Monitoring water quality in reservoirs for human supply through multi-biomarker evaluation in tropical fish

Paraíba do Sul River is located at a very densely inhabited region of Brazil crossing the three most industrialized states of the country (S?o Paulo, Minas Gerais and Rio de Janeiro states). As a result, industrial and farming residues as well as urban sewage are frequently disposed without appropriate treatment. The current study aimed at investigating the water quality in three reservoirs along the Paraíba do Sul River (Ilha dos Pombos, Santa Cecília and Santa Branca), through physiological, morphological, biochemical, and genetic biomarkers. The bioindicator chosen was the catfish Pimelodus maculatus, sampled during the dry (June 2008) and rainy (February 2009) seasons. Also, some water physicochemical parameters were analyzed from the sampling sites, but displayed no alterations according to the Brazilian Agency for Water Quality Legislation. Branchial carbonic anhydrase activity was inhibited in the dry season, while renal carbonic anhydrase activity was inhibited in the rainy season in the Santa Branca reservoir, indicating disturbance of osmoregulatory and acid-base regulation processes. Histopathological alterations were observed in the gills (neoplasic and tissue hyperplasia processes) and liver (necrosis), indicating serious damage to the functional integrity of these organs. A high incidence of melanomacrophage centers was observed in the liver, suggesting an intense immune response in all reservoirs. Acetylcholinesterase and catalase activity showed also differences corroborating some morphological results. Likewise, the induction of the micronucleus and DNA damage indicate genotoxicity, but mainly in the Santa Branca reservoir. Thus, the health status of P. maculatus warrants caution in the use of the water from the 3 reservoirs for direct human consumption, particularly after the accidental spill of endosulfan in November 2008, three months before the rainy season sampling.     

Photocatalytic reduction of carbon dioxide over Cu/TiO<Subscript>2</Subscript> photocatalysts

The photocatalytic reduction of CO₂ with H₂O was investigated using Cu/TiO₂ photocatalysts in aqueous solution. For this purpose, Cu/TiO₂ photocatalysts (with 0.2, 0.9, 2, 4, and 6 wt.% of Cu) have been synthesized via sol-gel method. The photocatalysts were extensively characterized by means of inductively coupled plasma optical emission spectrometry (ICP-OES), N₂ physisorption (BET), XRD, UV-vis DRS, FT-IR, Raman spectroscopy, TEM-EDX, and photoelectrochemical measurements. The as-prepared photocatalysts contain anatase as a major crystalline phase with a crystallite size around 13 nm. By increasing the amount of Cu, specific surface area and band gap energy decreased in addition to the formation of large agglomeration of CuO. Results revealed that the photocatalytic reduction of CO₂ decreased in the presence of Cu/TiO₂ in comparison to pure TiO₂, which might be associated to the formation of CuO phase acting as a recombination center of generated electron-hole pair. Decreasing of photoactivity can also be connected with a very low position of conduction band of photocatalysts with high Cu content, which makes H₂ production necessary for CO₂ reduction more difficult.     

Spectral trend of vegetation with rainfall in events of El Niño-Southern Oscillation for Atlantic Forest biome,Brazil

This study aimed to analyze the spectral trend of vegetation with rainfall in El Niño-Southern Oscillation events (ENSO) in the Atlantic Forest, Brazil. Monthly rainfall data were collected from 85 conventional meteorological stations (EMC), data from the Enhanced Vegetation Index 2 (EVI2) and ENSO events (El Niño, La Niña, and Neutral) in the period from 2001 to 2013. Afterwards, state cluster analysis was performed using the results of non-parametric tests. The Mann-Kendall (MK) non-parametric test did not identify a trend pattern in rainfall distribution in the Atlantic Forest. The results for EVI2 by state and region showed that the trend is decreasing in the Northeast Region, except for the states of Alagoas and Pernambuco. Southeast region showed an increasing trend of EVI2 (except for Rio de Janeiro and São Paulo), while the South region showed a decreasing trend. In the Midwest, the trend was significantly decreasing. In the prognosis elaborated for the future, the regions with significant declines of the vegetation were the Northeast and Midwest. This study shows that the Atlantic Forest in some regions of Brazil has been suffering from the growing urbanization process and there is a trend of soil degradation.     

