生物柴油对柴油机排放和人类健康的影响

综述了近年来生物柴油作为柴油机燃料时污染物排放特征的研究结果,以及使用生物柴油对环境和人类健康影响的研究.介绍了对生物柴油常规污染物和非常规污染物的重要研究成果,还介绍了目前关于生物柴油排放污染物的细胞毒性、致突变性的研究成果.     

Analysis of the changes of vegetation coverage of western Beijing mountainous areas using remote sensing and GIS

Mentougou District acts as a crucial component in the ecological buffer in western Beijing mountainous areas, Beijing, China. Using two Landsat MSS/TM images acquired on July 14, 1979 and July 23, 2005, the vegetation coverage of Mentougou District was calculated based on normalized difference vegetation index and spectral mixture analysis (NDVI-SMA) model. Its temporal and spatial changes were analyzed according to digital elevation model (DEM) image, social and economic data. The results showed that the vegetation coverage decreased from 76.4% in 1979 to 72.7% in 2005. Vegetation degradation was probably the result of human disturbance, such as outspreading of resident areas, and coal and stone mining activities, while vegetation restoration might be contributed by the combined effects of both natural processes and ecological construction effort. Vegetation changes were closely related to topographical characteristics. Plants at high altitude were more stable and less degraded than the plants at low altitude, while the plants on steep slope or northwest aspect were more vulnerable to degradation. During the period of 26 years, landscape appeared to become more fragmental, and ecological quality of the land seemed deteriorated sharply in that highly-covered vegetation area has been decreased by 24%.     

Preparation of a new Fenton-like catalyst from red mud using molasses wastewater as partial acidifying agent

Using molasses wastewater as partial acidifying agent, a new Fenton-like catalyst (ACRM _sm ) was prepared through a simple process of acidification and calcination using red mud as main material. With molasses wastewater, both the free alkali and the chemically bonded alkali in red mud were effectively removed under the action of H₂SO₄ and molasses wastewater, and the prepared ACRM _sm was a near-neutral catalyst. The ACRM _sm preparation conditions were as follows: for 3 g of red mud, 9 mL of 0.7 mol/L H₂SO₄ plus 2 g of molasses wastewater as the acidifying agent, calcination temperature 573 K, and calcination time 1 h. Iron phase of ACRM _sm was mainly α-Fe₂O₃ and trace amount of carbon existed in ACRM _sm . The addition of molasses wastewater not only effectively reduced the consumption of H₂SO₄ in acidification of red mud but also resulted in the generation of carbon and significantly improved the distribution of macropore in prepared ACRM _sm . It was found that near-neutral pH of catalyst, generated carbon, and wide distribution of macropore were the main reasons for the high catalytic activity of ACRM _sm . The generated carbon and wide distribution of macropore were entirely due to the molasses wastewater added. In degradation of orange II, ACRM _sm retained most of its catalytic stability and activity after five recycling times, indicating ACRM _sm had an excellent long-term stability in the Fenton-like process. Furthermore, the performance test of settling showed ACRM _sm had an excellent settleability. ACRM_sm was a safe and green catalytic material used in Fenton-like oxidation for wastewater treatment.

     

生态净化工艺在上海崇明农村污水的应用研究

介绍生态净化的工艺方法。通过在上海崇明前卫村建立示范工程,研究以高效生态纤维塘＋潜流式人工湿地组合工艺对有机污染物、氮、磷、浊度等去除效果与机理。结果表明,COD、TN、TP和浊度的平均去除率分别为53.4%、45.3%、49.8%和94.89%。去除有机污染物主要靠微生物代谢,氮的去除主要靠微生物硝化与反硝化,总磷主...     

Equilibrium and kinetics of adsorption of phosphate onto iron-doped activated carbon

Purpose

Two series of activated carbons modified by Fe (II) and Fe (III) (denoted as AC/N-Fe^II and AC/N-Fe^III), respectively, were used as adsorbents for the removal of phosphate in aqueous solutions.

Method

The synthesized adsorbent materials were investigated by different experimental analysis means. The adsorption of phosphate on activated carbons has been studied in kinetic and equilibrium conditions taking into account the adsorbate concentration, temperature, and solution pH as major influential factors.

Results

Maximum removals of phosphate are obtained in the pH range of 3.78?C6.84 for both adsorbents. Langmuir isotherm adsorption equation well describes the experimental adsorption isotherms. Kinetic studies revealed that the adsorption process followed a pseudo-second order kinetic model. Results suggest that the main phase formed in AC/N-Fe^II and AC/N-Fe^III is goethite and akaganeite, respectively; the presence of iron oxides significantly affected the surface area and the pore structure of the activated carbon.

