Ethylenediamine-modified activated carbon for aqueous lead adsorption

This study is to develop a carbon-based adsorbent containing multiple functional ligands for effective removal of lead ions from aqueous media. Activated carbon was oxidized by nitric acid, followed by chlorination with thionyl chloride and reaction with ethylenediamine. Modified activated carbon (MAC) was characterized using scanning electron microscopy in conjunction of energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FT-IR), and potentiometric titration. Surface characterizations confirmed that carboxyl, amine, and chlorine functional groups were effectively introduced onto the carbon surface by the treatments. The modifications lowered the pH at the point of zero charge (pH_pzc) from 9.6 to 2.55 and resulted in more negatively charged surfaces. Adsorptive experiments showed that aqueous Pb removal by MAC was faster, with a 62% higher capacity than the original activated carbon (60.2 vs. 37.2 mg g⁻¹).     

Media surface properties and the development of nitrifying biofilms in mixed cultures for wastewater treatment

Plastic was tested to select biofilm support media that would enhance nitrification in the presence of heterotrophs. Eight different types (acrylonitrile butadiene styrene, nylon, polycarbonate, polyethylene, polypropylene, polytetrafluoroethylene (PTFE), polyvinyl chloride and tufnol) were immersed in an aerobic fed-batch reactor receiving domestic settled wastewater. Nitrification rates did not correlate with biomass concentrations, nor surface roughness of the plastics as measured by atomic force microscopy (AFM). The maximum nitrification rate of 1.5 g/m² d^?1 was obtained from biofilms growing on PTFE which had the lowest surface adhesion force (8 nN). Nitrification rates for the biofilms were inversely correlated with the attraction forces as measured by AFM.     

Urban Revitalisation Partnerships: Perceptions of the university's role in Louisville,Kentucky

The university has a role to play in helping revitalise US cities. University participation contributes to all three aspects of life on campus: teaching, research and service. This evaluation uses a case study qualitative approach in order to assess a $2 million university-community partnership programme in Louisville, Kentucky. A selective sample of business, community, university and government leaders was interviewed to evaluate the impact of the University of Louisville Housing and Neighborhood Development Strategies programme. The programme consisted of special classroom and related projects devoted to applied research by faculty and students including, but not limited to, housing development and the recycling of environmental infrastructure (i.e. housing lots, storm and sanitary sewers and water pipes, etc.). The partnership has won environmental awards from the Sierra Club and the US Environmental Protection Agency, and was a semi-finalist in the Innovations in American Government Awards from Harvard University. It also included use of professional staff to deliver a broad spectrum of human resource services to the community with a feedback loop to research themes. There are positive and negative aspects to these partnerships. On balance, both town and gown have the potential to gain immeasurably from the collaborative efforts of university- community partnerships.     

Learning sustainable water practices through participatory irrigation management in Thailand

Participatory irrigation management (PIM) was adopted in Thailand in 2004 to encourage the sustainable use of water in the agricultural sector. The research presented in this paper sought to understand the relationships between public participation, learning, and the implementation of more sustainable water practices through PIM in Thailand. Data was collected through document reviews, observation, informal meetings, and a total of 55 semi‐structured face‐to‐face interviews of local irrigators from two case study regions around the Krasiew Reservoir. Results showed that participating in PIM activities facilitated both instrumental (e.g., water supply and demand data, benefits of on‐time water delivery) and communicative (e.g., reasons for past PIM failure, expectations of fellow farmers) learning among PIM participants. Findings also revealed that social action is fostered through the recognition of human dignity and compassionate communication that instils a sense of ownership and solidarity among irrigators. Sustainable water practices among local farmers were spurred further through learning that the reservoir is a finite water source.     