Bird on the wire: Landscape planning considering costs and benefits for bird populations coexisting with power lines

Power-line grids are increasingly expanding worldwide, as well as their negative impacts on avifauna, namely the direct mortality through collision and electrocution, the reduction of breeding performance, and the barrier effect. On the other hand, some bird species can apparently benefit from the presence of power lines, for example perching for hunting purposes or nesting on electricity towers. In this perspective essay, we reviewed the scientific literature on both costs and benefits for avifauna coexisting with power lines. Overall, we detected a generalized lack of studies focusing on these costs or benefits at a population level. We suggest that a switch in research approach to a larger spatio-temporal scale would greatly improve our knowledge about the actual effects of power lines on bird populations. This research approach would facilitate suitable landscape planning encompassing both mitigation of costs and promotion of benefits for bird populations coexisting with power lines. For example, the strategic route planning of electricity infrastructures would limit collision risk or barrier effects for threatened bird populations. Concurrently, this strategic route planning would promote the range expansion of threatened populations of other bird species, by providing nesting structures in treeless but potentially suitable landscapes. We suggest establishing a collaborative dialogue among the scientific community, governments, and electricity companies, with the aim to produce a win–win scenario in which both biodiversity conservation and infrastructure development are integrated in a common strategy.     

The impact of global change on economic values of water for Public Irrigation Schemes at the São Francisco River Basin in Brazil

Economic values of water for the main Public Irrigation Schemes in the sub-middle region of the São Francisco River Basin, in northeastern Brazil, are determined in this study using an integration of a global agro-economic land and water use (MAgPIE) with a local economic model (Positive Mathematical Programming). As in the latter, the water values depend on the crops grown, and as Brazilian agriculture is strongly influenced by the global market, we used a regionalized version of the global model adapted to the region in order to simulate the crop land use, which is in turn determined by changes in global demand, trade barriers, and climate. The allocation of sugarcane and fruit crops projected with climate change by the global model, showed an impact on the average yields and on the water costs in the main schemes resulting in changes in the water values locally. The economic values for all schemes in the baseline year were higher than the water prices established for agricultural use in the basin. In the future, these water values will be higher in all the schemes. The highest water values currently and in the future were identified in municipalities with a significant proportion of area growing irrigated sugarcane. Being aware of current water values of each user in a baseline year and in a projected future under global climate and socioeconomic changes, decision makers should improve water allocation policies at local scale, in order to avoid conflicts and unsustainable development in the future.     

The humanitarian common logistic operating picture: a solution to the inter‐agency coordination challenge

Although significant progress has been made in developing the practice of humanitarian logistics, further improvements in efficiency and effectiveness have the potential to save lives and reduce suffering. This paper explores how the military/emergency services’ concept of a common operating picture (COP) can be adapted to the humanitarian logistics context, and analyses a practical and proven approach to addressing the key challenge of inter‐agency coordination and decision‐making. Successful adaptation could provide the mechanism through which predicted and actual demands, together with the location and status of material in transit, are captured, evaluated, and presented in real time as the basis for enhanced decision‐making between actors in the humanitarian supply network. Through the introduction of a humanitarian logistics COP and its linkages to national disaster management systems, local communities and countries affected by disasters and emergencies will be better placed to oversee and manage their response activities.     

