Photosynthesis and respiration of exposed salt-marsh fucoids

Photosynthesis and respiration of the salt-marsh fucoids Ascophyllum nodosum ecad scorpioides and Fucus vesiculosus were investigated using an infrared CO₂ gas analyzer under a variety of light intensities, temperatures, and levels of desiccation while the algae were exposed to the atmosphere. Results indicated that net photosynthesis (0.5 to 2.0 mg C/g dry weight/h) saturated rapidly at light intensities (0.1 to 0.2 g cal/cm²/min) which were approximately 10 to 50% of the daily summer maximum intensities for algae found under phanerogam (Spartina alterniflora) canopies. Desiccation exhibited the most pronounced effect on photosynthesis, which increases slightly between 0 and 25% water loss, levels off, and decreases sharply at water losses greater than 50%. Dark respiration (0.1 to 0.3 mg C/g dry weight/h) is also inhibited by desiccation. Both species of algae appear to be broadly adapted to all three parameters investigated.This research was supported by research grants AG-375 and BO 38018 from the National Science Foundation and, in part, by the State University of New York Research Foundation and the Energy Research and Development Administration (ERDA).Communicated by M.R. Tripp, Newark     

X-ray absorption spectroscopy studies of reactions of technetium, uranium and neptunium with mackinawite

Technetium, uranium and neptunium may all occur in the environment in more than one oxidation state (IV or VII, IV or VI and IV or V respectively). The surface of mackinawite, the first-formed iron sulfide phase in anoxic conditions, can promote redox changes so a series of laboratory experiments were carried out to explore the interactions of Tc, U and Np with this mineral. The products of reaction were characterised using X-ray absorption spectroscopy. Technetium, added as TcO4(-), is reduced to oxidation state IV and forms a TcS(2)-like species. On oxidation of the mackinawite in air to form goethite, Tc remains in oxidation state IV but in an oxide, rather than a sulfide environment. At low concentrations, uranium forms uranyl surface complexes on oxidised regions of the mackinawite surface but at higher concentrations, the uranium promotes surface oxidation and forms a mixed oxidation state oxide phase. Neptunium is reduced to oxidation IV and forms a surface complex with surface sulfide ions. The remainder of the Np coordination sphere is filled with water molecules or hydroxide ions.     

Environmental Accountability: Who's Kidding Whom?

International declarations and charters have been produced to encourage and support higher education institutions (HEIs) to address their environmental responsibilities. This paper discusses the results of a critical examination of a range of international HEIs that have signed the global environmental Talloires Declaration. It also assesses the Talloires Secretariat (University Leaders for a Sustainable Future, ULSF) and the extent to which this has been a primary stimulus. An international survey was undertaken and the results presented in a discursive format in order to highlight key driving forces, barriers, and opportunities for environmental responsibility in HEIs. Analysis reveals that they occur on two distinct and evolving levels: the macro national framework level and the micro institutional framework level. Survey responses revealed that none of the HEIs have an embedded institutional environmental culture and most did not have all the micro institutional mechanisms in place for an integrated university-wide environmental response. Many of the institutional barriers to environmental responsibility occurred as a result of this lack of strategy. The most significant institutional opportunity cited was enthusiastic individuals, particularly those at senior management or directorate level, and these individuals were found to be a key driving force. Results also showed that environmental reporting along the lines developed by the private sector is a flexible mechanism that can stimulate progress internally and externally and can be cost effectively disseminated via the World Wide Web. Moreover the survey results indicate that ULSF is not currently a primary stimulus for institution wide action.     

Common criteria for the redefinition of Intermediate Less Favoured Areas in the European Union

This article defines eight key climate, soil and terrain criteria that have been developed for the future delimitation of the Intermediate Less Favoured Areas (LFAs) support, a measure of the Common Agricultural Policy. The LFA scheme has existed since 1975 and is a broad mechanism for improving the viability of agriculture in areas with natural handicaps. The common criteria have been developed for the European Commission's Directorate-General for Agriculture and Rural Development to satisfy the objectives in the Rural Development Policy 2007–2013 (Axis II), which aim to improve the environment and the countryside by more sustainable land management. The criteria were developed by experts, coordinated by the European Commissions Joint Research Centre, to meet the requirement for a robust and harmonised approach of identifying areas that experience natural constraints to agriculture throughout the EU 27 Member States. The criteria proposed are: temperature, heat stress, drainage, soil texture and stoniness, soil rooting depth, soil chemical properties, soil moisture balance and slope. Each criterion is described and an indicative threshold for assessment of its impact on agriculture is provided. The criteria are currently being tested by the EU Member States for a future possible legislation.     

