Degradation characteristics and metabolic pathway of 4-nitrophenol by a halotolerant bacterium Arthrobacter sp. CN2

Arthrobacter sp. strain CN2, capable of degrading 4-nitrophenol, was isolated from activated sludge. Degradation of 4-nitrophenol was optimized at pH 7.7, 30?°C, and 0.53% of glucose. Salt tolerance of 4-nitrophenol degradation was as high as 6% (w/v). Several biodegradation intermediates were identified and quantified by high-performance liquid chromatography and mass spectrometry. 4-Nitrocatechol is involved in the degradation of 4-nitrophenol by CN2. Scale-up of 4-nitrophenol degradation was conducted in a bioreactor with different salinity. When the salinity was below 7%, the degradation rate of 4-nitrophenol was above 90% (100 mg L^?1, 3 L).     

Numerical study of wave–current–vegetation interaction in coastal waters

Research on interactions among wave, current, and vegetation has received increasing attention. An explicit depth-averaged hydrodynamic model coupled with a wave spectral model (CMS-wave) was proposed in this study in order to simulate the wave and wave-induced current in coastal waters. The hydrodynamic model was based on the finite volume method while the intercell flux was computed by employing the Harten–Lax–van Leer approximate Riemann solver to investigate the dry-to-wet interface, and the drag force of vegetation was modeled as the sink terms in the momentum equations. The CMS-wave model was used to investigate the non-breaking and the breaking random waves propagation in vegetation fields. Afterwards, an empirical wave energy dissipation term with plant effect was derived to represent the resistance induced by aquatic vegetation in the wave-action balance equation. The established model was calibrated and validated with both the experimental and field data. The results showed that the wave height decreased significantly along the wave propagation direction in the presence of vegetations. The sensitivity analysis for the plant density, the wave height, and the water depth were performed by comparing the numerical results for the wave height attenuation. In addition, wave and wave-induced current through a finite patch of vegetation in the surf zone were investigated as well. The strong radiation stress gradient could be produced due to the variation of the energy dissipation by vegetation effect in the nearshore zone, which impacted the direction and amplitude of the longshore current. The calculated results showed that the coupling model had good performance in predicting wave propagation and the current over vegetated water regions.     

Laboratory study investigating the regeneration potential of iron particles by and the hydrodynamics of a dam-break generated flow from an infinite reservoir into a channel with an adverse slope

To determine the feasibility of using a dam-break generated flow from the sea into a storm-drain to aid in the regeneration of iron particles that control the production of H₂S in the storm-drain, a laboratory experimental investigation is carried out to measure the regeneration potential and the detailed hydrodynamics of the dam-break generated flow that causes the regeneration. The experiments are carried out using a reservoir of essentially infinite size, the sea, and a channel of limited width and adverse slope 1:20, the storm-drain. The regeneration experiments confirmed the ability of the dam-break generated flow to aid in the regeneration of the iron particles, however the regeneration potential varies from good to poor with distance away from the gate into the channel. The detailed measurements of the hydrodynamics highlighted that the dam-break generated flow from an infinite reservoir diverges little during the first uprush, has much smaller velocities during the first backwash and includes significant free surface waves. An initially wet channel bed reduces the flux into the channel. Close to the gate the flow depth increases more quickly but the velocity, and therefore the regeneration potential, is smaller.     

On the front conditions for gravity currents in channels of general cross-section

We consider the propagation of a high-Reynolds-number gravity current in a horizontal channel with general cross-section whose width is \(f(z), 0 \le z\le H\), and the gravity acceleration g acts in \(-z\) direction. (The classical rectangular cross-section is covered by the particular case \(f(z) =\) const.) We assume a two-layer system of homogeneous fluids of constant densities \(\rho _{c}\) (current, of height \(h < H \)) and smaller \(\rho _{a}\) (ambient, filling the remaining part of the channel). We focus attention on the calculation and assessment of the nose Froude-number condition \(Fr = U/(g' h)^{1/2}\); here U is the speed of propagation of the current and \(g' = (\rho _{c}/\rho _{a}-1) g\) is the reduced gravity. We first revisit the steady-state current, and derive compact insightful expressions of Fr and energy dissipation as a function of \(\varphi \) (\(=\) area fraction occupied by the current in the cross-section). We show that the head loss \(\delta _0\) on the stagnation line is formally a degree of freedom in the determination of \(Fr(\varphi )\), and we clarify the strong connections with the head loss \(\delta \) in the ambient fluid, and with the overall rate of dissipation \(\dot{{\mathcal{D}}}\). We demonstrate that the closure \(\delta _0 = 0\) [suggested by Benjamin (J Fluid Mech 31, 209–248, 1968) for the rectangular cross-section] produces in general the smallest Fr for a given \(\varphi \); the results are valid for a significant range \([0, \varphi _{\max }]\), in which the current is dissipative, except for the point \(\varphi _{\max }\) where \(\delta = \dot{{\mathcal{D}}} = 0\). We show that imposing the closure \(\delta = \dot{{\mathcal{D}}} = 0\), which corresponds to an energy-conserving or non-dissipative current, produces in general unacceptable restrictions of the range of validity, and large values of Fr; in particular, deep currents (\(\varphi < 0.3\) say) must be excluded because they are inherently dissipative. On the other hand, the compromise closure \(\delta (\varphi ) =\delta _0(\varphi )\) produces the simple \(Fr(\varphi ) = \sqrt{2}(1 - \varphi )\) formula whose values and dissipation properties are very close, and the range of validity is identical, to these obtained with Benjamin’s closure (moreover, we show that this corresponds to circulation-conservation solutions). The results are illustrated for practical cross-section geometries (rectangle, \(\Delta \) and \(\nabla \) triangle, circle, and the general power-law \(f(z) = b z ^\alpha \) (\(b>0, \alpha \ge 0, 0< z \le H\)). Next, we investigate the connection of the steady-state results with the time-dependent current, and show that in a lock-released current the rate of dissipation of the system is equal to, or larger than, that obtained for Fr corresponding to the conditions at the nose of the current. The results and insights of this study cover a wide range of cross-section geometry and apply to both Boussinesq and non-Boussinesq systems; they reveal a remarkable robustness of Fr as a function of \(\varphi \).     

