Arsenic mobilization and attenuation by mineral-water interactions: implications for managed aquifer recharge

Managed aquifer recharge (MAR) has potential for addressing deficits in water supplies worldwide. It is also widely used for preventing saltwater intrusion, maintaining the groundwater table, and augmenting ecological stream flows, among many other beneficial environmental applications. However, field MAR sites have experienced arsenic mobilization from aquifer formation minerals due to induced changes in groundwater chemistry. To address this environmental concern, it is crucial to understand the potential sources and sinks impacting arsenic mobilization. This paper outlines important mineral-water interactions that can occur at MAR sites. Detailed information on minerals of concern, physiochemical processes for arsenic mobilization or attenuation, and the potential impact of microbial activity and hydrology on these processes is provided. Based on these mineral-water interactions, guidelines for predicting arsenic mobility are presented, and recommendations are made concerning MAR site monitoring. The review emphasizes important aspects in correlating interfacial reactions to reactive transport modeling and elucidating future challenges, a first step toward developing safer and more sustainable MAR operations.     

Changes in wind erosion over a 25-year restoration chronosequence on the south edge of the Tengger Desert,China: implications for preventing desertification

Wind erosion is a primary cause of desertification as well as being a serious ecological problem in arid and semi-arid areas across the world. To determine mechanisms for restoring desertified lands, an unrestored shifting sand dune and three formerly shifting sand dunes (desertified lands) that had been enclosed and afforested for 5, 15, and 25 years were selected for evaluation on the south edge of the Tengger Desert, China. Based on sampling heights between 0.2 and 3 m, the critical threshold average wind speed was 6.5 m s^?1 at 2 m where the sand transport rate was reduced from 285.9 kg m^?2 h^?1 on the unrestored dunes to 9.1 and 1.8 kg m^?2 h^?1 on the sites afforested and enclosed for 5 and 15 years, respectively. The percentage of wind eroded area was reduced from 99.9% on the unrestored dune to 94.5, 9.0, and 0.5% on the sites afforested and enclosed for 5, 15, and 25 years, respectively. Wind erosion was effectively reduced after 15 years. Although there were different driving factors for wind erosion mitigation on the different restoration stages, an increase in the vegetation cover, surface roughness, soil shear strength, soil clay content, organic matter, and reduction in the near-surface wind speed were the primary variables associated with the restoration chronosequence. We conclude that reducing the wind speed and developing a biological crust through vegetation restoration were the critical components for restoration of desertified land.     

A theoretical integration of leader emergence and leadership effectiveness: Over,under, and congruent emergence

There is a long and rich history of research on the concept of leader emergence. Much of this research positions leader emergence alongside leadership effectiveness as an epiphenomenal criterion in leadership research. Although this view has enhanced our understanding of factors that influence leader emergence and leadership effectiveness individually, our understanding of the potential alignment or misalignment of these concepts remains opaque. Following from this, we are left with unanswered questions concerning how, why, and under what conditions do the right or wrong leaders emerge or fail to emerge. Theory that develops insights into these questions is needed to advance our understanding of leadership and to cope with challenges of identifying and developing effective leaders and maximizing leadership potential in organizations. By integrating theories of leader emergence and leadership effectiveness—and considering their implications jointly—we provide a conceptual basis for identifying and understanding a more complete range of leader emergence than has been suggested in the literature. Importantly, our theoretical frame explains how our leader emergence types—over-emergence, under-emergence, congruent emergence, and congruent non-emergence—are differentially associated with a common set of factors. In doing so, we illuminate tradeoffs that might accompany different interventions intended to enhance leadership in organizations.     

