Reproductive partitioning in communally breeding guira cuckoos,<Emphasis Type="Italic"> Guira guira</Emphasis>

Guira cuckoos, Guira guira, exhibit a rare polygynandrous reproductive system with groups containing several male and female breeders, allowing for important tests of reproductive skew models. Female reproductive strategies involve leaving the group, varying clutch size, egg ejection and infanticide, among others. Here we examined the predictions of reproductive skew models relative to reproductive partitioning among females in groups. We used yolk protein electrophoresis to identify individual females eggs in joint nests. We found that reproductive partitioning favors early-laying females, which lay and incubate more eggs than females that begin laying later. Because the female that lays first tends to switch between repeated nesting bouts, and females do not always contribute eggs to each bout, female reproductive success tends to equalize within groups over time. The pattern of reproductive partitioning differs from that described for anis, another crotophagine joint-nester. We calculated reproductive skew indices for groups in 2 years, for both laying and incubation, as well as an overall population value. These were compared to random skew generated by simulations. Varying degrees of skew were found for different groups, and also across sequential nesting bouts of the same groups. Overall, however, skew did not deviate from random within the population. Nests that reached incubation tended to have lower skew values during the laying phase than nests terminated due to ejection of all eggs followed by desertion. Groups had higher reproductive skew indices in their first nesting bout of the season, and these nests frequently failed. These results illustrate the importance of social organization in determining not only individual, but group success in reproduction, and highlight the flexibility of vertebrate social behavior.Communicated by J. Dickinson     

Solar photocatalytic decolorization of methylene blue in water

In this study, a photocatalytic decolorization system equipped with immobilized TiO2 and illuminated by solar light was used to remove the color of wastewater. To examine the decoloring efficiency of this system, photocatalytic decolorization of an organic dye such as methylene blue was studied as an example. The effects of light source, pH, as well as the initial concentration of dye were also investigated. It was observed that the solution of methylene blue could be almost completely decolorized by the solar light/TiO2 film process while there was about 50% color remaining with solar irradiation only. In addition, it was found that the decoloring efficiency of solution was higher with solar light irradiation than with artificial UV light irradiation, even though the artificial UV light source supplied higher UV intensity at 254 nm. The color removal rate of methylene blue with solar light irradiation was almost twice that of artificial UV light irradiation. This phenomena was mainly attributed to that some visible light range of solar light was useful for exciting the methylene blue molecules adsorbed on TiO2 film, leading to a photosensitization process undergoing and decoloring efficiency promoted. This solar-assisted photocatalytic device showed potential application for decoloring organic dyes in wastewater.     

Photocatalytic oxidation of pesticide rinsate

Pesticide rinsate has been considered as one of the major threats for the environment. In this study, photocatalysts such as TiO2 and O3 were used to promote the efficiency of direct UV photolysis to prevent such wastewater pollution. Carbofuran (a carbamate pesticide) and mevinphos (an organophosphate pesticide) with a concentration of 100 mg/L were selected as the test pesticide rinsates. Parent pesticide compound, COD, and microtoxicity analysis were employed to investigate the effect of photocatalyst on the degradation efficiency of pesticide in rinsate. It was found that the photocatalytic oxidation process (UV/O3, UV/TiO2) showed much higher COD removal and microtoxicity reduction efficiency for pesticide rinsate than did direct UV photolysis under the imposed conditions, suggesting that photocatalytic oxidation processes such as UV/O3 and UV/TiO2 could be a better alternative to treat pesticide rinsate. In addition, it was noted that increasing the initial pH of mevinphos rinsate to a basic level was required to reach higher COD removal efficiency and positive microtoxicity reduction efficiency while it was not necessary for the treatment of carbofuran rinsate.     

