全文获取类型
收费全文 | 1400篇 |
免费 | 63篇 |
国内免费 | 490篇 |
专业分类
安全科学 | 82篇 |
废物处理 | 87篇 |
环保管理 | 87篇 |
综合类 | 784篇 |
基础理论 | 235篇 |
污染及防治 | 502篇 |
评价与监测 | 64篇 |
社会与环境 | 54篇 |
灾害及防治 | 58篇 |
出版年
2024年 | 1篇 |
2023年 | 16篇 |
2022年 | 68篇 |
2021年 | 53篇 |
2020年 | 40篇 |
2019年 | 42篇 |
2018年 | 52篇 |
2017年 | 57篇 |
2016年 | 58篇 |
2015年 | 66篇 |
2014年 | 99篇 |
2013年 | 121篇 |
2012年 | 118篇 |
2011年 | 118篇 |
2010年 | 93篇 |
2009年 | 70篇 |
2008年 | 63篇 |
2007年 | 67篇 |
2006年 | 76篇 |
2005年 | 58篇 |
2004年 | 55篇 |
2003年 | 55篇 |
2002年 | 42篇 |
2001年 | 51篇 |
2000年 | 60篇 |
1999年 | 51篇 |
1998年 | 54篇 |
1997年 | 39篇 |
1996年 | 45篇 |
1995年 | 40篇 |
1994年 | 24篇 |
1993年 | 21篇 |
1992年 | 19篇 |
1991年 | 6篇 |
1990年 | 13篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 2篇 |
排序方式: 共有1953条查询结果,搜索用时 625 毫秒
471.
纳米Ag粒子原位杂化PVDF超滤膜的抗污染性能 总被引:2,自引:2,他引:0
以AgNO3为前驱体,聚偏氟乙烯(PVDF)为聚合物基体,聚乙烯吡咯烷酮(PVP)为分散剂和成孔剂,N,N-二甲基甲酰胺(DMF)为还原剂和溶剂,利用相转化法制备了纳米Ag粒子原位杂化PVDF超滤膜.采用扫描电镜、透射电镜、原子力显微镜及接触角测定仪对杂化膜的结构和性能进行了表征.结果表明:原位形成的纳米Ag粒子均匀地分散在聚合物基体中,纳米Ag粒子的添加改善了PVDF膜的亲水性能.以腐殖酸和牛血清蛋白作为污染物的代表,考察了Ag/PVDF膜的抗有机污染性能.以大肠杆菌、耐甲氧西林金黄色葡萄球菌及活性污泥作为微生物的代表,考察了杂化膜的抗生物污染性能.结果证实了与纯PVDF膜相比,Ag/PVDF膜通量衰减较慢,可有效抑制微生物的生长,表面受活性污泥污染程度小,具有显著的抗有机污染和抗生物污染性能. 相似文献
472.
Performance and microbial diversity of an expanded granular sludge bed reactor for high sulfate and nitrate waste brine treatment 总被引:1,自引:0,他引:1
Runhua Liao Yan Li Xuemin Yu Peng Shi Zhu Wang Ke Shen Qianqian Shi Yu Miao Wentao Li Aimin Li 《环境科学学报(英文版)》2014,26(4):717-725
The disposal of waste brines has become a major challenge that hinders the wide application of ion- exchange resins in the water industry in recent decades. In this study, high sulfate removal efficiency (80%-90%) was achieved at the influent sulfate concentration of 3600 mg/L and 3% NaC1 after 145 days in an expanded granular sludge bed (EGSB) reactor. Furthermore, the feasibility of treating synthetic waste brine containing high levels of sulfate and nitrate was investigated in a single EGSB reactor during an operation period of 261 days. The highest nitrate and sulfate loading rate reached 6.38 and 5.78 kg/(m3-day) at SO42--S/NO3-N mass ratio of 4/3, and the corresponding removal efficiency was 99.97% and 82.26% at 3% NaC1, respectively. Meanwhile, 454-pyrosequencing technology was used to analyze the bacterial diversity of the sludge on the 240th day for stable operation of phase X. Results showed that a total of 9194 sequences were obtained, which could be affiliated to 14 phyla, including Proteobacteria, Firmicutes, Chlorobi, Bacteroidetes, Synergistetes and so on. Proteobacteria (77.66%) was the dominant microbial population, followed by Firmicutes (12.23%) and Chlorobi (2.71%). 相似文献
473.