The limits to risk aversion: Part 1. The point of indiscriminate decision

The paper uses utility theory to investigate how much should be spent to avert all costs from an industrial accident apart from direct human harm. These “environmental costs” will include those of evacuation, clean-up and business disruption. Assuming the organisation responsible will need to pay such costs, the difference between its expected utility with and without an environmental protection system constitutes a rational decision variable for whether or not the scheme should be installed. The value of utility is dependent on the coefficient of relative risk aversion, “risk-aversion” for short. A model of an organisation's decision-making process has been developed using the ABCD model, linking the organisation's assets, A, the cost of the protection scheme, B, the cost of consequences, C, and the expected utility difference with and without the scheme, D. Increasing the organisation's risk-aversion parameter will tend to make it less reluctant to invest in a protection system, but can bring about such investment only when the scheme is relatively close to financial break-even. For such borderline schemes, the amount the organisation is prepared to spend on the protection system will rise as the risk-aversion increases. The ratio of this sum to the break-even cost is named the “Limiting Risk Multiplier”, the maximum value of which is governed by the maximum feasible value of risk-aversion. However, the mathematical model shows that increasing the risk-aversion will reduce the clarity of decision making generally. Although the reluctance to invest in a protection scheme may change sign and turn into a positive desire to invest as the risk-aversion increases, the absolute value of this parameter is a continuously decreasing function of risk-aversion, tending asymptotically to zero. As a result, discrimination will gradually diminish, being lost altogether at the “point of indiscriminate decision”. Here the decision maker will be able to distinguish neither advantage in installing the scheme nor disadvantage in installing its inverse. There is a close correspondence between this mathematically predicted state and that of panic, where an individual has become so fearful that his actions become random. The point of indiscriminate decision provides a natural upper bound for the value of risk-aversion. This bounds the Limiting Risk Multiplier in turn, and so sets an objective upper limit on the amount that it is rational to spend on an environmental protection system.     

Towards an alternative criterion for the shipping safety of activated carbons: Part 4. The role of times to ignition

To the previously developed and implemented new criterion for the shipping safety of activated carbons is added a consideration of ignition times. It is shown that there is considerable support for the view that in the past shipments of such materials deemed on the basis of the IMCO/ISO test procedures to be subcritical have actually been supercritical, but that the long ignition times, exceeding voyage times, have prevented fire from developing.     

LAND COVER AS A FRAMEWORK FOR ASSESSING RISK OF WATER POLLUTION1

ABSTRACT: A survey of numerous field studies shows that nitrogen and phosphorous export coefficients are significantly different across forest, agriculture, and urban land‐cover types. We used simulations to estimate the land‐cover composition at which there was a significant risk of nutrient loads representative of watersheds without forest cover. The results suggest that at between 20 percent and 30 percent nonforest cover, there is a 10 percent or greater chance of N or P nutrient loads being equivalent to the median values of predominantly agricultural or urban watersheds. The methods apply to environmental management for assessing the risk to increased nonpoint nutrient pollution. Interpretation of the risk measures are discussed relative to their application for a single watershed and across a region comprised of several watersheds.     

A simple soil organic-matter model for biomass data assimilation in community-level carbon contracts.

Soil carbon (C) sequestration has been proposed as a transitional win-win strategy to help replenish organic-matter content in depleted agricultural soils and counter increases in atmospheric greenhouse gases. Data assimilation and remote sensing can reduce uncertainty in sequestered C mass estimates, but simple soil organic carbon (SOC) models are required to make operational predictions of tradeable amounts over large, heterogenous areas. Our study compared the performance of RothC26.3 and a reduced compartmental model on an 11-year fertilizer trial in subhumid West Africa. Root mean square error (RMSE) differences of 0.05 Mg C/ha between models on total SOC predictions suggest that for contractual purposes, SOC dynamics can be simulated by a two-pool structure with labile and stable components. Faster (seasonal) and slower (semicentennial and beyond) rates can be approximated by constants as instantaneous and infinite decay. In these systems, simulations indicate that cereal residue incorporation holds most potential for mitigation of transient C loss associated with recent land conversion to agriculture.