The effect of acidification on abiotic interactions of dissolved humic substances, iron and phosphate in epilimnetic water from the humex Lake Skjervatjern

The responses to pH of abiotic interactions between dissolved humic substances, iron and phosphate were investigated by examining redistributions of ⁵⁵FeCl₃ and ³²PO₄³⁻ added to epilimnetic lakewater from Lake Skjervatjern. The simultaneous movement of ⁵⁵Fe and ³²P to fractions of 10 000–20 000 and > 100 000 Daltons nominal molecular weight, as indicated by Sephadex gel filtration, diminished in response to decreasing pH. Variations in transformations to larger molecular size fractions with incubation time revealed by gel filtration were erratic, but indicated that transformations of added ⁵⁵Fe and ³²P are complete after circa 24 h. Movement of ³²P to particle size fractions (>0.2 μm) was not dependent on pH, whilst transformations of ⁵⁵Fe to material of particle size increased as pH was lowered. Precipitation of added ⁵⁵Fe and ³²P was minimal at all pH values tested. Responses of precipitation losses to pH were not coincident for both radionuclides.     

An environmental assessment of food supply chains: a case study on dessert apples

The contemporary food system provides consumers with convenience, extensive choice, and the year-round availability of fresh produce. In this paper these achievements are recognized within the context of the associated environmental impacts. While many analyses have considered the energy and material efficiency of various options for food production and packaging, very few studies have investigated the environmental impacts of the transport components of food supply chains. This is surprising, given that the global sourcing of food produce, centralized distribution systems, and shopping by car have become prevalent in recent decades and have contributed to an increase in the distance between producer and consumer or “food miles.” In a case study the transport energy consumption is calculated for all possible ways in which dessert apples can be supplied to the UK consumer. The aim is to assess the environmental performance of the predominant fresh produce supply chains and to investigate claims that localized systems are more environmentally efficient. The main criteria used to compare the environmental efficiency in alternative food supply chains are the transport-related fossil-fuel energy consumption and associated carbon dioxide emissions. Analysis of the empirical data shows that transportation is now responsible for a considerable fraction of the total energy consumption in the life cycle of fresh apples, and in most cases exceeds the energy consumed in commercial apple cultivation. By developing local production and marketing systems for fresh products, transport demand can be reduced and many of the environmental impacts associated with existing supply chains can be avoided. The results of the study are then discussed in relation to the wider issues of transport policy, international trade, food security, and product-related environmental information for consumers.     

Characterisation of airborne particles collected within and proximal to an opencast coalmine: South Wales,U.K

Airborne particulate matter has been collected from within,and proximal to, an opencast coal mine in south Wales. Thiswork forms the first part of a three year project to collectand characterise, then determine the possible toxicology ofairborne particles in the south Wales region. High-resolutionField Emission SEM has shown that the coal mine dusts consistlargely of an assemblage of mineral grains and vehicle exhaustparticles. SEM-EDX has shown that the mineralogical make-up ofthe PM10 is complex, heterogeneous, and constantly changing.These findings are supported by analytical TEM-EPXMA.However, patterns can be determined relating the mineralogicalcomposition of the airborne particles to collection locationsand mining activities within the opencast. At our studyopencast, Park Slip West, quartz, which has known healtheffects, never exceeded 30% of the total collection mass, andaverage levels were much less. Vehicle exhaust emissions wasthe largest source in terms of particle numbers. The mass ofairborne particulate matter within the pit averagedapproximately twice that of outside the pit: importantlyhowever, this higher mass was due to relatively large, andnon-respirable, mineral grains. This study demonstrates that the physicochemical andmineralogical characterisation of airborne particles frommining and quarrying is essential to quantify the respirablefraction, and to identify potentially hazardous componentswithin the PM10.     

