Development of Sediment and Nutrient Export Coefficients for U.S. Ecoregions

Water quality impairment due to excessive nutrients and sediment is a major problem in the United States (U.S.). An important step in the mitigation of impairment in any given water body is determination of pollutant sources and amount. The sheer number of impaired waters and limited resources makes simplistic load estimation methods such as export coefficient (EC) methods attractive. Unfortunately ECs are typically based on small watershed monitoring data, which are very limited and/or often based on data collected from distant watersheds with drastically different conditions. In this research, we seek to improve the accuracy of these nutrient export estimation methods by developing a national database of localized EC for each ecoregion in the U.S. A stochastic sampling methodology loosely based on the Monte‐Carlo technique was used to construct a database of 45 million Soil and Water Assessment Tool (SWAT) simulations. These simulations consider a variety of climate, topography, soils, weather, land use, management, and conservation implementation conditions. SWAT model simulations were successfully validated with edge‐of‐field monitoring data. Simulated nutrient ECs compared favorably with previously published studies. These ECs may be used to rapidly estimate nutrient loading for any small catchment in the U.S. provided the location, area, and land‐use distribution are known.     

Phosphorus losses through agricultural tile drainage in Nova Scotia, Canada

Tile drainage water from agricultural fields commonly exceeds environmental guidelines for phosphorus (P) in rivers and streams. The loss of P through artificial drainage is spatially and temporally variable, and is related to local factors. This study characterizes variability in total P (TP) and soluble reactive P (SRP) concentrations in weekly drainage samples from 39 agricultural fields in Nova Scotia, Canada, from April 2002 through December 2003. We examined connections between P concentrations and the factors: (i) soil texture; (ii) discharge flow rate; (iii) soil test P (STP); (iv) manure type; and (v) crop cover. Generally, variability between fields and samples was great, and fields with standard deviations exceeding the mean for TP, SRP, and flow rate were 71, 54, and 79%, respectively. It was evident that poultry and swine manure contributed to high STPs, and to constantly high TP concentrations with high proportions of SRP. Concentrations varied from week to week, and particularly in April, May, October, and November when the greatest TP, SRP, and flow rate averages were measured. Mean TP concentrations exceed the USEPA (1994) TP guideline of 0.10 mg L(-1) at 82% of the fields, and periodically concentrations more than 10 times, and occasionally more than 50 times higher than the guideline were found. The proportion of SRP in TP had a tendency to be higher when TP levels were high in coarse textured soils. In Nova Scotia, dairy manure is most often applied on permanent cover crops, which did not show as much P concentration variability as crop rotations. Daily or hourly observation of short-term increases in P concentrations related to the described factors would help to characterize the changes in P concentrations observed during frequent heavy drainage flow events.     

Agricultural pesticide residues in farm ditches of the Lower Fraser Valley, British Columbia, Canada

Transient and permanent farm ditches flowing to the Lower Fraser River tributary fish streams of British Columbia, Canada, were sampled at several locations in 2003-2004 to determine the occurrence and concentration of residues of selected pesticides, their transformation products, and soluble/extractable Cu++ ions. Of the 43 compounds analyzed, 28 and 22 pesticides were detected in transient farm ditch water and sediments, respectively. About 34% fewer pesticides, however, were found in both matrices of permanent farm ditches. Average concentrations (microg L(-1)) of those most frequently detected in permanent farm ditch water were atrazine (0.20), alpha -chlordane (0.06), desethylatrazine (0.13), diazinon (0.55), dieldrin (0.28), endosulfan sulfate (0.16), glyphosate (6), metalaxyl (0.27); and soluble Cu++ ions (25). Those most often found in ditch sediments (microg kg(-1)) were aminomethylphosphonic acid (AMPA) (2,300), 1,1,1-trichloro-2,2-bis-(4-chlorophenyl)ethane (DDT) (250), endosulfan sulfate (500), glyphosate (1,225); and extractable Cu++ ions (58,000). The risk potential of these pesticide residues to non-target aquatic organisms inhabiting Fraser River tributary fish streams contiguous to permanent farm ditches is evaluated and discussed.     

