Development of a waterjet system for direct delivery of granular iron and activated carbon to remediate contaminated aqueous sediments

While the techniques and technologies associated with contaminated sediment remediation are relatively mature, there are several issues associated with these practices that make them unattractive. The inability of currently used mechanical mixing implements to place amendments in aqueous environments and their intrusive behavior toward benthic communities are just two examples of a necessity for an improved delivery method. Waterjets may be a viable option for placement of particulate remediation amendments, such as activated carbon and granular iron, at depth. A custom waterjet nozzle and injection system has been fabricated by the authors to examine this delivery concept. The developed injection system's performance was tested by characterizing the waterjet‐delivered amendment (activated carbon and granular iron) distributions in a surrogate sediment. The delivered amendment distributions followed similar patterns for a range of injection times and a variety of amendments. The injection depths, however, were dependent upon the type of amendment being injected. These findings have led to a better understanding of what occurs during an amendment injection, which can be used for a more controlled placement of remediation amendments using this technique in the future. The laboratory results indicate that the subject waterjet system may have the potential for field‐scale applications, especially for granular iron delivery, as the authors were able to place between 60 and 70 wt percent into a surrogate sediment bed along the path of injection. © 2011 Wiley Periodicals, Inc.     

Simulating PM concentration during a winter episode in a subtropical valley: Sensitivity simulations and evaluation methods

We investigated a two-week episode with high PM concentrations in California Central Valley during the Christmas–New Year of 2000–2001 using a modeling system that consists of a computationally efficient, 3-D photochemical–microphysical transport model, a mesoscale meteorological model, emission models, and an evaluation package. One hundred simulations were conducted with fine resolutions and observational constraints, to reproduce spatial and temporal features of observed PM concentrations and to understand the formation mechanism of the episode. Simulated PM concentrations consist of secondary inorganic components, mainly ammonium nitrate, and total carbon in areas with elevated concentrations in the accumulation mode, and consist of mainly dust and sea salt in the coarse mode. Simulated oxidants and nitrate were significantly elevated over the valley, and the latter showed much less amplitude than the former. Simulated PM concentrations were evaluated with observations systematically with spatially and temporally paired method, a more restrictive multivariate method (NMFROC), and a more flexible “gradient evaluation” method. The paired evaluation shows that high correlation coefficient (R = ～0.8) and low fractional error (FE = ～0.1) could be achieved at stations with elevated 24-h concentration of PM in the accumulation mode in some simulations. The NMFROC method was used to extract useful information from seemingly failed simulations. A “gradient evaluation” method is introduced here to extract additional information from simulations. We found that emission reductions of NO_x and AVOC showed similar effects on percentage basis in different areas, and both are more effective than reducing NH₃ for abating elevated concentrations of accumulation mode PM in California Central Valley during the winter episode.     

Massive and distinctive effects of meadow voles on grassland vegetation

We ask whether vole herbivory in experimental grassland plots is sufficient to create an unpalatable community. In a six-year experiment, meadow voles (Microtus pennsylvanicus) reduced plant standing crop between 30% and 72%, well within the range of ungulate effects. Moreover, meadow voles reduced their available forage species by changing the plant community composition: four grass species and a legume upon which they foraged declined sharply in cover and/or number of individuals, five forbs avoided by voles increased, and two forbs neither declined nor increased with either measure. Reductions of diversity occurred when voles first defoliated the plots in 2000 but disappeared as plant species avoided by voles replaced vulnerable plants. Within six years, meadow voles created plant communities dominated by species that they did not eat.     

Evaluating inter-continental transport of fine aerosols: (1) Methodology,global aerosol distribution and optical depth

Our objectives are to evaluate inter-continental source-receptor relationships for fine aerosols and to identify the regions whose emissions have dominant influence on receptor continents. We simulate sulfate, black carbon (BC), organic carbon (OC), and mineral dust aerosols using a global coupled chemistry-aerosol model (MOZART-2) driven with NCEP/NCAR reanalysis meteorology for 1997–2003 and emissions approximately representing year 2000. The concentrations of simulated aerosol species in general agree within a factor of 2 with observations, except that the model tends to overestimate sulfate over Europe in summer, underestimate BC and OC over the western and southeastern (SE) U.S. and Europe, and underestimate dust over the SE U.S. By tagging emissions from ten continental regions, we quantify the contribution of each region's emissions on surface aerosol concentrations (relevant for air quality) and aerosol optical depth (AOD, relevant for visibility and climate) globally. We find that domestic emissions contribute substantially to surface aerosol concentrations (57–95%) over all regions, but are responsible for a smaller fraction of AOD (26–76%). We define “background” aerosols as those aerosols over a region that result from inter-continental transport, DMS oxidation, and emissions from ships or volcanoes. Transport from other continental source regions accounts for a substantial portion of background aerosol concentrations: 36–97% for surface concentrations and 38–89% for AOD. We identify the Region of Primary Influence (RPI) as the source region with the largest contribution to the receptor's background aerosol concentrations (or AOD). We find that for dust Africa is the RPI for both aerosol concentrations and AOD over all other receptor regions. For non-dust aerosols (particularly for sulfate and BC), the RPIs for aerosol concentrations and AOD are identical for most receptor regions. These findings indicate that the reduction of the emission of non-dust aerosols and their precursors from an RPI will simultaneously improve both air quality and visibility over a receptor region.     

Microtox assay to determine the toxicity of degradation products from degradable plastics

Six types of starch-polyethylene degradable plastics were evaluated for the release of water-soluble toxic compounds under accelerated degradation conditions. A plastic strip (2.5×15.2 cm) was placed in a 250-ml Erlenmeyer flask with 100 ml of ASTM type I water with or without trace element solutions and shaken at 65°C and 110 rpm for 20 weeks in replicates of two. High temperature was used to accelerate the oxidative degradation of polyethylene. Plastic degradation was measured by loss of tensile strength, percentage elongation, strain energy, and weight-average molecular weight. The most rapid period of polyethylene thermal degradation was complete for most materials by day 28. Ten-milliliter aqueous samples were removed from each flask at days 1, 7, 28, 56, 84, and 140 (water volumes were maintained at 100 ml with fresh type I water), filtered through glass filters, then evaluated by using the Microtox Toxicity Analyzer (Microbics Corporation, Carlsbad, CA). No water-soluble toxic compounds were detected during the period of rapid film degradation. Toxicity was observed at day 28 for one film and at day 84 for all films, which could possibly correlate with the release of small oxidative compounds such as formaldehyde and acetaldehyde. Because of the sensitivity of this assay, positive results must be confirmed by otherin vitro studies.Journal Paper No. J-14851 of the Iowa Agriculture and Home Economics Experiment Station, Ames, Iowa. Projects No. 2889 and 0178.     

WATER FOR ENERGY: AN APPROACH TO COMPREHENSIVE IMPACT ASSESSMENT1

ABSTRACT: The effects of energy development on the water resources of the Colorado River and Great Basin regions is expected to be substantial. Complex physical, economic and institutional interactions may be expected. Most research on these impacts appears single purpose, fragmented, uncoordinated, and often inaccessible to potential users - particularly those with responsibility for energy/water policy and program decisions. A comprehensive, integrative framework for assessing alternative water allocation decisions is outlined, taking a heuristic decision making model for evaluating impacts on maximization of gross (or net) regional product, and regional social welfare, and for assessing the region's contribution to national objectives. The suggested model provides a structure for application and integration of data of various kinds to a range of situations arising from possible impacts from energy proposals. The focus is on water and energy relationships but the model may provide a framework for comprehensive analysis of a variety of environmental actions and resulting system perturbations and effects.