污泥龄对LSP & PNR污泥减量新工艺运行效能的影响

通过研究分析污泥龄（SRT）对富磷污水除磷的LSP&PNR污泥减量新工艺运行效果的影响,结果发现,延长污泥龄有利于提高系统的厌氧释磷能力,但不影响其总的除磷率,同时磷的回收比例增大,当SRT=50 d时,磷回收率取得最大值70.4％;LSP&PNR系统污泥龄增加,还有利于污泥产率的降低。试验还发现,排富磷污水除磷的长污泥龄LSP&PNR系统的除磷效率与污泥产率之间不存在制约关系,即系统可以同时获得优异的污泥减量与生物除磷效果,当SRT=50 d时,每降解1 kg COD仅产生0.143 kg污泥,而除磷率达最高值928％;LSP&PNR系统中SRT、DO与SVI之间存在一定的相关性,在供氧充足（DO＝0.8～1.5 mg/L）条件下,SRT增加,SVI越高,但对于SRT为50 d的LSP&PNR系统,稳定运行时没有污泥膨胀之虞。     

西安市地面沉降成因机理中的若干问题探讨

针对西安市区的地质环境和地面沉降特征,总结国内外与此相关的研究成果,重点从土层渗流与变形特性、地面沉降和地裂缝的关系、下部地层压密与地面变形关系以及开采地热资源对地面沉降的影响等几个方面分析西安市区地面沉降研究的现状及存在的问题,并针对这些问题提出了几点建议.     

Partitioning of hydrogen peroxide between the gas and liquid phases in the presence of surfactant

Gas-liquid phase partitioning is a key physical property that can predict the environmental fate of a compound between two phases. Several environmental factors have been known to affect the gas-liquid phase partitioning. We investigated the influence of surfactant on the gas-liquid phase partitioning of hydrogen peroxide (H(2)O(2)). The surfactant used was ammonium perfluorooctanoate (APFO). H(2)O(2) solution containing the surfactant was equilibrated in a closed system and gas phase H(2)O(2) concentration was measured by the peroxyoxalate chemiluminescence (PO-CL) method. Gas phase H(2)O(2) concentrations remained constant below the critical micelle concentration (CMC) and increased linearly with surfactant concentration above the CMC, which indicated that surfactant micelles influenced the gas-liquid phase partitioning of H(2)O(2). This result showed that H(2)O(2)-micelle interactions are less favorable than H(2)O(2)-H(2)O interactions. Surfactant monomers did not affect the gas-liquid phase partitioning of H(2)O(2) due to the absence of micelles. Solvent (methanol) effect was also investigated and showed that gas phase H(2)O(2) concentrations increased with the addition of solvent. This indicated the unfavorable interaction of H(2)O(2) with hydrophobic medium compared to hydrophilic one. It is consistent with the result that H(2)O(2)-micelles has a weaker interaction than H(2)O(2)-water because surfactant micelles are hydrocarbon-like organic phase rather than aqueous phase.     

Aerobic degradation of bisphenol A by Achromobacter xylosoxidans strain B-16 isolated from compost leachate of municipal solid waste

A novel bacterium designated strain B-16 was isolated from the compost leachate of the municipal solid waste (MSW) in a laboratory reactor. This strain was identified as a gram-negative bacterium, Achromobacter xylosoxidans that could grow on bisphenol A (BPA, a representative endocrine disruptor) as a sole carbon source under aerobic condition. BPA-degrading characteristics of strain B-16 were investigated in liquid cultures. The results show that BPA degradation was influenced by several factors (e.g. inoculum size, substrate concentration, temperature and pH, etc). The half-lives, optimum temperature and pH were found to be 0.58-3.1d, 35 degrees C and 7.0, respectively. BPA-degrading activity and cell growth were inhibited at high substrate concentration. Metabolic intermediates detected during the degradation process were identified as p-hydroxybenzaldehyde, p-hydroxybenzoic acid and p-hydroquinone, respectively. Metabolic pathway of BPA degradation was proposed in this study.     