Characteristics of aerosols collected in central Taiwan during an Asian dust event in spring 2000

Aerosol samples for PM(2.5) and PM(2.5-10) were collected at four locations in central Taiwan from 26 to 31 March 2000, a period that experienced exceedingly high PM levels from 29 to 30 March due to the passage of an Asian dust storm. The samples were analyzed for mass, metallic elements, ions, and carbon. The purpose of this paper is to investigate the influence of the dust storm on the characteristics of local ambient particulate matter. The results indicate that the concentrations of the crustal elements Ca, Mg, Al, Fe and the sea salt species Na+ and Cl- in PM(2.5-10) during the dust episode exceed the mean concentrations in the non-dust period by factors of 3.1, 2.9, 2.6, 2.2, 2.3 and 2.1 respectively. Enrichment factors of Ca, Fe, and Mg in PM(2.5-10) during the dust event are close to unity, indicating that these elements are from soil. Reconstruction of aerosol compositions revealed that soil of coarse particulates elevated approximately 50% in the dust event. It is noted that during the dust event, the ratio of Mg/Al in PM(2.5-10) ranged from 0.21 to 0.25 while that of Ca/Al ranged from 0.6 to 0.9, levels more constant than those obtained in non-dust period.     

Computational investigation of the effects of knee airbag design on the interaction with occupant lower extremity in frontal and oblique impacts

Objective: The lower extremity of the occupant represents the most frequently injured body region in motor vehicle crashes. Knee airbags (KABs) have been implemented as a potential countermeasure to reduce lower extremity injuries. Despite the increasing prevalence of KABs in vehicles, the biomechanical interaction of the human lower extremity with the KAB has not been well characterized. This study uses computational models of the human body and KABs to explore how KAB design may influence the impact response of the occupant's lower extremities.

Methods: The analysis was conducted using a 50th percentile male occupant human body model with deployed KABs in a simplified vehicle interior. The 2 common KAB design types, bottom-deploy KAB (BKAB) and rear-deploy KAB (RKAB), were both included. A state-of-the-art airbag modeling technique, the corpuscular particle method, was adopted to represent the deployment dynamics of the unfolding airbags. Validation of the environment model was performed based on previously reported test results. The kinematic responses of the occupant lower extremities were compared under both KAB designs, 2 seating configurations (in-position and out-of-position), and 3 loading conditions (static, frontal, and oblique impacts). A linear statistical model was used to assess factor significance considering the impact responses of the occupant lower extremities.

Results: The presence of a KAB had a significant influence on the lower extremity kinematics compared to no KAB (P <.05) by providing early restraint and distributing contact force on the legs during airbag deployment. For in-position occupants, the KAB generally tended to decrease tibia loadings. The RKAB led to greater lateral motion of the legs compared to the BKAB, resulting in higher lateral displacement at the knee joint and abduction angle change (51.2 ± 21.7 mm and 15° ± 6.0°) over the dynamic loading conditions. Change in the seating position led to a significant difference in occupant kinematic and kinetic parameters (P <.05). For the out-of-position (forward-seated) occupant, the earlier contact between the lower extremity and the deploying KAB resulted in 28.4° ± 5.8° greater abduction, regardless of crash scenarios. Both KAB types reduced the axial force in the femur relative to no KAB. Overall, the out-of-position occupant sustained a raised axial force and bending moment of the tibia by 0.8 ± 0.2 kN and 21.1 ± 8.7 Nm regardless of restraint use.

Conclusions: The current study provided a preliminary computational examination on KAB designs based on a limited set of configurations in an idealized vehicle interior. Results suggested that the BKAB tended to provide more coverage and less leg abduction compared to the RKAB in oblique impact and/or the selected out-of-position scenario. An out-of-position occupant was associated with larger abduction and lower extremity loads over all occupant configurations. Further investigations are recommended to obtain a full understanding of the KAB performance in a more realistic vehicle environment.     