474.
膜生物反应器中膜过滤特征及膜污染机理的研究 总被引:27,自引:6,他引:21
以膜生物反应器处理市政污水,通过对活性污泥进行终端过滤来反映膜污染机理,实验表明,最初很短时间内膜污染受膜孔堵塞模型控制,之后受沉积层阻力模型控制,后一阶段是膜污染的主要控制阶段;膜的相对通量随过滤时间呈指数衰减趋势,压力越大,通量衰减越快;污泥沉积层存在压密过程,这一过程中的污泥比阻随压力增大而增大,并得到处理市政污水的污泥压密指数为0.807 8;阻力分布实验表明沉积层阻力占总阻力的90%以上,是膜过滤污染阻力的主要组成部分;活性污泥各组分对膜污染均有贡献,其中悬浮固体、胶体颗粒和溶质产生的阻力分别占87.98%、6.20%和5.82%;根据实验和计算结果,探讨了MBR处理市政污水过程中可能的膜污染机理. 相似文献
475.
The effect of transpiration (high and low) on Pb uptake by leaf lettuce and on water soluble low molecular weight organic acids (LMWOAs) in rhizosphere has been studied. After two weeks of growth the plants were cultured in greenhouse for more four weeks and two days. Pb(NO(3))(2) solutions of different concentrations (100, 200, and 300 mg l(-1) of Pb) were then added to the quartz sand pots of different plants and studies were initiated. Blank experiments (without treating the quartz sand pots with Pb(NO(3))(2) solutions) were also run in parallel. No significant differences in the growth of the plants with the concentrations of added Pb(NO(3))(2) solutions were observed by both low and high transpirations at the end of the 0, 3rd, and 10th days of studies. The total evaporation of the volatiles during 10 days did not depend on the concentration of Pb(2+) but with high transpiration the rate of evaporation was significantly higher than with low transpiration. Uptake of Pb by shoots and roots of the plants was found to be proportional to the concentration of various Pb(NO(3))(2) solutions added and more accumulation was observed in roots than in shoots at the end of 3rd and 10th days. High transpiration created more Pb uptake than low transpiration did. One volatile acid, propionic acid and nine non-volatile acids, lactic, glycolic, oxalic, succinic, fumaric, oxalacetic, D-tartaric, trans-aconitic, and citric acids in rhizosphere quartz sands were identified and quantified by gas chromatography (GC) analysis. D-Tartaric and citric acids were major among the non-volatile acids. The amount of LMWOAs in rhizosphere quartz sands increased with the higher amount of Pb uptake and also with the duration of studies. The total quantities of the LMWOAs in the rhizosphere quartz sands were significantly higher under high transpiration with 300 mg l(-1) Pb solution addition at the end of 10th day. The present study shows prominent correlation between transpiration and uptake of heavy metal and interesting correlation between Pb contaminated level and quantity of water soluble LMWOAs in rhizosphere quartz sands. The latter thus deserves of further studies. 相似文献
476.