2D brine sewage after impinging on a shallow sea free surface

We consider the problem of the vertically upwards disposal of heavy brine sewage from a two-dimensional diffuser in a lighter, homogeneous, motionless and shallow ambient sea. The rejected high salinity water of seawater desalination plants for urban and agricultural uses is such a case of a two dimensional fountain. The disposal of brine sewage produces a negative buoyant jet due to its initial momentum, which impinges on the free surface, spreads laterally on it and then sinks downwards, because of the negative buoyancy. Laboratory experiments and dimensional considerations are used in this paper in order to investigate the spreading behavior (width) of the vertical fountain which impinges on the free surface of the shallow ambient fluid. The experimental results have been used to derive an equation relating the width at the free surface with the initial parameters of the flow. In addition, the experimentally measured dilution of the heavier brine sewage on the recipient’s surface is compared with the dilution which was calculated by a numerical simulation of a well-known commercial software package, CORJET (a CORMIX sub model).     

Mechanism of the intermittent motion of two-phase debris flows

A typical two-phase debris flow exhibits a high and steep flow head consisting of rolling boulders and cobbles with intermittent or fluctuating velocity. The relative motion between the solid phase and the liquid phase is obvious. The motion of a two-phase debris flow depends not only on the rheological properties of the flow, but also on the energy transmission between the solid and liquid phases. Several models have been developed to study two-phase debris flows. An essential shortcoming of most of these models is the omission of the interaction between the two phases and identification of the different roles of the different materials in two-phase debris flows. The tracer particles were used for the velocity of solid phase and the velocity of liquid phase was calculated by the water velocity on the surface of the debris flow in the experiments. This paper analyzed the intermittent feature of two-phase debris flows based on videos of debris flows in the field and flume experiments. The experiments showed that the height of the head of the two-phase debris flow increased gradually in the initiation stage and reached equilibrium at a certain distance from the start of the debris flow. The height growth and the velocity of the flow head showed fluctuating characteristics. Model equations were established and the analyses proved that the average velocity of the two-phase debris flow head was proportional to the flood discharge and inversely proportional to the volume of the debris flow head.     

Froude scaling limitations in modeling of turbidity currents

The scaling problem associated with the modeling of turbidity currents has been recognized but is yet to be explored systematically. This paper presents an analysis of the dimensionless governing equations of turbidity currents to investigate the scale effect. Three types of flow conditions are considered: (i) conservative density current; (ii) purely depositional turbidity current; and (iii) mixed erosional/depositional turbidity current. Two controlling dimensionless numbers, the Froude number and the Reynolds number, appear in the non-dimensional governing equations. When densimetric Froude similarity is satisfied, the analysis shows that the results would be scale-invariant for conservative density current under the rough turbulent condition. In the case of purely depositional flows, truly scale-invariant results cannot be obtained, as the Reynolds-mediated scale effects appear in the bottom boundary conditions of the flow velocity and sediment fall velocity. However, the scale effect would be relatively modest. The Reynolds effect becomes more significant for erosional or mixed erosional/depositional turbidity currents as Reynolds-mediated scale effects also appear in the sediment entrainment relation. Numerical simulations have been conducted at three different scales by considering densimetric Froude scaling alone as well as combined densimetric Froude and Reynolds similarity. Simulation results confirm that although the scaling of densimetric Froude number alone can produce scale-invariable results for conservative density currents, variations occur in the case of turbidity currents. The results become scale invariant when densimetric Froude and Reynolds similarities are satisfied simultaneously.     

Local air pollution and global climate change taxes: a distributional analysis for the case of Spain

Global climate change measures are difficult to implement. In this context, local air pollution measures may play an important role in the political agenda since their effects are felt more immediately by citizens. Distributional implications are one of the main barriers for implementing environmental policies. This paper explores the distributional implications of air pollution taxes and compares them to climate change taxes. For the comparison, both tax schemes were set to yield the same revenue. Methodologically, the study uses a top–down approach linking a macro model to a micro model. We find that taxes on local air pollutants are more regressive than those levied on CO₂. This is because the goods implicitly taxed have a greater weight in the consumer basket of low-income groups, even if the tax revenues are recycled. Furthermore, the revenue-neutral recycle scheme increases both taxes efficiency, but, at the same time, can increase regressivity.