农业生态系统的氮素循环研究进展

在自然和人为作用的双重驱动下,地球表面氮素的生物地球化学过程及其环境效应成为当前全球变化中区域研究的重要内容。探讨了氮素循环各个过程及其数量特征,对氮素循环模型进行了介绍,并对当前生态系统中氮素循环的研究热点进行了简要的论述。     

四川省卧龙地区土壤中二噁英类化合物和多氯萘的海拔梯度分布及对牦牛的毒性风险评价

初步研究了四川省卧龙地区5个不同海拔高度的表层土壤和2个牦牛样品中二噁英/呋喃(PCDD/Fs)、共平面多氯联苯(co-PCBs)和多氯萘(PCNs)的分布特征、来源、毒性当量以及生态风险状况.土壤样品中总2,3,7,8-PCDD/Fs的含量范围为2.48-4.30 pg·g-1dw,平均3.50 pg·g-1dw,最高含量在海拔3927 m的塘房.co-PCBs的总含量平均为9.14 pg·g-1dw,最高值在海拔4487 m的垭口.总2,3,7,8-PC-DD/Fs和总co-PCBs含量随海拔高度的变化表现出正相关关系.不同海拔高度土壤中的PCDD/Fs和co-PCBs异构体的分布相似,表明具有相同的来源.总PCNs与海拔梯度呈负相关关系,最高含量出现在海拔3345 m的贝母坪,平均21.4 pg·g-1dw,主要以3.氯为主.土壤中PcDD/Fs毒性当量浓度范围为0.29-0.43pg TEQ·g-1dw.牦牛肉和牦牛组织中PcDD,/Fs总浓度分别为27.5和23.6 pg·g-1脂肪,毒性当量浓度为4.04和4.07 pg TEQ·g-1脂肪.结果表明,牦牛中的PCDD/Fg,co-PcBs和PCNs不大可能对卧龙地区人群导致严重的负面效应.     

基于决策树的辽宁省北部沙漠化信息提取研究

以沙漠化问题较突出的辽宁省北部地区为例,选取2007年Landsat 5 TM遥感影像作为基本数据源,通过对影像中耕地、林地、草地、水域等常见地物及典型沙漠化土地进行光谱特征分析和波段间的相互运算,将修改型土壤调整植被指数（MSAVI）、归一化差异水体指数（NDWI）和遥感图像缨帽变换后的土壤亮度指数（SBI）、绿度植被指数（GVI）及湿度指数（WVI）等特征变量融入决策树分类模型后进行分层分离,从而实现对沙漠化信息的高精度提取。结果显示,决策树分类法可排除提取地物时的干扰信息,是保证沙漠化土地信息快速自动提取的方法之一。     

石灰性土壤中高效解磷细菌菌株的分离、筛选及组合

对石灰性土壤样品进行了解磷细菌的分离和筛选,得到具有明显溶磷圈的解磷细菌71株.分析了菌株分泌磷酸酶、释放速效磷及pH降低等综合因素和特征,研究了菌株生长动态.最后筛选出解磷能力较强且无拮抗反应的6株解磷细菌,并将其组合成为解磷细菌菌群.图8表2参17     

无瓣海桑和互花米草群落土壤化感作用比较

为揭示不同植物群落土壤在无瓣海桑(Sonneratia apetala)控制互花米草(Spartina alterniflora)中的作用,利用化感生物测定的方法,选用黑麦草(Lolium perenne)为受体,对比分析红树林无瓣海桑群落、互花米草群落以及无瓣海桑+互花米草群落土壤水提液的化感作用大小。结果表明3,种植物群落土壤水提液对黑麦草具有化感作用,无瓣海桑群落土壤和无瓣海桑+互花米草群落土壤水提液对黑麦草根长和苗高的影响表现出低促高抑的现象;ρ为0.25 g·mL-1的土壤水提液对黑麦草种子发芽和幼苗生长影响不大,1.0 g·mL-1土壤水提液对黑麦草根长和苗高产生显著影响,加入活性碳之后能减弱水提液的化感作用。ρ为0.25或0.5 g·mL-1条件下3,种土壤浸提液对黑麦草发芽率的影响无显著差异;ρ为1.0 g·mL-1的3种水提液都显著抑制黑麦草根长,而无瓣海桑群落土壤水提液表现出更强的化感作用,ρ为1.0 g·mL-1的土壤水提液显著抑制黑麦草苗高,无瓣海桑群落土壤对苗高的抑制作用显著强于互花米草群落土壤(P<0.01)。以黑麦草为受体,无瓣海桑群落土壤化感作用强于互花米草群落土壤,通过根系分...     

酸性条件下剩余污泥中Ca2＋和Mg2＋溶出对磷回收的影响

为了在酸性条件下实现剩余污泥中磷的高效回收,对pH=3时剩余污泥水解酸化过程中氨氮、正磷酸盐和钙镁离子的溶出现象以及磷回收进行了研究分析。结果表明：当pH=3时,所溶出的氨氮、镁离子和钙离子与磷酸盐的摩尔比均大于1,能满足采用鸟粪石沉淀法或者羟磷灰石沉淀法回收磷的要求;但所溶出的钙镁离子的摩尔比大于1,会对鸟粪石沉淀法回收磷的顺利进行有较大影响;有无外加镁剂对磷回收率影响不大。采用改型后的镁型强酸性阳离子交换树脂进行离子交换可以得到较高纯度的鸟粪石沉淀产品,通过XRD检测其纯度为95％以上。     

