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781.
Bai S Srikantaswamy S Krishnanandan V Naik OP 《Environmental monitoring and assessment》2012,184(1):239-249
Urban wastewater treatment leads to the generation of large quantities of biosolids. Accumulation of biosolids is a problem
of environmental relevance due to the existence of heavy metals in the biosolids. Determination of total metal in biosolid
provides information relating pollution levels. Determination of their mobilization capacity and behaviour in the environment
is an important task. An experimental approach commonly used for studying the mobility, transport and bioavailability of metal
in biosolids is the use of selective sequential extraction procedure. In the present study an attempt has been made to study
the heavy metal properties in biosolid samples collected from urban wastewater treatment plants located at Mysore, Karnataka.
Few heavy metals selected for the present study are cadmium, chromium, copper, iron, nickel and zinc. The concentration of
these metals in biosolids and their partition in different fractions are studied. The speciation of metals based on the sequential
extraction scheme was carried out. The concentration of heavy metals is lower than that established by European legislation.
The residual fraction has the maximum percentage of heavy metals whereas, only a small fraction of heavy metals (Fe, Zn and
Cd) are extracted in the most soluble fractions, exchangeable and carbonate fractions. 相似文献
782.
Concentration of heavy metals (Cd, Ni, Zn, Fe, Cu, Mn, Pb, Cr, Hg and As) in the waters of River Yamuna and in the soil of
agricultural fields along its course in Delhi are reported from 13 sites, spread through the Delhi stretch of Yamuna, starting
from the Wazirabad barrage till the Okhla barrage. Varying concentration of heavy metals was found. Peaks were observed in
samples collected downstream of Wazirabad and Okhla barrage, indicating the anthropogenic nature of the contamination. The
Wazirabad section of the river receives wastewater from Najafgarh and its supplementary drains, whereas the Shahdara drain
releases its pollution load upstream of the Okhla barrage. Average heavy metal concentration at different locations in the
river water varied in the order of Fe>Cr>Mn>Zn>Pb>Cu>Ni>Hg>As>Cd. The river basin soil shows higher level of contamination
with lesser variation than the water samples among sampling locations, thereby suggesting deposition over long periods of
time through the processes of adsorption and absorption. The average heavy metal concentration at different locations in soil
varied in the order of Fe>Mn>Zn>Cr>Pb>Ni>Hg>Cu>As>Cd. 相似文献
783.
de-la-Ossa-Carretero JA Del-Pilar-Ruso Y Giménez-Casalduero F Sánchez-Lizaso JL 《Environmental monitoring and assessment》2012,184(4):2133-2149
Physicochemical characteristics of sediment and benthic communities were studied in the proximity of seven sewage outfalls
with differences in flow and wastewater treatment in the Western Mediterranean Sea. Redox potential was the only abiotic parameter
which showed a pattern related with distance to outfalls, whereas granulometry, percentage of organic matter, metal concentrations
or pH did not show changes related with outfall presence. Benthic community analysis proved to be the most suitable monitoring
tool. The results showed that the highest impacted stations corresponded with those closest to outfall with the highest flow
and only pre-treatment, whilst a decrease of this tendency was detected in the locations where secondary treatment takes place.
Meta-analysis showed a decrease of amphipods and tanaids abundance as well as redox potential, as the indicators with the
clearest response to sewage presence. 相似文献
784.
The chemical forms and ecological risk of As were characterized in the sediment of the Daliao River System (DRS), which has
been affected by long-term intensive industrial, urban, and agricultural activities. Twenty-seven samples of surface sediment
were collected and analyzed for total As content and that of its chemical forms. The results indicated that the average total
As content in the sediment was 9.83 mg kg − 1 but that the levels ranged from 1.57 to 83.09 mg kg − 1. At the sites near cities, mining sites, and the estuary of the DRS, it is likely that adverse effects on aquatic organisms
occur, due to As levels in the sediment that are often higher than the threshold effect level and occasionally higher than
the probable effect level. A selectively sequential extraction indicated that the majority of As in the sediment was bound
to Fe oxides (62.1%), with moderate proportions of residual As (19.8%), specifically adsorbed As (17.9%), and a low proportion
of non-specifically adsorbed As (1.1%). In addition, the content of Fe in the sediment was positively and significantly correlated
with the contents of amorphous and crystalline Fe oxide-bound As, confirming the crucial role of Fe oxides in immobilizing
high amounts of As in superficial environments. The average molar ratio of As to Fe was 1.18 × 10 − 4 in the surface sediment of the DRS, similar to that of natural Fe oxides, but much lower than that of synthesized Schwertmannite.
Therefore, the release of As under reduced and low pH conditions can cause serious problems for water resources and for living
organisms. 相似文献
785.
The analysis of heavy metals is very important for assessing the feasibility of the agricultural utilization for the municipal
sludge. In this paper, a four-step sequential extraction method was applied to extract heavy metals (Cu, Zn, Mn, Cr, and Ni)
in municipal sludges from seven individual wastewater treatment plants located in Jilin and Heilongjiang Province, China,
for estimating the mobility and bioavailability of the metal ions in the agricultural application. The total concentrations
of heavy metals and their chemical fractions after the sequential extraction were determined. Principal component analysis
(PCA) was applied to analyze the relations of heavy metals fractions in the municipal sludges. Experimental results indicated
that the total concentrations of Cu, Zn, Cr, and Ni in all sludge samples were below the threshold values set out by the Chinese
legislation (GB18918-2002). Specially, Zn had a high bioavailability and mobility, Cu and Cr had potential bioavailability,
while Mn mainly existed in the residual fraction of municipal sludge. On the other hand, Ni had different mobility in different
municipal sludge. PCA results were confirmed by the environmental behavior of heavy metals. 相似文献
786.
