Experimental evaluation of emission factors of cement kilns burning hazardous wastes

Cement industry is an interesting way to eliminate combustible wastes. Thermal valorization is maximal, conditions of combustion are especially favorable to the destruction and the trapping of pollutants, and there are neither ultimate residues (slag) nor aqueous rejects. Moreover the properties of the cement are not modified. Nevertheless the increased use of substitution fuel may lead to deal with unusual amounts of heavy metals. Tests were realized on several rotary cement kilns with varying substitution ratios of fossil fuels by wastes. Mass balances were fitted over the whole plant, and emission factors were explained.     

A new hypothesis concerning the nature of small pelagic fish clusters: An individual-based modelling study of Sardinella aurita dynamics off West Africa

Coastal populations of small pelagic fish display nested aggregation levels. Above the level of the school structure, clusters are observed the nature of which has not been definitively determined. We hypothesized that these clusters corresponded to a materialisation of the microcohorts originating from successive spawnings of fish populations in their vital domain.A candidate individual-based model was developed to investigate this hypothesis. This model is based on pattern-oriented modelling of a concrete documented case: the dynamics of the round sardinella (Sardinella aurita) population living off the West African coasts and subject to environmental fluctuations caused by seasonal upwelling. The simulated agents were round sardinella microcohorts situated and moving in a discretised physical environment. The combined effects of environmental forcing (temperature, wind, retention) and inner biological dynamics (reproduction, growth and mortality, competition) condition the dynamics of this population.The modelled behaviour generated realistic dynamic patterns (population distribution, spawning zones, periods and plasticity, biomass fluctuations), which were obtained simultaneously and successfully compared with observations. The steady-state number of microcohorts obtained after simulation convergence was similar to the number of clusters observed in situ in this area for this population.The realism and diversity of the patterns simultaneously simulated suggested the cluster-microcohort equivalence hypothesis as a candidate framework accounting for the origin of the clusters observed in situ. Within this preliminary exploration, we discuss the consistency of the hypothesis and the accuracy of the model. If the correspondence between clusters and microcohorts proves to be real, it may be transient and progressively modified by other environmental factors. If stable over time, as simulated in the model, the number of observed clusters should be related to the number of spawning events in the species’ lifetime.     

Biodiversity of brackish water amphipods (crustacean) in two estuaries, southeast coast of India

The present study about the gammarid amphipods of Vellar and Uppanar estuaries was performed during two seasons (pre-monsoon and post-monsoon, 2005–2006), respectively, in nine habitats: five in the Vellar estuary and four in the Uppanar estuary. Amphipod samples were collected from sediments, oyster beds, seaweeds, sea grass, and mangroves. A total of 29 species of gammarid amphipods were collected in each area. The surface water temperature ranged from 16°C to 26°C, the salinity from 20 to 32 psu, and the pH between 7.5 and 8.3. Dissolved oxygen ranged from 5.3 to 7.8 ml/l. The maximum abundance of amphipods was observed during the pre-monsoon (July to September) in Vellar mangrove, and it was minimum during the pre-monsoon in Uppanar sea grass. It was found that several physicochemical factors, such as salinity, temperature, dissolved oxygen, pH, and the substrate have a marked effect on the distribution and the relative abundance of amphipods. The ranges of species diversity, richness, dominance, and evenness in the Vellar and Uppanar estuaries were 1.58–4.15, 1.82–5.29, 0–0.11, and 0.96–1, respectively. Using multivariate analyses, in each estuary, it was possible to identify different communities of amphipod species according to their habitats.     

Short-term changes in mobile dunes at Port Alfred,South Africa

Development along the western beachfront of Port Alfred, which is situated along a sandy shoreline, increased markedly in the 1960s as the coastal town became a popular holiday resort. This development included the removal of coastal vegetation, which resulted in the destabilization of dunes and migration of sand westerly onto the road, West Beach parking lot, and lawns of the cabanas. Sand traps were constructed to collect sand blowing across the dunes over set periods, and the net sand movement along the mobile dune belt was calculated using Hunter's equation. The dunes show an easterly movement of sand at a rate of 3.5 m/yr, which is comparable with figures recorded along other areas of this coastline. Considering the wind regime and amount of sand movement along this coast, it is inappropriate to clear vegetation and develop within the dune region.     

