回收电解锰渣中的可溶性锰

以电解锰渣滤液为实验原料,研究了利用二氧化碳和氨水回收锰渣滤液中可溶性锰的工艺,实验结果表明:当n(氨水):n(可溶性锰)为2.50、二氧化碳曝气流量为50 L/h、曝气时间为5 min、振荡时间为60 min时,可溶性锰回收率达75%以上;对沉淀物进行X射线衍射分析,碳酸锰纯度接近100%。1kg电解锰渣可回收27 mg碳酸锰。     

中国石油HSE专业标准化工作探讨

简要回顾了中国石油HSE标准化工作的历程,综合分析了HSE标准化工作面临的形势任务,对改进中国石油HSE标准化工作思路进行了探讨,明确了指导思想、遵循原则、重点工作,并提出做好HSE标准化工作要处理好四个方面关系的原则。     

Dynamics of mercury fluxes and their controlling factors in large Hg-polluted floodplain areas

Environmental pollution by mercury (Hg) is a considerable environmental problem world-wide. Due to the occurrence of Hg volatilization from their soils, floodplains can function as an important source of volatile Hg. Soil temperature and soil water content related to flood dynamics are considered as important factors affecting seasonal dynamics of total gaseous mercury (TGM) fluxes. We quantified seasonal variations of TGM fluxes and conducted a laboratory microcosm experiment to assess the effect of temperature and moisture on TGM fluxes in heavily polluted floodplain soils. Observed TGM emissions ranged from 10 to 850 ng m⁻² h⁻¹ and extremely exceeded the emissions of non-polluted sites. TGM emissions increased exponentially with raised air and soil temperatures in both field (R²: 0.49-0.70) and laboratory (R²: 0.99) experiments. Wet soil material showed higher TGM fluxes, whereas the role of soil water content was affected by sampling time during the microcosm experiments.     

生态功能区划在县域可持续发展指标体系中的应用

在分析县域可持续发展指标体系特点的基础上,从生态功能区划依据的原则、目标等方面,深入论述了生态功能区划在县域可持续发展指标体系中的三方面作用,提出了应用生态功能区划结果对某一区域内不同县域的可持续发展状况分类别进行评价的观点。     

景观富营养水体生态修复对浮游植物群落结构的影响

对以再生水为补给水源的北京稻香湖园林水系进行生态修复实验。通过对浮游植物群落和理化指标的分析,探讨浮游植物对生态修复的响应和修复效果。结果显示,生态修复实验实施后,TN、TP、COD和BOD5分别下降62.55%、66.42%、48.53%和40.95%,富营养程度明显降低;浮游植物密度和Chl-a含量分别下降86.1%和77.4%;Shan-non-Weaver物种多样性指数值从生态修复前低于2上升到2.74,且优势种群发生演替。相关分析表明:TP、PO4-P、pH与浮游植物密度呈极显著正相关(P(0.01);TN、NH4-N、NO2-N、COD和DO与浮游植物密度呈显著正相关(P(0.05);Chl-a含量与浮游植物密度呈极显著正相关(P(0.01)。浮游植物群落结构对城市富营养景观水系的生态修复措施表现出明显的响应。     

调理剂和通风方式对污泥生物干化效果的影响

采用了自主设计的污泥生物干化实验室模拟系统,研究了调理剂、物料配比和通风方式等实验条件对脱水污泥生物干化的影响效果。研究结果表明,与锯末相比,秸秆有利于反应物料温度的上升,含水率下降程度更大;利用秸秆调节污泥初始含水率在60%和65%的实验条件下时,物料的平均含水率分别下降了7%和6%,当初始含水率65%时,生物堆体的温度和含水率没有明显的变化;与连续通风相比较,间歇通风的实验条件有利于生物堆体的温度的升高和干化效果;在该实验中,最佳的生物干化条件是以秸秆为调理剂,初始含水率调至65%以下,以间歇方式进行通风。     

冬季燃油节能降耗设备的研制与应用

新疆等西北地区冬季时间长,温度低,由于--35#柴油的价格比0#柴油高,但其燃烧值低于0#柴油,因此考虑用0#柴油代替--35#柴油,以降低钻井成本。回收350℃高温尾气中的热量,进行水罐加热,使水温达到60℃;然后用60℃热水对0#柴油罐进行加热和保温,使油温达到30℃。达到在冬季用0#柴油代替--35#柴油的目的,使尾气回收利用设备不需要另外的能量补给。     