Warren C Duzgoren-Aydin NS Weston J Willett KL 《Environmental monitoring and assessment》2012,184(2):1107-1119
Hurricanes are relatively frequent ecological disturbances that may cause potentially long-term impacts to the coastal environment.
Hurricane Katrina hit the Mississippi Gulf Coast in August 2005, and caused a storm surge with the potential to change the
trace element content of coastal surface sediments. In this study, surface estuarine and marine sediments were collected monthly
following the storm from ten sites along the Mississippi Gulf Coast (Mobile Bay, Grand Bay Bayous Heron and Cumbest, Pascagoula,
Ocean Springs, Biloxi Gulf, Back Biloxi Bay, Gulfport Gulf, Gulfport Courthouse Rd, and Gulfport Marina). Concentrations of
V, Cr, Mn, Fe, Co, Ni, Zn, As, Cd, and Pb were measured by inductively coupled plasma–mass spectrometry to evaluate their
temporal and spatial variations in the year following Hurricane Katrina. Sediments were characterized by pH, particle size
distribution and total carbon and nitrogen content. Trace element contents of the sediments were determined in both <2 mm
and <63 μm grain size fractions. Results revealed no significant temporal and spatial variability in trace element concentrations,
in either size fraction. Potential ecological risk of the sediments was assessed by using NOAA SQuiRTs’ guideline values;
most concentrations remained below probable adverse effects guidelines to marine organisms suggesting that trace elements
redistributed by Hurricane Katrina would not cause an adverse impact on resident organisms. Instead, the concentrations of
trace elements were site-dependent, with specific contaminants relating to the use of the area prior to Hurricane Katrina. 相似文献
787.
Karakaya and Sultansuyu Dam Lakes, located in the eastern part of Turkey, are important water sources, both for irrigation
and fishery. The main goal of the study was to investigate water qualities of dam lakes using a set of biomarkers in the fish
Cyprinus carpio. For this aim, field sample and laboratory-acclimated fish were compared to identify changes in selected biomarkers. The
activities of ethoxyresorufin-O-deethylase, glutathione S-transferase, glutathione reductase, and carboxylesterase were determined in liver samples. Also, plasma and liver lactate
dehydrogenase, aspartate aminotransferase, and alanine aminotransferase activities were assayed. Brain acetylcholinesterase
and carboxylesterase activities were also determined. The hepatosomatic index and condition factors were calculated. Plasma
vitellogenin assays were evaluated for the presence of xenoestrogen. Physicochemical values of water samples showed the existence
of eutrophication risk, and also, some chemicals in both lakes were determined to be over tolerable limits. The comparisons
of samples from both dam lake and laboratory-acclimated fish showed that the lakes may be at risk of pollution by some xenobiotics,
namely xenoestrogens and acetylcholinesterase-inhibiting agents. 相似文献
788.
杭州地区农业土壤中重金属的分布特征及其环境意义 总被引:1,自引:0,他引:1
为了分析杭州地区农业土壤重金属的分布特征及其环境意义,通过现场采样和室内分析检测的方法,对杭州市各区县不同作物农业土壤表层土中的Hg、As、Cu、Pb、Cr、Cd 6种重金属元素进行检测,并对其分布特征进行了分析。结果表明,杭州地区农业土壤中除As外,其他5种重金属的平均含量均低于且接近浙江省土壤背景值,个别采样点的重金属含量超过了土壤环境质量国家二级标准。总体上,杭州地区农业土壤处于安全水平。通过重金属的区域分布特征分析表明,余杭区和富阳市农业土壤中重金属平均含量普遍高于其他区域。萧山区和建德市部分农业土壤则存在Cu和Hg含量较高的情况,而淳安县农业土壤中重金属含量差异较大,土壤中出现了As、Cr和Cd含量最大值。不同作物的农业土壤重金属含量存在一定的差异,但不明显。水稻田和蔬菜地的土壤中,重金属含量较其他作物种植类型的土壤中含量高;叶菜类(蔬菜、茶叶)作物土壤中的Cd含量要比根茎类(水稻)、茄果类(水果)及其他作物种植类型的土壤中的含量低。目前杭州地区土壤中6种重金属含量均对作物的直接危害不大,但由于萧山区个别采样点Cu含量严重超标,淳安县土壤中Cd受外源性来源影响也已较明显,需要相关部门加大监管力度,防止污染事件发生。同时,为防止农业土壤中重金属含量进一步升高,需要加大大气降尘监测与治理、废气污染监管与控制治理。 相似文献
789.
根据GB/T 15000.3—2008设计了苯系物标准气体的时间稳定性研究方案,制备了4瓶苯系物标准气体,随着时间的推移进行测定并将结果制图,结果显示量值随时间没有显著的变化趋势。以线性关系为模型,计算线性直线的斜率和斜率的标准偏差,用t检验判断斜率是否显著来评价标准气体的稳定性。计算结果显示,所有斜率均不显著,因此该研究制备的苯系物标准气体能够稳定保存22个月。根据时间稳定性数据计算由不稳定性引起的不确定度,并讨论了这种计算不稳定性引起不确定度的方法对结果有放大的可能性。 相似文献
790.
北京市地下水污染源荷载影响评价 总被引:1,自引:0,他引:1
在阐述地下水污染源荷载影响基本概念的基础上,介绍了污染源荷载影响评价的3大要素:污染荷载等级、含水层敏感性及地下水价值,说明了评价体系、指标和方法及过程。根据主要污染源荷载分析,结合地下水环境现状,对北京市进行了分区,提出污染源管理措施。 相似文献