduction and the highest amount of crystalline zeolite LTA: 79 wt.% from low carbon sludge and 65 wt.% from high carbon sludge. Notably, the zeolite crystallinity reported in this study was the higher than previous studies on this topic. The outlined approach may allow value adding of alum waste and produce a commodity which could be used locally by the water treatment plant as a water softener.     

Effect of Ca:Mg ratio and high ammoniacal nitrogen on characteristics of struvite precipitated from waste activated sludge digester effluent

This study revealed the relationship between the presence of calcium impurities and ammoniacal nitrogen concentration upon crystallization of struvite. The research hypothesis was that the presence of both calcium and high concentrations of ammoniacal nitrogen(328–1000 mg/L) in waste activated sludge may influence the struvite quality and acid stability. Hence, we studied the impact of Ca:Mg ratio upon morphology, particle size, purity and dissolution of struvite, in the presence of varying levels of excess ammoniacal nitrogen. X-ray diffraction revealed that up to 31.4%amorphous material was made which was assigned to hydroxyapatite. Increasing the ammoniacal nitrogen concentration and elevation of the Mg:Ca ratio maximized the presence of struvite. Struvite particle size was also increased by ammoniacal nitrogen as was twinning of the crystals. Tests with dilute solutions of organic acid revealed the sensitivity of struvite dissolution to the physical characteristics of the struvite. Smaller particles(21.2 μm) dissolved at higher rates than larger particles(35.86 μm). However,struvite dissolved rapidly as the p H was further reduced irrespective of the physical characteristics. Therefore, addition of struvite to low p H soils was not viewed as beneficial in terms of controlled nutrient release. Overall, this study revealed that waste activated sludge effluent with high ammoniacal nitrogen was prospective for synthesis of high quality struvite material.     

Dynamic model for a heat exchanger tube rupture discharging a high-pressure flashing liquid into a low-pressure liquid-filled shell

Shell-tube type heat exchangers are often used to exchange heat between a high-pressure fluid and a low-pressure fluid. The pressure difference between these two fluids could be significantly high. In the event of a partial or full rupture of a tube, a problem may arise in that a transient pressure rise phenomenon could occur due to the flashing of the high-pressure sub-cooled fluid in the tube into the low-pressure shell, which may cause the shell to rupture with subsequent damage to equipment. This paper presents a dynamic model to describe the transient phenomenon occurring on the shell side following various scenarios of tube rupture. The spatial and temporal aspects of the flow transients along the pressure safety valve riser are accounted for by solving the one-dimensional continuity and momentum hyperbolic partial differential equations as applied to the liquid-filled riser. The dynamics of the attached piping system are also accounted for via two mechanistic models; the first is based on an inertial-resistive assumption of the fluids in this system, while the other is based on the assumption of anechoic perturbations passing through a long section of the attached piping. The latter is justified in cases where the attached piping is long enough such that reflections from the downstream end do not interfere with transients occurring in the shell during the initial phase of fluid flashing into the shell side following rupture. The various phases of this phenomenon are described, however the paper focuses on the initial phase of the phenomenon during which shell overpressure may be encountered. The model is applied to two ethylene heaters in tandem; the first uses propylene on the shell side to heat the ethylene on the tube side, while the second uses methanol, also on the shell side. The ratio between the shell design pressure to the tube design pressure in these two heaters are 0.169 and 0.154, respectively, hence the motivation to accurately model the transients involved in this phenomenon. The practical aspects and discussion around techniques to alleviate potential overpressure scenarios due to tube rupture are emphasized throughout the paper.     

Effects of combining an intraguild predator with a cannibalistic intermediate predator on a species-level trophic cascade

A greater diversity of natural enemies can in some cases disrupt prey suppression, particularly when natural enemies engage in intraguild predation, where natural enemies compete with and prey upon each other. However, empirical studies have often demonstrated enhanced prey suppression despite intraguild predation. A recent theoretical study proposed the hypothesis that, when the intermediate predator is cannibalistic, intraguild predation can reduce cannibalism within the intermediate predator population, leading to little change in intermediate predator mortality and thus enhanced prey suppression. The goal of this study was to examine this hypothesis empirically. Two summer-long field enclosure experiments were conducted in cotton fields. We investigated the effects of adding an intraguild predator, Zelus renardii, on (1) the abundance of a cannibalistic intermediate predator, Geocoris pallens, (2) the abundance of a herbivore, Lygus hesperus, and (3) cotton plant performance. G. pallens adult abundance did not increase, even when food availability was high and natural enemies were absent, suggesting that density-dependent cannibalism imposes an upper limit on its densities. Furthermore, although Z. renardii is an intraguild predator of G. pallens, G. pallens long-term densities were unaffected by Z. renardii. In the presence of the intermediate predator, the addition of the intraguild predator Z. renardii enhanced suppression of L. hesperus, and there were suggestions that Z. renardii and G. pallens partitioned the L. hesperus population. Effects of herbivore suppression cascaded to the plant level, improving plant performance. In conclusion, we provide empirical support for the hypothesis that the addition of an intraguild predator may enhance prey suppression if the intermediate predator expresses density-dependent cannibalism. Intraguild predation and cannibalism co-occur in many communities; thus their joint effects may be broadly important in shaping predator effects on herbivores and plant performance.     