Error Assessment for Height Above the Nearest Drainage Inundation Mapping

Real‐time flood inundation mapping is vital for emergency response to help protect life and property. Inundation mapping transforms rainfall forecasts into meaningful spatial information that can be utilized before, during, and after disasters. While inundation mapping has traditionally been conducted on a local scale, automated algorithms using topography data can be utilized to efficiently produce flood maps across the continental scale. The Height Above the Nearest Drainage method can be used in conjunction with synthetic rating curves (SRCs) to produce inundation maps, but the performance of these inundation maps needs to be assessed. Here we assess the accuracy of the SRCs and calculate statistics for comparing the SRCs to rating curves obtained from hydrodynamic models calibrated against observed stage heights. We find SRCs are accurate enough for large‐scale approximate inundation mapping while not as accurate when assessing individual reaches or cross sections. We investigate the effect of terrain and channel characteristics and observe reach length and slope predict divergence between the two types of rating curves, and SRCs perform poorly for short reaches with extreme slope values. We propose an approach to recalculate the slope in Manning’s equation as the weighted average over a minimum distance and assess accuracy for a range of moving window lengths.     

The application and evaluation research of coffee residue ash into mortar

Coffee residue is usually regarded as a kind of agriculture waste; as its quantity increases the treatment of coffee residue will become an environmental problem. This research is innovative in that it derives the possibility of recycle application using coffee residue ash for cement replacement. In this research, coffee residue is burned in an electronic oven to three kinds of coffee residue ash at 500, 600 and 700 °C, and then appropriate apparatus is used to check the chemical and physical properties of these three types of coffee residue ash. After a general comparison, this study selected 500 and 600 °C coffee residue ashes with 2, 3, 5, 10 and 15 % cement replacements to make 5 cm³ cube mortar specimen to test different curing ages’ compressive strength. Through measurement and experiment, this research found that the compressive strength decreased by adding 500 or 600 °C coffee residue ash into the mortar. By considering waste reduction and practice application, this research derives that using the 600 °C coffee residue ash with 10 % replacement is better than others application, such using result also can get valuable efficiencies of financial and CO₂ reduction.     

Biodegradation of coplanar polychlorinated biphenyls by anaerobic microorganisms from estuarine sediments.

In this study, we investigated the biodegradability of biphenyl and 5 congeners (one non-planar and four coplanar) of polychlorinated biphenyl (PCB). Biphenyl, the non-planar congener 2,3',4',5-tetrachlorobiphenyl (25-34 CB), and the four coplanar congeners 3,3',4,4'-tetrachlorobiphenyl (34-34 CB), 3,4,4',5-tetrachlorobiphenyl (345-4 CB), 3,3',4,4',5-pentachlorobiphenyl (345-34 CB), and 3,3',4,4',5,5'-hexachlorobiphenyl (345-345 CB) were amended at a concentration of 10 mg/L into anoxic sediment slurries collected from the estuaries of the Tansui River and the Erjen River. During 2 years' incubation under sulfidogenic conditions, biphenyl was persistent, while all other chlorinated congeners, except for 345-345 CB, were dechlorinated with or without a lag period in sediment slurries collected from both rivers. Dechlorination of coplanar and non-planar congeners began with para chlorine removal. All para chlorines from the mono-, di-, and trichlorobiphenyl groups could be removed by sediment slurries from both rivers. Microbial communities in sediment from the Erjen River additionally fostered meta-dechlorination activity, but only after removal of all the para chlorines. Addition of Tween 20 (0.05%, v/v) into sediment slurries from the Tansui River did not enhance dechlorination rates or extents, but the addition of toluene- or 3-chlorobenzoate-adapted sediments enhanced dechlorination of 34-34 CB and 345-4 CB.     

Synergistic effects of combination of photolysis and ozonation on destruction of chlorophenols in water.

Synergistic effects including TOC elimination, ozone consumption and microtoxicity reduction for combination of photolysis and ozonation compared to those of direct photolysis and ozonation alone on destruction of chlorophenols including 2-chlorophenol, 4-chlorophenol and 2,4-dichlorophenol were studied. It was found that the synergistic effects of combination of photolysis and ozonation increased obviously with increasing initial pH of solution to basic pH levels. Results showed that the synergistic effects of photolytic ozonation under the conditions imposed was notable with mineralization rate enlarging more than 100%, oxidation index (OI) decreasing 50%, and microtoxicity being reduced by 30%, indicating that the potentialities of photolytic ozonation compared to direct photolysis and ozonation alone was remarkable for treatment of industrial wastewater containing chlorophenols.