Catalytic activity of Ru/Al2O3 for ozonation of dimethyl phthalate in aqueous solution

With dimethyl phthalate as the model pollutant and Ru/Al(2)O(3) as catalyst, this paper systemically investigates the removal of total organic carbon (TOC) of system. Our results have confirmed that Ru/Al(2)O(3) can significantly increase the effect of ozonation. TOC removal in 120 min can reach 72% while only 24% with ozone alone. The optimal catalyst preparing condition was 0.1 wt% Ru content, 600 degrees C calcination temperature, 0.5-1.0mm particle diameter, which is characterized by a high surface area and a large population of surface active sites. The contrasting experiments of ozone alone, catalyst adsorption after ozonation, and catalytic ozonation confirmed that catalytic reaction was the most important process to TOC removal in system with Ru/Al(2)O(3) as catalyst.     

塔里木河干流农田排水资源化研究

近几十年分析资料对比表明 ,农田排水对塔里木河干流水质盐化的影响不断加重。在塔里木河干流 ,农田排水资源化利用有如下几个有利条件 :( 1)农田排水有一定数量且渠网的延伸和改造难度不大 ;( 2 )荒漠可作为农田排水资源化利用的场所 ;( 3)农田排水仍可勉强适于耐盐植物生长。根据区域不同 ,利用农田排水拓展乔灌草防沙带、增加盐成土荒漠耐盐植被的盖度、使人工绿洲边缘的荒漠能够生长耐盐植物等都是农田排水资源化利用发展的方向     

固相萃取-气相色谱法测定水中硝基氯苯类化合物

建立固相萃取-气相色谱法测定水中15种硝基氯苯类化合物的方法。选用HLB柱为固相萃取柱,选用环己烷∶丙酮(3∶1,V∶V)混合溶剂作洗脱剂,得到方法检出限为0.011～0.040μg/L。空白水样加标回收率为73.6%～119%,相对标准偏差为6.1%～13.9%,精密度和准确度良好。对成分不复杂的实际水样进行测定,加标回收率为64.1%～118%,相对标准偏差为5.8%～15.6%,该方法能够基本满足成分不复杂的环境水体中痕量硝基氯苯类化合物的测定。     

生态工程建设背景下贵州高原的植被变化及影响因素分析

基于MODIS-NDVI和气象数据,运用趋势分析、偏相关分析和残差分析等方法,对生态工程建设背景下贵州高原的植被变化及影响因素进行分析,并定量探讨气候因素与人类活动对植被变化的影响。结果表明：(1)2000~2016年期间,贵州高原植被NDVI在空间上呈东高西低的分布特征,高值分布于野生动植物及自然保护区等,低值分布于湿地保护工程区。NDVI总体呈上升趋势,湿地保护工程区、退耕还林工程区等植被覆盖上升速率较快,野生动植物及自然保护区呈略微的下降趋势。(2)植被改善区域(83.74%)分布于研究区边缘及西北部,退化区域(16.26%)分布于研究区中部和东南部,其中退耕还林还草工程区植被改善最为明显,野生动植物保护及自然保护区和速生丰产工程区改善效果较差。(3)从气侯因素分析来看,气温和降水在总体上与NDVI均呈正相关,气温对贵州高原植被生长的影响大于降水。(4) 从人类活动分析来看,人类活动对植被的建设作用强于破坏作用,人类活动正作用（76.68%）主要分布于西北部,负作用（23.32%）集中分布于东南部。植被覆盖增加是气候因素和人类活动共同作用的结果,人类活动对植被的贡献率为75.53%,气候因素为24.47%。     

氨废水资源化利用的折流式超重力床集成技术

利用折流式超重力床将氨废水处理的精馏和吸收过程集成在一台设备中,开发出一种设备小型化、流程紧凑的氨废水资源化利用集成技术。与传统技术相比,该技术在大幅节省占地面积和空间的同时,还可大幅节约设备建设所用钢材。工业规模试验结果表明,不同浓度的氨废水经该技术处理后可转化为氨质量分数大于22%的氨水资源,处理出水中氨氮质量浓度低于8.2 mg/L,尾气中未检测到氨,处理结果优于GB 31573—2015《无机化学工业污染物排放标准》。