Bayesian analysis of Jolly-Seber type models

We propose the use of finite mixtures of continuous distributions in modelling the process by which new individuals, that arrive in groups, become part of a wildlife population. We demonstrate this approach using a data set of migrating semipalmated sandpipers (Calidris pussila) for which we extend existing stopover models to allow for individuals to have different behaviour in terms of their stopover duration at the site. We demonstrate the use of reversible jump MCMC methods to derive posterior distributions for the model parameters and the models, simultaneously. The algorithm moves between models with different numbers of arrival groups as well as between models with different numbers of behavioural groups. The approach is shown to provide new ecological insights about the stopover behaviour of semipalmated sandpipers but is generally applicable to any population in which animals arrive in groups and potentially exhibit heterogeneity in terms of one or more other processes.     

Estimating abundance: a non parametric mark recapture approach for open and closed systems

We present a novel, non-parametric, frequentist approach for capture-recapture data based on a ratio estimator, which offers several advantages. First, as a non-parametric model, it does not require a known underlying distribution for parameters nor the associated assumptions, eliminating the need for post-hoc corrections or additional modeling to account for heterogeneity and other violated assumptions. Second, the model explicitly deals with dependence of trials by considering trials to be dependent; therefore, cluster sampling is handled naturally and additional adjustments are not necessary. Third, it accounts for ordering, utilizing the fact that a system with a small population will have a greater frequency of recaptures “early” in the survey work compared to an identical system with a larger population. We provide mathematical proof that our estimator attains asymptotic minimum variance under open systems. We apply the model to a data set of bottlenose dolphins (Tursiops truncatus) and compare results to those from classic closed models. We show that the model has an impressive rate of convergence and demonstrate that there’s an inverse relationship between population size and the proportion of the population that need to be sampled, while achieving the same degree of accuracy for abundance estimates. The model is flexible and can apply to ecological situations as well as other situations that lend themselves to capture recapture sampling.     

Sparse PCA and investigation of multi-elements compositional repositories: theory and applications

The geochemistry of floodplain sediments is fundamental to monitor environmental changes and to quantify their contribution to natural and anthropic processes. A floodplain sediment composition is a vector of positive elements which sum to a fixed constant. The analysis of high-dimensional compositions requires methods that produce results involving only a small portion of the original variables. On the other hand, the analysis must take into account the additional constraints specific to compositions. With the purpose of studying these problems, a new procedure for sparse PCA is proposed on European floodplain sediment samples.     

Analysis and prediction of $$\mathrm{PM}_{10}$$ concentration levels in Tunisia using statistical learning approaches

Over the past years, the health impact of airborne particulate matter \(\mathrm{PM}_{10}\) has become a very topical subject. Thereby, a lot of research effort in the environmental sciences goes towards the modeling and the prediction of ambient \(\mathrm{PM}_{10}\) concentrations. In this paper, we are interested in the statistical classification of the daily mean \(\mathrm{PM}_{10}\) concentration in Tunisia according to the authority regulation. We consider two monitoring stations: a big industrial station and a traffic station. The main goal of this work is to determine the pertinent predictors of \(\mathrm{PM}_{10}\) concentration within a nonlinear multiclass framework. To do this, we used two popular statistical learning methods; the support vector machines (SVM) and the random forests (RF). The statistical results obtained on the real datasets, show that RF outperform SVM for the purpose of variable selection even with a reduced number of observations compared to the number of explicative variables. It was also demonstrated that the \(\mathrm{PM}_{10}\) concentration measured yesterday is the most relevant predictor of its present-day value. Moreover, we found that the more delayed values of \(\mathrm{PM}_{10}\) concentration may be crucial to get an accurate prediction.     

Vertical oil dispersion profile under non-breaking regular waves

An experimental program was conducted to investigate vertical oil dispersion of surface oil spills under non-breaking regular waves. The variation in oil concentration caused by oil dispersion in a water column was studied to determine the vertical oil dispersion profile. The experiments were performed using different waves characteristics for different volumes of oil spill to evaluate the variation in oil concentration at three depths at two sampling stations. The correlations between oil concentration and the main parameters of wave characteristics, oil spill volume, sampling depth, and distance of sampling stations to spill location were assessed. The results revealed that the trend of variation in oil concentration versus wave steepness is linear. The results obtained from experimental measurements indicated that the oil concentrations at mid-depth were 44–77 % and the concentrations near the flume bed were 12–33 % of the concentration near the water surface.