Field-Level Financial Assessment of Contour Prairie Strips for Enhancement of Environmental Quality

The impacts of strategically located contour prairie strips on sediment and nutrient runoff export from watersheds maintained under an annual row crop production system have been studied at a long-term research site in central Iowa. Data from 2007 to 2011 indicate that the contour prairie strips utilized within row crop-dominated landscapes have greater than proportionate and positive effects on the functioning of biophysical systems. Crop producers and land management agencies require comprehensive information about the Best Management Practices with regard to performance efficacy, operational/management parameters, and the full range of financial parameters. Here, a farm-level financial model assesses the establishment, management, and opportunity costs of contour prairie strips within cropped fields. Annualized, depending on variable opportunity costs the 15-year present value cost of utilizing contour prairie strips ranges from $590 to $865 ha^?1 year^?1 ($240–$350 ac^?1 year^?1). Expressed in the context of “treatment area” (e.g., in this study 1 ha of prairie treats 10 ha of crops), the costs of contour prairie strips can also be viewed as $59 to about $87 per treated hectare ($24–$35 ac^?1). If prairie strips were under a 15-year CRP contract, total per acre cost to farmers would be reduced by over 85 %. Based on sediment, phosphorus, and nitrogen export data from the related field studies and across low, medium, and high land rent scenarios, a megagram (Mg) of soil retained within the watershed costs between $7.79 and $11.46 mg^?1, phosphorus retained costs between $6.97 and $10.25 kg^?1, and nitrogen retained costs between $1.59 and $2.34 kg^?1. Based on overall project results, contour prairie strips may well become one of the key conservation practices used to sustain US Corn Belt agriculture in the decades to come.     

Relationship Between Woody Plant Colonization and Typha L. Encroachment in Stormwater Detention Basins

We studied stormwater detention basins where woody vegetation removal was suspended for 2 years in Virginia, USA to determine if woody vegetation can control Typha populations and how early woody plant succession interacts with Typha, other herbaceous vegetation, and site factors. Distribution and composition of woody vegetation, Typha and non-Typha herbaceous vegetation biomass, and site factors were assessed at 100 plots in four basins ranging in age from 7 to 17 years. A greenhouse study examined the interaction of shade and soil moisture on Typha biomass and persistence. Principal component analysis identified an environmental gradient associated with greater water table depths and decreased elevation that favored Typha but negatively influenced woody vegetation. Elevation was correlated with litter layer distribution, suggesting that initial topography influences subsequent environmental characteristics and thus plant communities. Soil organic matter at 0–10 cm ranged from 5.4 to 12.7 %. Woody plants present were native species with the exception of Ailanthus altissima and Pyrus calleryana. In the greenhouse, shade and reduced soil moisture decreased Typha biomass and rhizome length. The shade effect was strongest in flooded plants and the soil moisture effect was strongest for plants in full sun. Typha in dry soil and heavy shade had 95 % less total biomass and 83 % smaller rhizomes than Typha in flooded soil and full sun, but even moderate soil moisture reductions decreased above- and below-ground biomass by 63 and 56 %, respectively. Suspending maintenance allows restoration of woody vegetation dominated by native species and may suppress Typha invasion.     

Toward Consensus-Based Actions that Balance Invasive Plant Management and Conservation of At-Risk Fauna

Limiting the spread of invasive plants has become a high priority among natural resource managers. Yet in some regions, invasive plants are providing important habitat components to native animals that are at risk of local or regional extirpation. In these situations, removing invasive plants may decrease short-term survival of the at-risk taxa. At the same time, there may be a reluctance to expand invaded habitats to benefit at-risk species because such actions may increase the distribution of invasive plants. Such a dilemma can result in “management paralysis,” where no action is taken either to reduce invasive plants or to expand habitats for at-risk species. A pragmatic solution to this dilemma may be to develop an approach that considers site-specific circumstances. We constructed a “discussion tree” as a means of initiating conversations among various stakeholders involved with managing habitats in the northeastern USA to benefit several at-risk taxa, including New England cottontails (Sylvilagus transitionalis). Major components of this approach include recognition that expanding some invaded habitats may be essential to prevent extirpation of at-risk species, and the effective control of invasive plants is dependent on knowledge of the status of invasives on managed lands and within the surrounding landscape. By acknowledging that management of invasive plants is a complex issue without a single solution, we may be successful in limiting their spread while still addressing critical habitat needs.     