减少全球NOx排放:开发先进的能量和运输技术

从全球范围来讲,未来能量需求将会持续增长.由于发展中国家要提高其生活水平,因此,在可预见的将来,全球NOx排放会呈现出不断增加的趋势.美国采取了一些改善措施来减少固定和流动污染源的NOx排放,以减少对臭氧层的损坏.同时需要采取进一步的改进措施以降低与NOx排放有关的对身体健康和生态系统的影响.由于对电力和运输需求的增长,在世界上其他地区(尤其是发展中国家)NOx排放一直在稳定增长.如果实施适当的政策措施,能源和运输技术的改善会有助于减少NOx排放.这篇论文评价了商用电力生产和运输技术,相对于传统技术而言,它们排放较少的NOx,同时还评价了近10年内商用方面的先进技术.文章还评估了可以在地区、国家和全球水平上实施的不同政策措施,以此来促进这些先进技术的开发并最终减少NOx排放.论文提出了技术飞跃的概念,很可能有助于发展中国家缩减那些导致NOx排放增大的项目.     

Soil uranium,basement radon and lung cancer in Illinois,USA

Using counties as the sampling unit, a significant association between the chemical form of uranium occurring in soils with basement radon levels was found (Spearman r, 0.266; p > |r|, 0.007). Uranium atoms dispersed throughout the soil matrix are efficient emanators of Rn to soil gas, whereas Rn that is trapped diffuses very slowly from the several U-bearing minerals in Illinois soils and does not contribute significantly to explaining basement Rn. Basement Rn level is correlated with annual incidence of male and female lung cancers. Dispersed U is correlated with annual incidence of lung cancer in females with a Spearman correlation coefficient of 0.162 (p > |r|, 0.104) and males of 0.177 (p > |r|, 0.075).     

Accumulation of perchlorate in aquatic and terrestrial plants at a field scale

Previous laboratory-scale studies have documented perchlorate ClO(-)(4) uptake by different plant species, but less information is available at field scale, where ClO(-)(4) uptake may be affected by environmental conditions, such as distance to streams or shallow water tables, exposure duration, and species. This study examined uptake of ClO(-)(4) in smartweed (Polygonum spp.) and watercress (Nasturtium spp.) as well as more than forty trees, including ash (Fraxinus greggii A. Gray), chinaberry (Melia azedarach L.), elm (Ulmus parvifolia Jacq.), willow (Salix nigra Marshall), mulberry [Broussonetia papyrifera (L.) Vent.], and hackberry (Celtis laevigata Willd.) from multiple streams surrounding a perchlorate-contaminated site. Results indicate a large potential for ClO(-)(4) accumulation in aquatic and terrestrial plants, with ClO(-)(4) concentration in plant tissues approximately 100 times higher than that in bulk water. Perchlorate accumulation in leaves of terrestrial plants was also dependent on species, with hackberry, willow, and elm having a strong potential to accumulate ClO(-)(4). Generally, trees located closer to the stream had a higher ClO(-)(4) accumulation than trees located farther away from the stream. Seasonal leaf sampling of terrestrial plants indicated that ClO(-)(4) accumulation also was affected by exposure duration, with highest accumulation observed in the late growing cycle, although leaf concentrations for a given tree were highly variable. Perchlorate may be re-released into the environment via leaching and rainfall as indicated by lower perchlorate concentrations in collected leaf litter. Information obtained from this study will be helpful to understand the fate of ClO(-)(4) in macrophytes and natural systems.     

A low cost instrument based on a solid state sensor for balloon-borne atmospheric O(3) profile sounding

The design of an instrument based on a solid state tungsten oxide sensor for making profile measurements of atmospheric ozone from balloon platforms is described. The sensor is operated at a constant temperature, typically 530 [degree]C. The importance of a detailed consideration of the electronic design is demonstrated, with particular reference to the circuit to control the sensor heater. Calibration methods which are straightforward to implement are illustrated, and the results of a test flight alongside an electrochemical ozonesonde are shown. Quantitative agreement within 25% for most of the profile demonstrates the potential of this type of sensor for ozone sounding. Future improvements from manufacture to analysis are expected to improve on this.