Groundwater quality under the influence of spent mushroom substrate weathering

Nitrate and other solutes resulting from field-weathering of spent mushroom substrate (SMS) percolate into underlying soils and may migrate to groundwater. A field trial was conducted to investigate the potential influences of SMS weathering on groundwater quality. Spent mushroom substrate was deposited at 90 and 150 cm pile depths over a Typic Hapludult and weathered for 2 years. Eight casing wells were installed around the SMS piles to monitor the quality changes of groundwater with a high seasonal water table of 760 cm below the surface. Although leachate solutes had moved more than 200 cm deep in soil from the surface, no significant changes of groundwater quality caused by SMS weathering were observed even one year after removal of the SMS piles (3 years total). The groundwater had pH, electrical conductivity (EC) and dissolved organic carbon (DOC) of 4.3-5.7, 0.2-0.3 dS m(-1) and 0.7-2.2 mg L(-1), respectively. The major inorganic ions were Mg(2+), Ca(2+), Na(+), Cl(-), SO(4)(2-) and NO(3)(-), with a concentration range of 2.5-68.3 mg L(-1). The results suggest that SMS leachate solutes migrated fairly slow in deep subsurface soils of the experimental field. Considering that leachate solutes may move several meters in soil through preferential flow channels, weathering of SMS in fields with a high seasonal groundwater table >or=5 m below the ground is recommended. Conservatively, SMS weathering should be conducted on compact surfaces and leachate be collected and reused as liquid fertilizers.     

城市空气质量日报自动发布系统的研究与开发

详细介绍了“城市空气质量日报自动发布系统”的开发背景和开发过程 ,并对系统整体的架构和所用到的技术作了针对性的说明 ,阐明了作者对此类系统的前景和发展方向的看法。     

林格曼数监测存在的问题及时间——林格曼数计算方法的探讨

分析并讨论了目前国内关于锅炉烟尘林格曼数（黑度级）监测计算几种取值方法存在的问题，对时间－林格曼数这一新的取值方法进行了探讨。     

微波消解-氢化物发生原子荧光光谱法测定生活污水中的微量砷

采用硝酸-高氯酸微波消解水样,在盐酸介质中以硫脲-抗坏血酸处理样品,以硼氰化钾的氢氧化钠溶液为还原剂,氢化物发生原子荧光光谱法测定生活污水中的痕量砷.方法检出限＜0.02μg/L,精密度0.14%,加标回收率92%～108%,操作简单,结果准确,重现性好.     

库仑滴定法测定一氧化碳

本文就一氧化碳的测定条件和CO氧化过程中氧化剂的选择进行了研究。试验表明:ReAO_4-Ⅱ为氧化CO的活性催化剂,转化率可达100％(在300℃以上),本法简便,可用于空气中一氧化碳的测定和催化剂对CO活性测试。     

Removal of high concentrated ammonia nitrogen from landfill leachate by landfilled waste layer

The landfill of municipal solid waste(MSW) could be regarded as denitrification reactor and involved in ammonia nitrogen biological removal process. In this research, the process was applied to municipal solid waste collected in Shanghai, China, which was characterized by high food waste content. The NH4^ removal efficiency in the system of SBR nitrifying reactor followed by fresh and matured landfilled waste layer in series was studied. In the nitrifying reactor, above 90% of NH4^ in leachate was oxidized to NO2^- and NO3^- . Then high concentrated NO2^- and NO3^- were removed in the way of denitrification process in fresh landfilled waste layer. At the same time, degradation of fresh landfilled waste was accelerated. Up to the day 120, 136.5 gC/(kg dry waste) and 17.9 gN/(kg dry waste) were converted from waste layer. It accounted for 50.15 % and 86.89 % of the total carbon and nitrogen content of preliminary fresh waste, which was 4.42 times and 5.17 times higher than that of reference column respectively. After filtering through matured landfilled waste, BOD5 concentration in leachate dropped to below 100 mg/L, which would not affect following nitrification adversely. Because the matured landfilled waste acted as a well methanogenic reactor, 23% of carbon produced accumulatively from fresh landfilled waste degradation was converted into CH4.     

对熏烟扩散模式应用的探讨

工程上应用的大气污染物扩散模式中 ,熏烟模式由于其非定常性而与其他扩散模式有很大的区别。正确处理模式中各参数及变量的相互关系才能客观地反映污染物对环境影响的结果。本研究通过对熏烟模式的非定常性和各参数、变量相互关系的分析 ,提出了正确使用该模式的方法     

Occurrence and congeners specific of poiychlorinated biphenyls in agricultural soils from Southern Jiangsu, China

A total of 198 agricultural soil samples were collected from Zhangjiagang and Changshu in Southern Jiangsu for analysis of 13 polychlorinated biphenyls (PCBs) in order to assess the levels of pollution, sources, area distribution, and potential risk for the environment. All methods were rigorously tested and an adequate quality control was ensured. Only one site had no PCBs residues, and the highest total PCBs concentration in the surface soils was 32.83 ng/g. The average concentration in all the soil samples was 4.13 ng/g, signaling low-level pollution. Tetra-, penta-, and hexa-chlorinated biphenyls were dominant species in soil samples, accounting for more than 75% ofΣPCBs in the soil samples. PCB118 was the most abundant congener in all the samples. The PCB118 was about 20% ofΣPCBs. The soil organic matter content showed only a weak correlation with the levels of all PCB congeners, in which a better correlation was noted for the more volatile lighter PCB congeners than for the heavier homologues. To a certain extent, the sources and land use seemed to influence the levels of PCBs.     

中国粮食产量不同风险类型的地理分布

论文以中国各省份、各地区历年粮食单产为基本资料,采用统计方法,以风险分析技术为核心,定义粮食产量风险评价指标。在此基础上采用迭代自组织动态聚类分析方法分别对全国地区级和省级粮食生产单元进行了减产风险要素分区和综合风险指数分区,分区的结果反映了粮食生产风险水平的区域分异与各地区孕灾环境、致灾因子性质和生产力水平有密切联系。     

圆杯—多边形杆复合挤压的上限研究

此文采用三次多项式表示的流线速度场和基元圆环技术相结合的混合流动模型对国杯—多边形截面杆型复合挤压进行了上限分析,得到挤压力的上限解,分析了杆部截面形状对复合挤压分流点位置及变形力的影响规律并对理论计算进行了实验验证.