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41.
Bioremediation of chlorobenzene-contaminated ground water in an in situ reactor mediated by hydrogen peroxide 总被引:5,自引:0,他引:5
Vogt C Alfreider A Lorbeer H Hoffmann D Wuensche L Babel W 《Journal of contaminant hydrology》2004,68(1-2):121-141
New in situ reactive barrier technologies were tested nearby a local aquifer in Bitterfeld, Saxonia-Anhalt, Germany, which is polluted mainly by chlorobenzene (CB), in concentrations up to 450 microM. A reactor filled with original aquifer sediment was designed for the microbiological remediation of the ground water by indigenous bacterial communities. Two remediation variants were examined: (a) the degradation of CB under anoxic conditions in the presence of nitrate; (b) the degradation of CB under mixed electron acceptor conditions (oxygen+nitrate) using hydrogen peroxide as the oxygen-releasing compound. Under anoxic conditions, no definite degradation of CB was observed. Adding hydrogen peroxide (2.94 mM) and nitrate (2 mM) led to the disappearance of CB (ca. 150 microM) in the lower part of the reactor, accompanied by a strong increase of the number of cultivable aerobic CB degrading bacteria in reactor water and sediment samples, indicating that CB was degraded mainly by productive bacterial metabolism. Several aerobic CB degrading bacteria, mostly belonging to the genera Pseudomonas and Rhodococcus, were isolated from reactor water and sediments. In laboratory experiments with reactor water, oxygen was rapidly released by hydrogen peroxide, whereas biotic-induced decomposition reactions of hydrogen peroxide were almost four times faster than abiotic-induced decomposition reactions. A clear chemical degradation of CB mediated by hydrogen peroxide was not observed. CB was also completely degraded in the reactor after reducing the hydrogen peroxide concentration to 880 microM. The CB degradation completely collapsed after reducing the hydrogen peroxide concentration to 440 microM. In the following, the hydrogen peroxide concentrations were increased again (to 880 microM, 2.94 mM, and 880 microM, respectively), but the oxygen demand for CB degradation was higher than observed before, indicating a shift in the bacterial population. During the whole experiment, nitrate was uniformly reduced during the flow path in the reactor. 相似文献
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User behaviour, best practice and the risks of non-target exposure associated with anticoagulant rodenticide use 总被引:1,自引:0,他引:1
Tosh DG Shore RF Jess S Withers A Bearhop S Ian Montgomery W McDonald RA 《Journal of environmental management》2011,92(6):1503-1508
Usage of anticoagulant rodenticides (ARs) is an integral component of modern agriculture and is essential for the control of commensal rodent populations. However, the extensive deployment of ARs has led to widespread exposure of a range of non-target predatory birds and mammals to some compounds, in particular the second-generation anticoagulant rodenticides (SGARs). As a result, there has been considerable effort placed into devising voluntary best practice guidelines that increase the efficacy of rodent control and reduce the risk of non-target exposure. Currently, there is limited published information on actual practice amongst users or implementation of best practice. We assessed the behaviour of a typical group of users using an on-farm questionnaire survey. Most baited for rodents every year using SGARs. Most respondents were apparently aware of the risks of non-target exposure and adhered to some of the best practice recommendations but total compliance was rare. Our questionnaire revealed that users of first generation anticoagulant rodenticides rarely protected or checked bait stations, and so took little effort to prevent primary exposure of non-targets. Users almost never searched for and removed poisoned carcasses and many baited for prolonged periods or permanently. These factors are all likely to enhance the likelihood of primary and secondary exposure of non-target species. 相似文献
45.