Degradation of carbofuran in water by solar photocatalysis in presence of photosensitizers

The effect of the presence of photosensitizers, methylene blue (MB) and rose Bengal (RB), on the degradation of carbofuran (2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate) in water in a solar photocatalytic system was investigated. It was found that as compared to MB, RB generally showed a stronger effect on the decomposition of carbofuran under comparable conditions. Among the conditions studied, adding 2 x 10(-6) M of RB, that corresponding to 2% of the initial concentration of carbofuran solution in the system, rendered the most effective degradation of carbofuran. As a result, a carbofuran removal percentage of 69.9%, a mineralization efficiency of 28.0%, and a microtoxicity reduction of 65.0% could be achieved. The degradation and mineralization of carbofuran was found to follow the pseudo-first order reaction kinetics. The decomposition mechanism of carbofuran was further investigated through identification of the intermediates to elaborate the influence of dye photosensitizer on the solar photocatalysis of carbofuran in water. On the basis of the intermediates identified, including carbofuran phenol, 3-hydroxy carbofuran phenol, and substituted alcohols (3-phenoxy 1-propanol, 2-ethyl 1-hexanol, 2-butoxyl ethanol), it appears that hydrolysis and hydroxylation were the two key mechanisms for decomposing carbofuran during the process of solar photocatalysis with the aid of dye photosensitizer.     

Methyl tertiary hexyl ether and methyl tertiary octyl ether as gasoline oxygenates: assessing risks from atmospheric dispersion and deposition

Methyl tertiary hexyl ether (MtHxE) and methyl tertiary octyl ether (MtOcE) are currently being developed as replacement oxygenates for methyl tertiary butyl ether (MtBE) in gasoline. As was the case with MtBE, the introduction of these ethers into fuel supplies guarantees their introduction into the environment as well. In this study, a screening-level risk assessment was performed by comparing predicted environmental concentrations (PEC) of these ethers to concentrations that might cause adverse effects to humans or ecosystems. A simple box model that has successfully estimated urban air concentrations of MtBE was adapted to predict atmospheric concentrations of MtHxE and MtOcE. Expected atmospheric concentrations of these ethers were also estimated using the European Union System for the Evaluation of Substances (EUSES) multimedia fate model, which simultaneously calculates PECs in the various environmental compartments of air, water, soil, and sediment. Because little or no data are available on the physicochemical, environmental, and toxicological properties of MtHxE and MtOcE, estimation methods were used in conjunction with EUSES to predict both the PECs and the concentrations at which these ethers might pose a threat. The results suggest that these ethers would contaminate the air of a moderately sized U.S. city (Boston, MA) at levels similar to those found previously for MtBE. The risk assessment module in EUSES predicted risk characterization ratios of 10(-3) and 10(-2) for MtHxE and MtOcE, respectively, in Boston, and 10(-2) and 10(-1) in very large urban centers, suggesting that these ethers pose only a minimal threat to ecosystems at the anticipated environmental concentrations. The assessment also indicates that these compounds are possible human carcinogens and that they may be present in urban air at concentrations that pose an unacceptable cancer risk. Therefore, testing of the toxicological properties of these compounds is recommended before they replace MtBE in gasoline.     

EFFECT OF WATERSHED SUBDIVISION ON SWAT FLOW,SEDIMENT, AND NUTRIENT PREDICTIONS1

ABSTRACT: The size, scale, and number of subwatersheds can affect a watershed modeling process and subsequent results. The objective of this study was to determine the appropriate level of subwatershed division for simulating flow, sediment, and nutrients over 30 years for four Iowa watersheds ranging in size from 2,000 to 18,000 km² with the Soil and Water Assessment Tool (SWAT) model. The results of the analysis indicated that variation in the total number of subwatersheds had very little effect on streamflow. However, the opposite result was found for sediment, nitrate, and inorganic P; the optimal threshold subwatershed sizes, relative to the total drainage area for each watershed, required to adequately predict these three indicators were found to be around 3, 2, and 5 percent, respectively. Decreasing the size of the subwatersheds below these threshold levels does not significantly affect the predicted levels of these environmental indicators. These threshold subwatershed sizes can be used to optimize input data preparation requirements for SWAT analyses of other watersheds, especially those within a similar size range. The fact that different thresholds emerged for the different indicators also indicates the need for SWAT users to assess which indicators should have the highest priority in their analyses.     

