Health risk assessment of groundwater nitrate contamination: a case study of a typical karst hydrogeological unit in East China

Environmental Science and Pollution Research - Nitrate pollution in rivers, lakes, shallow groundwater, and even deep groundwater occurs in many parts of the world. And, it’s essential to...     

产业发展、土地集约利用与城市土地扩张

城市土地扩张速度过快是当前中国社会需要解决的一个重要问题。利用2000～2014年中国30个省会城市的面板数据,实证检验了全国层面和区域层面下,产业发展、土地集约利用与城市土地扩张之间的关系,并重点分析了土地集约利用在其中的中介作用。研究表明:(1)就全国层面看,第三产业规模提升和产业结构升级会抑制城市土地的扩张,土地集约利用在其中发挥部分中介效应,且其对总效应的贡献率分别为10.3%和12.6%;(2)就区域层面看,第三产业规模提升和产业结构升级会通过提高土地集约利用水平对东部城市土地扩张产生间接负向影响;第二产业规模增加对中部城市土地扩张有直接的促进效果;(3)该研究揭示了不同产业发展类型对不同区域城市土地扩张的影响及其中的作用路径,并针对性的提出了一系列政策建议,这对控制我国城市土地的过度扩张具有现实的指导意义。     

Understanding of regional air pollution over China using CMAQ,part I performance evaluation and seasonal variation

The U.S. EPA Models-3 Community Multiscale Air Quality (CMAQ) modeling system with the process analysis tool is applied to China to study the seasonal variations and formation mechanisms of major air pollutants. Simulations show distinct seasonal variations, with higher surface concentrations of sulfur dioxide (SO₂), nitrogen dioxide (NO₂), and particulate matter with aerodynamic diameter less than or equal to 10 μm (PM₁₀), column mass of carbon monoxide (CO) and NO₂, and aerosol optical depth (AOD) in winter and fall than other seasons, and higher 1-h O₃ and troposphere ozone residual (TOR) in spring and summer than other seasons. Higher concentrations of most species occur over the eastern China, where the air pollutant emissions are the highest in China. Compared with surface observations, the simulated SO₂, NO₂, and PM₁₀ concentrations are underpredicted throughout the year with NMBs of up to ?51.8%, ?32.0%, and ?54.2%, respectively. Such large discrepancies can be attributed to the uncertainties in emissions, simulated meteorology, and deviation of observations based on air pollution index. Max. 1-h O₃ concentrations in Jan. and Jul. at 36-km are overpredicted with NMBs of 12.0% and 19.3% and agree well in Apr. and Oct. Simulated column variables can capture the high concentrations over the eastern China and low values in the central and western China. Underpredictions occur over the northeastern China for column CO in Apr., TOR in Jul., and AODs in both Apr. and Jul.; and overpredictions occur over the eastern China for column CO in Oct., NO₂ in Jan. and Oct., and AODs in Jan. and Oct. The simulations at 12-km show a finer structure in simulated concentrations than that at 36-km over higher polluted areas, but do not always give better performance than 36-km. Surface concentrations are more sensitive to grid resolution than column variables except for column NO₂, with higher sensitivity over mountain and coastal areas than other regions.     

服装热湿舒适性能评价方法综述1

评价服装热湿舒适性能的方法有很多,包括主观和客观评价,物理、生理和心理方面的评价,以及各种具体的评价方法,但是一直没有对这些方法进行全面汇总研究.本文正是基于以上目的,对于服装热湿舒适性能研究中所用到的评价方法及其适用性逐一分析,最后对全面评价服装热湿舒适性能给出建议.     

Phytoremediation of phenol using Polygonum orientale,including optimized conditions

Removing phenol from wastewater has become a major challenge of international concern. Phytoremediation is a novel and eco-friendly method and is attracting an increasing amount of attention for treating phenol in wastewater. We studied the ability of Polygonum orientale, which is frequently present around water bodies and in wetlands in China, to phytoremediate phenol. We determined the inhibition concentration for phenol on P. orientale using emergency toxicology experiments and morphological observations. Isothermal and kinetic models were created to assess the adsorption process involved in phenol removal. Comparison tests in sterile conditions demonstrated that metabolic removal was the main way in which the phenol concentrations were decreased, and removal by adsorption played a smaller role. An orthogonal test was performed to determine the optimum conditions under which P. orientale will remove phenol, and these were found to be an initial phenol concentration of 5 mg L^?1, 100 % natural light, and a 13-day treatment time. These results provide a theoretical basis for increasing our understanding of the mechanisms involved in the removal of phenol by P. orientale and will help in developing its application in the greening of urban areas to provide both phytoremediation and esthetic landscaping.     

Catalytic Activity of Biomorphic α-MoO(3) in the Degradation of Methyl Violet Dye

A network of fibers comprising orthorhombic molybdenum trioxide (α-MoO(3)) crystals were synthesized using paper as template via a biomorphic approach. The template was completely removed by annealing the sample at 600°C for 5?min. Monoclinic MoO(3) was formed and consequently converted into orthorhombic α-MoO(3) after prolonged annealing. Three milligrams of the biomorphic α-MoO(3) could degrade up to 90% of a methyl violet aqueous solution with a concentration of 20?mg/L under normal visible light. The size of the α-MoO(3) grains and the porosity of the biomorphic sample affected catalytic performance.     

紊动对水体中有机物降解影响的实验

利用专门设计的紊动诱发装置,对不同紊动强度水体进行了紊动对有机物生物降解影响的实验研究．通过３种不同紊动强度的实验,发现紊动对有机物的降解有明显的影响紊动强度越大,有机物的降解率和降解速度越大．通过对较高紊动强度水体的降解实验数据分析发现,在水体有紊动时,有机物的降解反应并不遵循一级反应动力学。     

多参量综合指标冲击地压预测技术研究

提出了"全局-区域-局部"多参量综合指标冲击地压预测技术,多种预测方法相互协调与配合、优势互补,形成空间上层次化全方位的预测体系,可极大提高冲击地压预测准确性。结合老虎台矿冲击地压发生机理与影响因素,提出利用微震法对采区全局范围内微震事件进行实时监测,划分具有冲击危险区域,全局范围预测冲击地压;利用电磁辐射法监测工作面及巷道近场围岩的应力场和煤岩变形破坏变化状况,确定近场围岩高冲击危险区域,局部范围预测冲击地压;采用矿压监测法和钻屑法对确定具有冲击危险的区域进行重点监测,判断冲击危险程度,对采取防治措施后的防冲效果进行检测;采用采空区气体分析法预测电磁辐射法和矿压观测法等无法监测到的采空区的冲击地压。实践证明:全局-区域-局部"多参量综合指标预测技术的各种预测方法在功能上表现出明显的互补特征,在老虎台矿的冲击地压预报中取得良好效果。     

党校的城市生态环境教育

本文论述了党校开展城市生态环境教育的重要意义,城市生态环境的特点,与城市发展的关系,提出了加强城市生态环境管理的对策。     

Pd/MCM-41催化水溶液中碘苯Ullmann反应的研究

以水溶剂中Ullmann反应为目标反应,设计具有纳米介孔结构的Pd/MCM-41作为其高效催化剂.与传统SiO2载体负载的Pd催化剂比较,该催化剂在以水为介质的碘苯偶合（Ullmann反应）中显示出优良的催化活性和对联苯的选择性.