Effects of metsulfuron-methyl on the microbial population and enzyme activities in wheat rhizosphere soil 总被引:1,自引:0,他引:1
He YH Shen DS Fang CR He R Zhu YM 《Journal of environmental science and health. Part. B》2006,41(3):269-284
The effects of metsulfuron-methyl, a sulfonylurea herbicide, on the wheat soil microorganisms were evaluated by the methods of microbial inoculation culture, and the activities of three enzymes were measured using the colorimetric method. The tolerant microorganisms that can resist 500 microg x g(-1) metsulfuron-methyl in the counting culture medium were studied specially. Metsulfuron-methyl distinctly inhibited the common aerobic heterotriphic bacteria, but the effects on common fungi and common actinomycete were not evident. In the meantime, the number of tolerant fungi increased greatly in the rhizosphere after the application of metsulfuron-methyl in contrast to the significant decrease of the amount of tolerant actinomycete. It indicates that fungi might turn into the dominant microbial type and actinomycete is the sensitive factor in the soil polluted by sulfonylurea residues. The population of aromatic compounds-decomposing bacteria, aerobic azotobacter, and nitrite bacteria all increased in the earlier period, but the aerobic azotobacter decreased rapidly in number 30 days later, and the amount of nitrite bacteria also showed a temporary decrease with time 15 days later. However, the denitrifying bacteria just began to increase significantly after the crops had grown for 50 days. The amount of sulfur-oxidizing bacteria gradually decreased with the growth of crops, and so were the sulfate-reducing bacteria after metsulfuron-methyl application. To all types of microorganisms, there were more microbes in rhizosphere samples than those in nonrhizosphere except aerobic azotobacter. It means the growth of wheat root system can stimulate the growth of most microorganisms. The activities of hydrogen peroxidase and polyphenol oxidase in soil samples after metsulfuron-methyl application were notably lower than those in the control, and the difference of the activities between the samples of rhizosphere and nonrhizosphere was evident. On the contrary, the activity of dehydrogenase was not inhibited by the application of metsulfuron-methyl, and the rhizosphere effect was not obvious either. 相似文献
477.
Teng-Chien Chen Yun-Hwei Shen Wen-Jhy Lee Chih-Chung Lin Meng-Wei Wan 《Journal of Cleaner Production》2010,18(18):1850-1858
In recent years, the increasing world population and rapid industrial development has increased the consumption of fossil fuel-derived oils. In response to the resulting exhaustion of fossil fuel energy, many countries around the world are investigating methods of waste energy recovery and reuse, including oil recovery from the pyrolysis process of waste tires. This study investigates the efficiency of an ultrasound-assisted oxidative desulfurization (UAOD) process in sulfur reduction from diesel oil and the pyrolysis oil from waste tires treatment. The results indicate that the oxidation efficiency increases as the doses of transition metal catalyst are increased. Longer sonication time also enhances the oxidation process, apparently through the biphasic transfer of oxidants, which results in a high yield of organic sulfur oxidation products. The best desulfurization efficiency was 99.7% (2.67 ppm sulfur remaining) and 89% (800 ppm sulfur remaining) for diesel and pyrolysis oils, respectively, via a process executed by two UAOD units connected in series and combined with solid adsorption using 30 g of Al2O3 in 6 cm columns. These batch experiment results demonstrate clean waste energy recovery and utilization, while fulfilling the requirements of Taiwan EPA environmental regulations (sulfur concentrations less than 5000 ppm). 相似文献
478.
日地环境对人类自发攻击性事件的影响 总被引:1,自引:0,他引:1
考察了日地空间物理环境扰动与人类自发攻击性群体性事件发生率之间相关性。统计分析发现,两者之间的相关程度很高,历元叠加后相关系数可达0.84和0.79、这表明日地空间物理环境对人类攻击性本能和情绪具有显著的调节作用,导致全球自发攻击性群体事件年发生率具有11a准周期波动特征。其作用机制可能是地磁场活动和大气温度的影响。 相似文献
479.
石油野外作业工人体力劳动强度分级调查 总被引:1,自引:0,他引:1
据GB3869—83标准对江汉油田测量、地震、钻井、井下四类野外作业34名工人、24个工种进行了体力劳动强度分级调查,其结果:测量作业为Ⅰ~Ⅱ级;钻井作业Ⅱ级占5/8,Ⅲ级占1/4;井下作业Ⅲ级占2/3;地震作业Ⅲ、Ⅳ级各占4/9、2/9。说明前两类基本属中等强度劳动,后两类大部分属重强度劳动。 相似文献
480.