Water quality changes in a polluted stream over a twenty-five-year period

The Deckers Creek watershed in northern West Virginia (USA), containing a land area of 166 km2 (63 mi2), has a long history of industrial development and attendant environmental abuses from both land and water pollution practices. The water in Deckers Creek was sampled in 1974 at 29 locations along the main stem and resampled in 1999-2000 to determine water quality changes over this 25-year period. Water samples were analyzed for pH, acidity, alkalinity, iron, and calcium at both times, while aluminum, manganese, zinc, and fecal coliform (FC) bacteria densities were added in 1999-2000. Water at almost all sampling points showed lower acidity and metal contents in 1999-2000 compared with 1974. Water pH increased at the mouth from 5.4 in 1974 to 6.0 in 1999-2000. Acidity and iron concentrations were decreased an average of 70% in the upper stretches of the creek. However, one major untreated point source of water from an abandoned underground mining complex continues to degrade the quality of the creek in its lower stretches. In the upper section, the water quality in Deckers Creek has improved due to decreased surface and underground coal mining activities, reclamation of abandoned and recently permitted surface mined lands, and natural healing of past land use scars from timbering and mining over time. The decrease in mineral extraction activities and the reclamation of disturbed lands has occurred due to the passage and enforcement of water quality and land reclamation laws and regulations. More time and additional reclamation projects will continue to enhance the water quality in the creek. Improved water chemistry in the majority of the creek, however, shows the previously unnoticeable biological contamination from sewage inputs.     

How future trends in societal aging, air bag availability, seat belt use, and fleet composition will affect serious injury risk and occurrence in the United States

The objective of this study was to quantify the importance of societal aging relative to other factors that are known to affect injury risk. An aging population's effect on Maximum Abbreviated Injury Scale (MAIS) 3+ injury trends for passenger car drivers in frontal crashes was projected and compared to the effects of projected changes in fleet composition, changes in seat belt usage, and changes in air bag availability. It was determined that increased frailty due to an aging population will result in 19,816 to 43,568 additional injuries to passenger car drivers in frontal crashes from 1996 to 2012. Aging was shown to have an effect similar to the increased presence of light trucks in the fleet (a cumulative increase of approximately 47,428 injuries). Aging and changing fleet composition were shown to have a smaller effect than the projected increases in seat belt use or air bag availability, though the effect of increased belt use is not much greater than the effect of aging. After 2012, however, air bag availability and seat belt use will plateau, while societal aging will continue.     

Firewood consumption in a Nepali village

People's dependence on firewood as a primary source of energy is causing serious deforestation problems in many developing countries. Reliable information on firewood consumption rates is needed to develop afforestation plans and to control deforestation. This study compares three methods used to determine firewood consumption in a Nepali village. Cultural and environmental factors that affect firewood consumption in the village are also examined.Theweight survey proved to be the most accurate method used. The less precisedaily recall andannual recall surveys overestimated actual firewood consumption by factors of 1.76 and 1.95, respectively. Overestimates are attributed to both physical and social factors. In view of the good agreement between daily and annual recall surveys, and the much greater ease of conducting the latter, annual recall surveys are recommended as the most practical method of monitoring firewood consumption rates. Validating the survey with occasional weighed measurements is suggested as a means of improving accuracy.     

Development of bacteria and benthic total maximum daily loads: a case study, Linville Creek, Virginia

Two total maximum daily load (TMDL) studies were performed for Linville Creek in Rockingham County, Virginia, to address bacterial and benthic impairments. The TMDL program is an integrated watershed management approach required by the Clean Water Act. This paper describes the procedures used by the Center for TMDL and Watershed Studies at Virginia Tech to develop the Linville Creek TMDLs and discusses the key lessons learned from and the ramifications of the procedures used in these and other similar TMDL studies. The bacterial impairment TMDL was developed using the Hydrological Simulation Program-Fortran (HSPF). Fecal coliform loads were estimated through an intensive source characterization process. The benthic impairment TMDL was developed using the Generalized Watershed Loading Function (GWLF) model and the reference watershed approach. The bacterial TMDL allocation scenario requires a 100% reduction in cattle manure direct-deposits to the stream, a 96% reduction in nonpoint-source loadings to the land surface, and a 95% reduction in wildlife direct-deposits to the stream. Sediment was identified as the primary benthic stressor. The TMDL allocation scenario for the benthic impairment requires an overall reduction of 12.3% of the existing sediment loads. Despite the many drawbacks associated with using watershed-scale models like HSPF and GWLF to develop TMDLs, the detailed watershed and pollutant-source characterization required to use these and similar models creates information that stakeholders need to select appropriate corrective measures to address the cause of the water quality impairment when implementing the TMDL.