Perceptions and Behaviors of Indigenous Populations Regarding Illegal Use of Protected Area Resources in East Africa’s Mountain Gorilla Landscape

Illegal activities and use of park resources are the main challenges facing mountain gorilla (Gorilla beringei beringei) conservation and the protection of their habitats in the East Africa’s Greater Virunga Transboundary Landscape (GVTL). Indigenous residents around GVTL are considered the primary illegal users of park resources. Despite this, there is limited understanding of the current and past perceptions of indigenous residents living in communities adjacent to two GVTL parks; Volcanoes National Park in Rwanda and Mgahinga Gorilla National Park in Uganda. Equally, there is also limited understanding regarding the actual incidences of illegal activities inside both parks. This paper addresses these gaps. Perception data were collected from indigenous residents living adjacent to both parks. Further, Ranger-based Monitoring (RbM) data from both parks were analyzed to determine actual numbers and types of illegal activities over the 9-year period. Interestingly, findings indicated that residents perceived the prevalence of illegal activities to be decreasing across GVTL. To the contrary, RbM findings indicated that the number of actual illegal activities was increasing significantly, particularly in Volcanoes National Park. The discrepancy found between the two perspectives provides for a discussion of the social biases potentially present in these data, and their implications for management. Results also illuminated the subsistence-related nature of most illegal behaviors and suggest that to reduce illegal activities and local dependency on park resources, park management must work with communities and support them in tapping into alternative livelihoods and finding ways to address community household subsistence needs.     

Observations on the methane oxidation capacity of landfill soils

The objective of this study was to determine the role of CH₄ loading to a landfill cover in the control of CH₄ oxidation rate (g CH₄ m⁻² d⁻¹) and CH₄ oxidation efficiency (% CH₄ oxidation) in a field setting. Specifically, we wanted to assess how much CH₄ a cover soil could handle. To achieve this objective we conducted synoptic measurements of landfill CH₄ emission and CH₄ oxidation in a single season at two Southeastern USA landfills. We hypothesized that percent oxidation would be greatest at sites of low CH₄ emission and would decrease as CH₄ emission rates increased. The trends in the experimental results were then compared to the predictions of two differing numerical models designed to simulate gas transport in landfill covers, one by modeling transport by diffusion only and the second allowing both advection and diffusion. In both field measurements and in modeling, we found that percent oxidation is a decreasing exponential function of the total CH₄ flux rate (CH₄ loading) into the cover. When CH₄ is supplied, a cover’s rate of CH₄ uptake (g CH₄ m⁻² d⁻²) is linear to a point, after which the system becomes saturated. Both field data and modeling results indicate that percent oxidation should not be considered as a constant value. Percent oxidation is a changing quantity and is a function of cover type, climatic conditions and CH₄ loading to the bottom of the cover. The data indicate that an effective way to increase the % oxidation of a landfill cover is to limit the amount of CH₄ delivered to it.     

Discussion1-“Stream Temperature Relationships to Forest Harvest in Western Washington” by Michael M. Pollock,Timothy J. Beechie,Martin Liermann,and Richard E. Bigley2

Ice, George G., George W. Brown, John A. Gravelle, C. Rhett Jackson, Jeffrey T. Light, Timothy E. Link, Douglas J. Martin, Dale J. McGreer, and Arne E. Skaugset, 2010. Discussion –“Stream Temperature Relationships to Forest Harvest in Western Washington” by Michael M. Pollock, Timothy J. Beechie, Martin Liermann, and Richard E. Bigley. Journal of the American Water Resources Association (JAWRA) 46(4): 838-842. DOI: 10.1111/j.1752-1688.2010.00441.x     

Frame alignment and environmental advocacy: the influence of NGO strategies on policy outcomes in China

ABSTRACT

The link between environmental frames and policy outcomes in China is explored. Environmental nongovernment organizations’ (ENGOs) issue interpretation and presentation affect environmental policy changes. The notion of ‘frame alignment’ is introduced, and it is argued that it can serve to link ENGOs’ advocacy needs and frame resonance among different stakeholders, thus successfully promoting advocacy. Based on in-depth interviews and analysis of news reports over a span of 10 years, it is found that where ENGOs are able to align their issue frames with those of the central state and media, the resulting frame resonance smooths policy change. In contrast, where ENGOs adopt conflict frames critical of state authorities, the absence of alignment leads to a slim chance of policy change. The findings shed light on why some ENGOs successfully create linkage and achieve their desired outcomes while others fail to do so.     