Conclusions

Studies revealed that iron-doped activated carbons were effective in removing phosphate. AC/N-Fe^II has a higher phosphate removal capacity than AC/N-Fe^III, which could be attributed to its better intra-particle diffusion and higher binding energy. The activation energy for adsorption was calculated to be 22.23 and 10.89 kJ mol^?1 for AC/N-Fe^II and AC/N-Fe^III, respectively. The adsorption process was complex; both surface adsorption and intra-particle diffusion were simultaneously occurring during the process and contribute to the adsorption mechanism.     

高风险城市环境地铁小净距隧道近接隧道群施工方案优选

为优选高风险城市环境中小净距隧道近接施工方案,依托北京地铁19号线新草区间新建小净距隧道近接隧道群工程,利用有限差分软件FLAC3D,对工程采取管棚管幕预加固措施和改变施工顺序2种施工方案,并对2种方案下的位移控制效果进行研究.研究结果表明:采用管棚管幕预加固措施,并以东侧隧道完工后西侧隧道开挖的顺序施工,可有效控制位...     

Excitation-emission matrix (EEM) fluorescence spectroscopy for characterization of organic matter in membrane bioreactors: Principles,methods and applications

• Principles and methods for fluorescence EEM are systematically outlined. • Fluorophore peak/region/component and energy information can be extracted from EEM. • EEM can fingerprint the physical/chemical/biological properties of DOM in MBRs. • EEM is useful for tracking pollutant transformation and membrane retention/fouling. • Improvements are still needed to overcome limitations for further studies. The membrane bioreactor (MBR) technology is a rising star for wastewater treatment. The pollutant elimination and membrane fouling performances of MBRs are essentially related to the dissolved organic matter (DOM) in the system. Three-dimensional excitation-emission matrix (3D-EEM) fluorescence spectroscopy, a powerful tool for the rapid and sensitive characterization of DOM, has been extensively applied in MBR studies; however, only a limited portion of the EEM fingerprinting information was utilized. This paper revisits the principles and methods of fluorescence EEM, and reviews the recent progress in applying EEM to characterize DOM in MBR studies. We systematically introduced the information extracted from EEM by considering the fluorescence peak location/intensity, wavelength regional distribution, and spectral deconvolution (giving fluorescent component loadings/scores), and discussed how to use the information to interpret the chemical compositions, physiochemical properties, biological activities, membrane retention/fouling behaviors, and migration/transformation fates of DOM in MBR systems. In addition to conventional EEM indicators, novel fluorescent parameters are summarized for potential use, including quantum yield, Stokes shift, excited energy state, and fluorescence lifetime. The current limitations of EEM-based DOM characterization are also discussed, with possible measures proposed to improve applications in MBR monitoring.     

蒸发壁式超临界水氧化反应器处理分散红和活性红染料废水的比较

采用蒸发壁式超临界水氧化反应器对染料分散红C.I.60和活性艳红M-2B配制的模拟废水进行降解实验.实验结果表明,2种染料的COD和TN去除率随着反应温度、氧化剂过量比(r)的升高而上升.COD去除率活性红要高于分散红,而TN去除率则相反.根据GC-MS分析和陶瓷膜SEM图像,分析测得2种染料主要反应中间产物均含有苯酚和苯甲酸,2种染料的反应对陶瓷膜均有轻微的腐蚀.     

生物膜法A／O工艺A段脱氮动力学研究

研究了生物膜法A/O工艺A段的动力学模式，根据在碳源充足时，反硝化速率和硝酸盐浓度呈零级动力学反应，从理论得出A段Vmax、变化不大，膜单位面积传质速率（dF/dt)与基质浓度无关，与生物膜厚度（δ）成正比，dF/dt=k1A√C0-Ce,动力学参数k1=√CmaxX表明A段NO3^--N去除率与进出水浓度差的平方根和填料表面积成正比，并通过试验求出动力学系数，K1=0.016。     

数字水准仪DiNi11/12原理及应用中应注意的问题

本文介绍了数字水准仪的原理、特点,着重分析了对台站跨断层观测精度影响较大的几个因素,并结合台站工作实际提出了减弱这些影响的措施,实测结果表明:采取这些措施可以有效地提高测量精度.