Larissa Schneider Lauren Belger Joanna Burger Richard Carl Vogt Christian Jeitner Jose Reinaldo Pacheco Peleja 《毒物与环境化学》2013,95(2):238-250
This study determined the concentrations of mercury (Hg) in four tissues of six species of turtles from the Rio Negro in the Amazon Basin. For two species, blood and carapace tissues were correlated with concentrations in internal tissues to establish whether blood or carapace could serve as a non-lethal indicator of internal metal exposure or body burden. The four tissues’ Hg levels were also correlated to turtle size and gender. The liver in five species of turtles had the highest concentration, followed by carapace, muscle, and blood. The exception was Chelus fimbriatus, which had a higher metal concentration in the muscle than carapace. Regarding the correlation between total Hg concentrations in tissues of the two species, no significant correlation was noted for Podocnemis erythrocephala. However, for Podocnemis sextuberculata significant correlation was found between muscle?×?liver, muscle?×?blood, and liver?×?blood. For P. erythrocephala, there was a correlation between Hg concentration in carapace and turtle size. For P. sextuberculata, there was no marked correlation between Hg concentration and size, but concentration in muscle was significantly influenced by gender. The patterns of Hg accumulation in tissues of the five species followed those described for freshwater species and some species of sea turtles. The difference in C. fimbriatus may be a result of a different pattern of non-living keratin layers on the carapace tissue. The use of carapace to infer internal concentrations of Hg is common in freshwater and sea turtles, but in this study it was found that only blood might be a reliable indicator of Hg concentrations in liver and muscle tissues for P. sextuberculata. Thus blood may be used as a non-invasive method to study concentrations of Hg in liver and muscle of P. sextuberculata. 相似文献
46.
Andres Gartmann Mathias D. Müller Eberhard Parlow Roland Vogt 《Environmental Fluid Mechanics》2012,12(2):185-200
Studying urban air-transport phenomena is highly complex, because of the heterogenous flow patterns that can arise. The main
reason for these is the variable topology of urban areas, however, there is a large number of influencing variables such as
meteorological conditions (e.g., wind situation, temperature) and anthropogenic factors such as traffic emissions. During
a one-year CO2 measurement campaign in the city of Basel, Switzerland, steep CO2 gradients were measured around a large building. The concentration differences showed a strong dependency on the local flow
regimes. Analysis of the field data alone did not provide a complete explanation for the mechanisms underlying the observed
phenomena. The key numerical parameters were defined and the influence of turbulent kinetic energy dependency on the time
interval for the Reynolds decomposition was studied. A Reynolds-Average Navier-Stokes Computational Fluid Dynamics (CFD) approach
was applied in the study area and the CO2 concentrations were simulated for six significant meteorological situations and compared to the measured data. Two flow regimes
dependent on the wind situation, which either enhanced or suppressed the concentration of CO2 in the street canyon, were identified. The enhancement of CO2 in the street canyon led to a large difference in CO2 concentration between the backyard- and street-sides of a building forming the one wall of the canyon. The specific characteristics
of the flow patterns led to the identification of the processes determining the observed differences in CO2 concentrations. The combined analysis of measurement and modeling showed the importance of reliable field measurements and
CFD simulations with a high spatial resolution to assess transport mechanisms in urban areas. 相似文献
47.
Defined polychlorinated terphenyl (PCT) single congeners as reference standards are the prerequisite for the development of analytical methods for their determination and quantification in the environment. The selective synthesis of PCTs for environmental analytical purposes by application of the Suzuki-coupling reaction is described. Under easily modified standard reaction conditions of this coupling process the PCTs can be obtained by reaction of benzeneboronic acids with dibromobenzenes mostly in good yields, as described by the synthesis of following PCT congeners: p-PCT (3,3("),5,5(")-tetrachloro-, 2,2("),4,4(")-tetrachloro-, 2('),3,3("),5,5(")-pentachloro-); m-PCT (3,3("),5,5(")-tetrachloro-) and o-PCT (3,3("),5,5(")-tetrachloro-). The terphenyl congeners were characterized by NMR (1H, 13C)- and FT-IR-spectroscopy. Their purity was checked by GC/MS analysis. The experimental and quantum-chemically calculated FT-IR-spectra were compared and it was shown, that the determination of the chlorine substitution pattern in the terphenyl congeners by their typical absorption spectra is possible. 相似文献
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49.
Marguerite Vogt 《Die Naturwissenschaften》1941,29(48):725-726
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