Agricultural nitrogen model: A tool for regional environmental management

A detailed nitrogen budget was devised for agricultural activities in the Florida peninsula, based on routine data published by state agricultural agencies. The model demonstrates that important unmonitored fluxes of nitrogen can often be calculated by mass balance on individual model compartments, and that the reasonability of poorly quantified fluxes can be assessed. The results of such models can be very useful in designing and assessing the results of field experiments and in prioritizing environmental monitoring programs.     

Institutional dynamics and climate change adaptation in South Africa

Climate change is a multi-dimensional issue and in terms of adaptation numerous state and non-state actors are involved from global to national and local scales. The aim of this paper is first to analyse specific institutional networks involved in climate change predominantly at the national level in South Africa and second to determine how different stakeholders perceive their role vis-a-vis climate change adaptation. Within the South African context there is a gap in understanding and evaluating how institutional networks operate and thus the findings of this work may help inform and strengthen such relationships in the future. Results showed that few institutions fully understand the implications of adaptation and their roles and responsibilities have not yet been properly defined. Constraints relating to capacity, lack of awareness and poor information flow need to be addressed. Climate change is perceived as an important issue although problems such as poverty reduction and job creation remain national priorities. Most importantly this research has demonstrated how adaptation challenges the hierarchical manner in which government works and a more collaborative approach to climate change adaptation is needed. Adaptation needs to be mainstreamed and institutional networks need to be strengthened in order for adaptation mechanisms to be effectively implemented.

A critical review on different roughness geometries and their effect on heat transfer and friction factor

Solar air heater (SAH) is simple and the greatest effective approach to utilize and convert solar energy into thermal energy for heating utilizations. The employment of artificial roughness under side of the observer surface is the key technique for augmenting heat transfer with minimal friction factor penalty. Current paper summarized different kinds of artificial roughness used in SAH, which augments its performance. In this review article, 96 research papers are cited, which provide detailed information about the effect of different geometrical parameters on heat transfer and friction factor. This paper also brings the information about the optimum roughness parameters and heat transfer and friction factor correlation developed by different investigators in tabular form. Optimum roughness parameters and empirical correlations are used for comparative analysis of heat transfer, friction factor, and thermo-hydraulic performance parameter (THPP) of different roughness geometries. The best performing roughness geometry is reported on the basis of comparative analysis. Mathematical model is developed for predicting the thermal efficiency (η_th) of roughened SAH duct.

     

Formation and destruction of PCDD/F inside a grate furnace

Formation and destruction of polychlorinated dibenzo-p-dioxins and dibenzofurans PCDD/F during the combustion process was investigated experimentally in a pilot plant. All important process steps like the burnout of the fuel bed on the grate, the burnout of the flue gas inside the combustion chamber, the heat recovery in a boiler as well as influences of the fuel composition are described in detail.

High concentrations especially of PCDF are formed during the burnout of the fuel bed. The formation reaction is mainly influenced by the fuel composition and the burnout characteristic of the fuel bed. Fuels with low chlorine and low metal content (Cu) result only in negligible concentrations of PCDD/F.

Under stable combustion conditions characterized by an excellent flue gas burnout PCDD/F will almost be completely destroyed already inside the combustion chamber. “Cold strands” of unburned flue gas (high CO concentrations) caused by disturbed combustion conditions will result in high concentrations of PCDD and especially of PCDF in the raw gas.

A second place of PCDD/F formation is the well-known boiler section. Here fly ash deposits containing residual carbon (mainly soot particles) are the source for the formation reaction. Under stationary effective combustion conditions, they are dominant for PCDD/F concentrations in the raw gas over a very long period of time.

Stationary efficient flue gas burnout (especially soot) together with effective boiler cleaning will guaranty low concentrations of PCDD/F in the flue gas in front of the flue gas cleaning system.