Ignoring the irrelevant: auditory tolerance of audible but innocuous sounds in the bat-detecting ears of moths

Noctuid moths listen for the echolocation calls of hunting bats and respond to these predator cues with evasive flight. The African bollworm moth, Helicoverpa armigera, feeds at flowers near intensely singing cicadas, Platypleura capensis, yet does not avoid them. We determined that the moth can hear the cicada by observing that both of its auditory receptors (A1 and A2 cells) respond to the cicada's song. The firing response of the A1 cell rapidly adapts to the song and develops spike periods in less than a second that are in excess of those reported to elicit avoidance flight to bats in earlier studies. The possibility also exists that for at least part of the day, sensory input in the form of olfaction or vision overrides the moth's auditory responses. While auditory tolerance appears to allow H. armigera to exploit a food resource in close proximity to acoustic interference, it may render their hearing defence ineffective and make them vulnerable to predation by bats during the evening when cicadas continue to sing. Our study describes the first field observation of an eared insect ignoring audible but innocuous sounds.     

Role of winter temperature and climate change on the survival and future range expansion of the hemlock woolly adelgid (Adelges tsugae) in eastern North America

Global climate change has already affected the abundances, range limits, and interactions of many species. The hemlock woolly adelgid (Adelges tsugae), an invasive insect introduced to eastern North America from Japan, has decimated stands of eastern hemlock (Tsuga canadensis) and Carolina hemlock (T. caroliniana) from Georgia to Connecticut. However, its spread across central and northern New England has been slowed substantially by its inability to tolerate cold winter temperatures. Using data from previous lab and field studies collected over the past 17 years, including adelgid spread and overwintering mortality, we first characterize the temperature conditions that may limit adelgid spread. We then show how, in the future, rising winter temperatures due to climate change are likely to remove the conditions currently limiting adelgid spread, and facilitate the northward expansion as more suitable habitat becomes available.     

Nonylphenol in the environment: a critical review on occurrence, fate, toxicity and treatment in wastewaters

Nonylphenol is a toxic xenobiotic compound classified as an endocrine disrupter capable of interfering with the hormonal system of numerous organisms. It originates principally from the degradation of nonylphenol ethoxylates which are widely used as industrial surfactants. Nonylphenol ethoxylates reach sewage treatment works in substantial quantities where they biodegrade into several by-products including nonylphenol. Due to its physical-chemical characteristics, such as low solubility and high hydrophobicity, nonylphenol accumulates in environmental compartments that are characterised by high organic content, typically sewage sludge and river sediments, where it persists. The occurrence of nonylphenol in the environment is clearly correlated with anthropogenic activities such as wastewater treatment, landfilling and sewage sludge recycling. Nonylphenol is found often in matrices such as sewage sludge, effluents from sewage treatment works, river water and sediments, soil and groundwater. The impacts of nonylphenol in the environment include feminization of aquatic organisms, decrease in male fertility and the survival of juveniles at concentrations as low as 8.2 mug/l. Due to the harmful effects of the degradation products of nonylphenol ethoxylates in the environment, the use and production of such compounds have been banned in EU countries and strictly monitored in many other countries such as Canada and Japan. Although it has been shown that the concentration of nonylphenol in the environment is decreasing, it is still found at concentrations of 4.1 mug/l in river waters and 1 mg/kg in sediments. Nonylphenol has been referred to in the list of priority substances in the Water Frame Directive and in the 3rd draft Working Document on Sludge of the EU. Consequently there is currently a concern within some industries about the possibility of future regulations that may impose the removal of trace contaminants from contaminated effluents. The significance of upgrading sewage treatment works with advanced treatment technologies for removal of trace contaminants is discussed.