Solvent extraction for heavy crude oil removal from contaminated soils

A new strategy of heavy crude oil removal from contaminated soils was studied. The hexane-acetone solvent mixture was used to investigate the ability of solvent extraction technique for cleaning up soils under various extraction conditions. The mixtures of hexane and acetone (25 vol%) were demonstrated to be the most effective in removing petroleum hydrocarbons from contaminated soils and approx 90% of saturates, naphthene aromatics, polar aromatics, and 60% of nC₇-asphaltenes were removed. Kinetic experiments demonstrated that the equilibrium was reached in 5 min and the majority of the oil pollutants were removed within 0.5 min. The effect of the ratio between solvent and soil on the extraction efficiency was also studied and results showed that the efficiency would increase following the higher solvent soil ratio. Then the multistage continuous extraction was considered to enhance the removal efficiency of oil pollutants. Three stages crosscurrent and countercurrent solvent extraction with the solvent soil ratio 6:1 removed 97% oil contaminants from soil. Clearly the results showed that the mixed-solvent of hexane and acetone (25 vol%) with character of low-toxic, acceptable cost and high efficiency was promising in solvent extraction to remove heavy oil fractions as well as petroleum hydrocarbons from contaminated soils.     

Characterization of PM10 atmospheric aerosol at urban and urban background sites in Fuzhou city, China

Background

PM₁₀ aerosol samples were simultaneously collected at two urban and one urban background sites in Fuzhou city during two sampling campaigns in summer and winter. PM₁₀ mass concentrations and chemical compositions were determined.

Methods

Water-soluble inorganic ions (Cl^?, NO ₃ ^? , SO ₄ ^2? , NH ₄ ⁺ , K⁺, Na⁺, Ca²⁺, and Mg²⁺), carbonaceous species (elemental carbon and organic carbon), and elements (Al, Si, Mg, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, As, Se, Br, and Pb) were detected using ion chromatography, thermal/optical reflectance, and proton-induced X-ray emission methods, respectively.

Results

PM₁₀ mass concentrations, as well as most of the chemical components, were significantly increased from urban background to urban sites, which were due to enhanced anthropogenic activities in urban areas. Elements, carbonaceous species, and most of the ions were more uniformly distributed at different types of sites in winter, whereas secondary ion SO ₄ ^2? , NO ₃ ^? , and NH ₄ ⁺ showed more evident urban-background contrast in this season. The chemical mass closure indicated that mineral dust, organic matters, and sulfate were the most abundant components in PM₁₀. The sum of individually measured components accounted for 86.9?C97.7% of the total measured PM₁₀ concentration, and the discrepancy was larger in urban area than in urban background area.

Conclusion

According to the principal component analysis?Cmultivariate linear regression model, mineral dust, secondary inorganic ions, sea salt, and motor vehicle were mainly responsible for the PM₁₀ particles in Fuzhou atmosphere, and contributed 19.9%, 53.3%, 21.3%, and 5.5% of PM₁₀, respectively.     

Bioaccumulation, maternal transfer and elimination of polybrominated diphenyl ethers in wild frogs

To investigate bioaccumulation, maternal transfer and elimination of polybrominated diphenyl ethers (PBDEs) in amphibians, we collected adult frogs (Rana limnocharis) from a rice field in an e-waste recycling site in China. We found that ∑PBDEs in the whole frogs and various tissues (brain, liver, testis and egg) ranged from 17.10 to 141.11 ng g⁻¹ wet weight. Various tissues exhibited a similar PBDE congener profile, which was characterized by intermediate brominated congeners (BDE-99 and BDE-153) as the largest contributors, with less lower brominated congeners (BDE-28 and BDE-47) and higher brominated congeners (BDE-209). The maternal transfer capacity of PBDEs declined with the increase in bromine numbers of PBDE congeners. We suggest that the bromine atom number (the molecular size, to some degree) might be a determining factor for the maternal transport of a PBDE congener rather than K_ow (Octanol-Water partition coefficient), which expresses a compound’s lipophilicity. ∑PBDEs concentrations in frogs decreased over time during a depuration period of 54 days when these wild frogs were brought to the lab from the e-waste recycling site. The half-life of ∑PBDEs was 35 days, with about 14 days for BDE-47, and 36 and 81 days for BDE-99 and BDE-153, respectively. The data shows that the elimination of PBDEs has no essential difference from aquatic and terrestrial species.