Microbial degradation of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in compost

The microbial degradation of tensile test pieces made of poly(3-hydroxybutyrate) [P(3HB)] or copolymers with 10% [P(3HB-co-10%3HV)] and 20% [P(3HB-co-20%3HV)] 3-hydroxyvaleric acid was studied in small household compost heaps. Degradation was measured through loss of weight (surface erosion) and changes in molecular weight and mechanical strength. It was concluded, on the basis of weight loss and loss of mechanical properties, that P(3HB) and P(3HB-co-3HV) plastics were degraded in compost by the action of microorganisms. No decrease inM _w could be detected during the degradation process. The P(3HB-co-20%3HV) copolymer was degraded much faster than the homopolymer and P(3HB-co-10%3HV). One hundred nine microbial strains capable of degrading the polymersin vitro were isolated from the samples used in the biodegradation studies, as well as from two other composts, and identified. They consisted of 61 Gram-negative bacteria (e.g.,Acidovorax facilis), 10 Gram-positive bacteria (mainlyBacillus megaterium), 35Streptomyces strains, and 3 molds.     

The role and expectancy participation model: An empirical assessement and extension

Four hypotheses were investigated. The results substantially support and extend the usefulness of Schuler's role and expectancy participation model (1980). Schuler's model posits that participation intervenes to attenuate the relationships between job objectives and role conflicts and ambiguity. Also, participation, role conflict and role ambiguity are assumed to intervene to attenuate the relationships between job objectives and job satisfaction. The four hypotheses were tested using a sample of 187 retail store managers. Results revealed that job objectives were related to the role variables and satisfaction. Participation significantly attenuated the job objectives, role conflict and job satisfaction relationships. Implications for the use of the attributes of job objectives approach to integrate other objective setting paradigms are discussed.     

Landscapes and environments on the island of Ouessant,Brittany, France: From traditional maintenance to the management of abandoned areas

For about 50 years the desertion of areas by traditional activities has led to an important evolution of landscapes and environments on the island of Ouessant. The study of this evolution has been undertaken at different spatial and temporal scales. On one part of the island, a scientific investigation carried out at the scale of the parcel enabled the form of the landscape in 1850 to be compared with that of 1985. On the whole island, the evolution of spatial organization and land use was compared between 1950 and 1985. For each of three main ecological environments, vegetational successions after the decrease of agriculture have been studied along with their future potential changes. This work highlights some considerations about the present management of the environment in relation to the major objectives of island environmental policies.     

Radon-222 signatures of natural ventilation regimes in an underground quarry

Radon-222 activity concentration has been monitored since 1999 in an underground limestone quarry located in Vincennes, near Paris, France. It is homogeneous in summer, with an average value of 1700 Bq m(-3), and varies from 730 to 1450 Bq m(-3) in winter, indicating natural ventilation with a rate ranging from 0.5 to 2.4 x 10(-6) s(-1) (0.04-0.22 day(-1)). This hypothesis is supported by measurements in the vertical access pit where, in winter, a turbulent air current produces a stable radon profile, smoothly decreasing from 700 Bq m(-3) at 20 m depth to 300 Bq m(-3) at surface. In summer, a thermal stratification is maintained in the pit, but the radon-222 concentration jumps repeatedly between 100 and 2000 Bq m(-3). These jumps are due to atmospheric pressure pumping, which induces ventilation in the quarry at a rate of about 0.1 x 10(-6) s(-1) (0.009 day(-1)). Radon-222 monitoring thus provides a dynamical characterisation of ventilation regimes, which is important for the assessment of the long-term evolution of underground systems.     

Response of Organic and Inorganic Carbon and Nitrogen to Long-Term Grazing of the Shortgrass Steppe

We investigated the influence of long-term (56 years) grazing on organic and inorganic carbon (C) and nitrogen (N) contents of the plant–soil system (to 90 cm depth) in shortgrass steppe of northeastern Colorado. Grazing treatments included continuous season-long (May–October) grazing by yearling heifers at heavy (60–75% utilization) and light (20–35% utilization) stocking rates, and nongrazed exclosures. The heavy stocking rate resulted in a plant community that was dominated (75% of biomass production) by the C₄ grass blue grama (Bouteloua gracilis), whereas excluding livestock grazing increased the production of C₃ grasses and prickly pear cactus (Opuntia polycantha). Soil organic C (SOC) and organic N were not significantly different between the light grazing and nongrazed treatments, whereas the heavy grazing treatment was 7.5 Mg ha^–1 higher in SOC than the nongrazed treatment. Lower ratios of net mineralized N to total organic N in both grazed compared to nongrazed treatments suggest that long-term grazing decreased the readily mineralizable fraction of soil organic matter. Heavy grazing affected soil inorganic C (SIC) more than the SOC. The heavy grazing treatment was 23.8 Mg ha^–1 higher in total soil C (0–90 cm) than the nongrazed treatment, with 68% (16.3 Mg ha^–1) attributable to higher SIC, and 32% (7.5 Mg ha^–1) to higher SOC. These results emphasize the importance in semiarid and arid ecosystems of including inorganic C in assessments of the mass and distribution of plant–soil C and in evaluations of the impacts of grazing management on C sequestration.