发酵鸡粪和有机磷肥对土壤中Pb、Cd污染的影响

研究了湘西地区常用的发酵鸡粪和有机磷肥施用对不同程度Pb、Cd复合污染土壤中乙三胺五醋酸(DTPA)提取态Pb(DTPA-Pb)、DTPA提取态Cd(DTPA-Cd)和土壤酶的影响,并研究了对于种植黑麦草(Lolium perenne L.)的影响。结果表明:(1)施用发酵鸡粪和有机磷肥均能显著改善土壤酸性,一定程度上提高土壤有机质含量。在加入质量浓度200mg/kg总Pb、2mg/kg总Cd复合污染土壤中施用有机磷肥,能有效钝化土壤DTPA-Pb、DTPA-Cd,但在400mg/kg总Pb、4mg/kg总Cd复合污染土壤中钝化效果有限,其优先钝化DTPA-Pb。施用发酵鸡粪不能有效钝化土壤DTPA-Pb、DTPA-Cd。(2)施用发酵鸡粪和有机磷肥均显著提高黑麦草鲜重。虽然施用有机磷肥能更有效的钝化土壤DTPA-Pb、DTPA-Cd,但对于黑麦草种植而言,施用发酵鸡粪能更有效的降低其对Pb和Cd的积累,并且主要积累到根部。(3)施用发酵鸡粪对土壤碱性磷酸酶活性、脱氢酶活性和脲酶活性有显著的促进作用。综合而言,湘西地区种植牧草黑麦草,施用发酵鸡粪比较合适,能有效改善土壤酸性,提高黑麦草鲜重和土壤酶活性,降低黑麦草对Pb和Cd的积累。     

Pollution characteristics of 23 veterinary antibiotics in livestock manure and manure-amended soils in Jiangsu province,China

The aim of this study was to investigate the pollution characteristics of typical veterinary antibiotics in manure and soil of livestock farms in Jiangsu province. This investigation employed solid-phase extraction (SPE) coupled with ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). A total of 53 manure and 50 amended soil samples from 16 livestock farms in Jiangsu province were collected for analysis. In the manure samples, the highest detected frequencies and concentrations were those of tetracyclines (TCs, 54.1 ± 5775.6 μgkg^?1), followed by fluoroquinolones (FQs, 8.4 ± 435.6 μgkg^?1), sulphonamides (SAs, 3.2 ± 5.2 μgkg^?1) and macrolides (MACs, 0.4 ± 110.5 μgkg^?1). Statistical analysis was used to illuminate the pollution characteristics of 23 veterinary antibiotics for various animal types and different regions in Jiangsu province. The results showed that the pollution level in cow manure was relatively lower compared with pig and chicken manure due to the relative restriction of medication. Furthermore, contamination was serious in amended soil from chicken farms. The pollution level in manure among different regions was higher to the south and north compared with the centre of the region. The same outcome was found for soil. Antibiotic residues in organic fertilizer were also investigated in this study. We found that although the detected concentration was lower in organic fertilizer than in fresh manure, detection frequencies (10–90%) were high, especially for roxithromycin (90%) in MACs (30–90%). This finding suggests attention should be paid to the pollution levels in organic fertilizer. This study is the first extensive investigation of the occurrence and distribution of many kinds of typical veterinary antibiotics in manure and soil from livestock farms of Jiangsu province. This investigation systematically assesses veterinary antibiotics usage and related emissions in southeast China.     

内配型钢的圆钢管混凝土轴压构件的耐火性能

在钢管混凝土构件中内置型钢可有效提高整个构件的承载力和耐火性能。采用ABAQUS软件建立了标准火灾下内配型钢的圆钢管混凝土轴压构件的热力耦合数值模型,并与已有研究者完成的试验数据进行了对比验证;在此基础上,计算了火灾作用下该类构件柱顶轴向位移和跨中挠度随升温时间变化的关系曲线,根据破坏特征可以分为升温初期膨胀阶段、轴向压缩阶段和破坏阶段,并确定了该类构件的耐火极限;最后计算了火灾作用下每个组件间的相互作用力和参数分析。结果表明:随着温度的升高,钢管与混凝土、混凝土与型钢之间的接触应力呈降低趋势;火灾荷载比、长细比、钢管含钢率及防火保护层厚度对构件耐火极限影响较为显著。     

Adsorption-desorption characteristics of mercury in paddy soils of China

Mercury (Hg) has received considerable attention because of its association with various human health problems. Adsorption-desorption behavior of Hg at contaminated levels in two paddy soils was investigated. The two representative soils for rice production in China, locally referred to as a yellowish red soil (YRS) and silty loam soil (SLS) and classified as Gleyi-Stagnic Anthrosols in FAO/UNESCO nomenclature, were respectively collected from Jiaxin County and Xiasha District of Hangzhou City, Zhejiang Province. The YRS adsorbed more Hg(2+) than the SLS. The characteristics of Hg adsorption could be described by the simple Langmuir adsorption equation (r2 = 0.999 and 0.999, P < 0.01, respectively, for the SLS and YRS). The maximum adsorption values (Xm) that were obtained from the simple Langmuir model were 111 and 213 mg Hg(2+) kg(-1) soil, respectively, for the SLS and YRS. Adsorption of Hg(2+) decreased soil pH by 0.75 unit for the SLS soil and 0.91 unit for the YRS soil at the highest loading. The distribution coefficient (kd) of Hg in the soil decreased exponentially with increasing Hg(2+) loading. After five successive desorptions with 0.01 mol L(-1) KCl solution (pH 5.4), 0 to 24.4% of the total adsorbed Hg(2+) in the SLS soil was desorbed and the corresponding value of the YRS soil was 0 to 14.4%, indicating that the SLS soil had a lower affinity for Hg(2+) than the YRS soil at the same Hg(2+) loading. Different mechanisms are likely involved in Hg(2+) adsorption-desorption at different levels of Hg(2+) loading and between the two soils.