Methane emissions from 20 landfills across the United States using vertical radial plume mapping

Landfill fugitive methane emissions were quantified as a function of climate type and cover type at 20 landfills using US. Environmental Protection Agency (EPA) Other Test Method (OTM)-10 vertical radial plume mapping (VRPM) with tunable diode lasers (TDLs). The VRPM data were initially collected as g CH4/sec emission rates and subsequently converted to g CH4/m2/ day rates using two recently published approaches. The first was based upon field tracer releases of methane or acetylene and multiple linear regression analysis (MLRM). The second was a virtual computer model that was based upon the Industrial Source Complex (ISC3) and Pasquill plume stability class models (PSCMs). Calculated emission results in g CH4/m2/day for each measured VRPM with the two approaches agreed well (r2 = 0.93). The VRPM data were obtained from the working face, temporary soil, intermediate soil, and final soil or synthetic covers. The data show that methane emissions to the atmosphere are a function of climate and cover type. Humid subtropical climates exhibited the highest emissions for all cover types at 207, 127, 102, and 32 g CH4/m2/day, for working face (no cover), temporary, intermediate, and final cover, respectively. Humid continental warm summers showed 67, 51, and 27 g CH4/m2/day for temporary, intermediate, and final covers. Humid continental cool summers were 135, 40, and 26 g CH4/m2/day for the working face, intermediate, and final covers. Mediterranean climates were examined for intermediate and final covers only and found to be 11 and 6 g CH4/m2/day, respectively, whereas semiarid climates showed 85, 11, 3.7, and 2.7 g CH4/m2/day for working face, temporary, intermediate, and final covers. A closed, synthetically capped landfill covered with soil and vegetation with a gas collection system in a humid continental warm summer climate gave mostly background methane readings and average emission rates of only 0.09 g CH4/m2/day flux when measurable.     

Analytical solution for estimating storage efficiency of geologic sequestration of CO2

During injection of carbon dioxide (CO₂) into deep saline aquifers, the available pore volume of the aquifer may be used inefficiently, thereby decreasing the effective capacity of the repository for CO₂ storage. Storage efficiency is the fraction of the available pore space that is utilized for CO₂ storage, or, in other words, it is the ratio between the volume of stored CO₂ and the maximum available pore volume. In this note, we derive and present simple analytical expressions for estimating CO₂ storage efficiency under the scenario of a constant-rate injection of CO₂ into a confined, homogeneous, isotropic, saline aquifer. The expressions for storage efficiency are derived from models developed previously by other researchers describing the shape of the CO₂-brine interface. The storage efficiency of CO₂ is found to depend on three dimensionless groups, namely: (1) the residual saturation of brine after displacement by CO₂; (2) the ratio of CO₂ mobility to brine mobility; (3) a dimensionless group (which we call a “gravity factor”) that quantifies the importance of CO₂ buoyancy relative to CO₂ injection rate. In the particular case of negligible residual brine saturation and negligible buoyancy effects, the storage efficiency is approximately equal to the ratio of the CO₂ viscosity to the brine viscosity. Storage efficiency decreases as the gravity factor increases, because the buoyancy of the CO₂ causes it to occupy a thin layer at the top of the confined formation, while leaving the lower part of the aquifer under-utilized. Estimates of storage efficiency from our simple analytical expressions are in reasonable agreement with values calculated from simulations performed with more complicated multi-phase-flow simulation software. Therefore, we suggest that the analytical expressions presented herein could be used as a simple and rapid tool to screen the technical or economic feasibility of a proposed CO₂ injection scenario.     

论小城镇核心竞争力的构建和提升

小城镇作为中国城镇化进程的重要组成部分,对于我国城镇发展的作用举足轻重.研究我国小城镇的核心竞争力问题,有助于加深对小城镇经济发展的认识,帮助政府部门从更高的层次制定小城镇经济发展战略.本文界定了小城镇核心竞争力的概念,探讨了培育和提升小城镇经济核心竞争力的重要意义,并从自然环境、人文环境、基础设施、软件环境、创新能力及产业集群等方面对小城镇核心竞争力的构成进行分析;针对小城镇核心竞争力的构建和提升,提出了优化小城镇发展环境,完善小城镇创新体系,增强小城镇产业集群的发展等建议;得出了发展小城镇经济的关键是要增强其竞争力,而要保持小城镇经济持续的竞争优势,关键在于小城镇经济核心竞争力的培育和提升的结论,为促进我国小城镇经济的持续、快速发展及核心竞争力的构建与提升提供参考和借鉴.