Effects of Acidification and its Mitigation with Lime and Wood Ash on Forest Soil Processes in Southern Sweden. A Joint Multidisciplinary Study

A joint multidisciplinary investigation was undertaken to studythe effects of lime and wood ash applications on two Norway spruce forest Spodosolic soils. The two sites, typical for southern Sweden, were treated in 1994 with either 3.25 t ha^-1 dolomite or 4.28 t ha^-1 wood ash (Horröd site) or in 1984 with either 3.45 or 8.75 t ha^-1 dolomite (Hasslöv site). Both sites show signs of acidification by atmospheric anthropogenic deposition and possessed low soil pH(4.3) and high concentrations of inorganic Al (35 M) in theupper illuvial soil solution. The prevailing soil conditions indicated perturbed soil processes. Following treatment with lime or wood ash, the soil conditions were dramatically altered. Cation exchange capacity (CEC) and base saturation (BS) was considerable increased after addition. Four years after application most of the added Ca and Mg was still present in the mor layer. Fifteen years after application,Mg in particular, became integrated deeper in the soil profile with a greater proportion lost by leaching incomparison to Ca. The concentrations of these ions were greatestin the mor layer soil solutions and Mg had higher mobility givinghigher concentrations also deeper in the profile. Four years after treatment, the application of wood ash and limeresulted in lower pH values and higher inorganic Al in mineral subsoil solutions compared to the untreated soil. We hypothesize that this was probably due to an increased flow of hydrogen ionsfrom the upper soil as a result of displacement by Ca and Mg ionsin the enlarged exchangeable pool. In contrast, fifteen years after lime and wood ash application, the mineral subsoil horizonspossessed a higher pH and lower soil solution Al content than theuntreated plots.Liming promoted soil microbial activity increasing soil respiration 10 to 36%. This is in the same range as net carbon exchange for forests in northern Sweden and could potentially have a climatological impact. The turnover of low molecularweight organic acids (LMWOA) by the soil microbial biomass werecalculated to contribute 6 to 20% to this CO₂ evolution.At Horröd, citrate and fumarate were the predominant LMWOAs with lowest concentrations found in the treated areas. In contrast, at the Hasslöv site, propionate and malonate were the most abundant LMWOAs. Higher microbial activity in the upper soil horizons was also theprobable cause of the considerably higher DOC concentrations observed in the soil solution of ash and lime treated areas. Thelime-induced increase in DOC levels at Hasslöv could be attributed to increases in the 3–10 kDa hydrophobic size fraction. Liming also promoted nitrification with high liming doses leading to extreme concentrations of NO₃ ^- (1 mM) in soil solution.At Hasslöv the community of mycorrhizal fungi was dramatically changed by the addition of lime, with only four of 24 species recorded being common to both control and treated areas.Many of the observed effects of lime and ash treatment can be viewed as negative in terms of forest sustainability. After fouryears of treatment, there was a decrease in the pH of the soil solution and higher concentrations of inorganic Al and DOC. Increased organic matter turnover, nitrification and NO₃ ^-leakage were found at Hasslöv. Considering that the weathering rate and the mineral nutrient uptake by trees is mostprobably governed by mycorrhizal hyphae etchingmineral grains in the soil, it is important to maintain this ability of the mycorrhizal fungi. The lime and ash-induced changed mycorrhizal community structure may significantly affect this capability. In light of this investigation and others, as reviewed by Lundström et al. (2003), the implications ofliming on forest health are multifaceted with complex relationships occurring over both space and time.     

Corer-reactors for contaminant flux measurement in sediments

Design details and operating instructions are provided for a sediment corer that can be converted into a reactor for the measurement of the fluxes of contaminants from sediments to overlying waters. The corer-reactor permits measurements, under controlled laboratory conditions, on intact, largely undisturbed sediment cores, without significantly perturbing the physical and chemical conditions found in the field. The design can be constructed in-house for around US dollar 240 (A dollar 400) (excluding motor and corer lid), making it a relatively inexpensive system.     

Nutrient movement and removal in a switchgrass biomass-filter strip system treated with dairy manure

Manure use on cropland has raised concern about nutrient contamination of surface and ground waters. Warm-season perennial grasses may be useful in filter strips to trap manure nutrients and as biomass feedstock for nutrient removal. We explored the use of 'Alamo' switchgrass (Panicum virgatum L.) in a biomass production-filter strip system treated with dairy manure. We measured changes in extractable P in the soil, NO3 -N in soil water, and changes in total reactive P and chemical oxygen demand (COD) of runoff water before and after a switchgrass filter strip. Five rates of dairy manure (target rates of 0, 50, 100, 150, and 200 kg N ha(-1) from solid manure in 1995; 0, 75, 150, 300, and 600 kg N ha(-1) from lagoon effluent in 1996 and 1997) were surface-applied to field plots of switchgrass (5.2 by 16.4 m) with a 5.2- by 16.4-m switchgrass filter strip below the manured area. Yield of switchgrass from the manured area increased linearly with increasing manure rate in each year. Soil water samples collected at 46 or 91 cm below the soil surface on 30 dates indicated < 3 mg L(-1) of NO3-N in all plots. Concentrations of total reactive P in surface runoff water were reduced an average of 47% for the 150 kg N rate and 76% for the 600 kg N rate in 1996 and 1997 after passing through the strip. Manure could effectively substitute for inorganic fertilizer in switchgrass biomass production with dual use of the switchgrass as a vegetative filter strip.     

Ombrotrophic peat as a medium for historical monitoring of heavy metal pollution

Knowledge of historical trends in heavy metal deposition can aid the study and impact prediction of contemporary pollution. For this purpose, analysis of ombrotrophic peat cores has proved a valuable complement to other sedimentary analyses. However, doubts still remain concerning the mobility of heavy metals in peat. The debate cannot be resolved until the behaviour of these elements in peat is better understood. Peat cores were collected from hollows and hummocks on Ringinglow Bog in the southern Pennines. The cores were sliced into contiguous 1-cm slices. Samples were analysed for total concentrations of major elements (Al, Ca, K, Mg, Na) and trace metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn) using atomic absorption spectrophotometry. Multivariate statistical analysis was conducted on the data. Preliminary results indicate relatively high concentrations of Cd, Cu, Fe, Pb and Zn reflecting the influence of industrial activities in Sheffield and Manchester. As aluminium, cadmium, copper, lead and zinc exhibit similar profiles they may be suitable surrogates for monitoring historical pollution. However, other elements (e.g. Fe, K, Mn, Na) are clearly influenced by bog hydrology or plant translocation and would be inappropriate monitors.     

Silver concentrations in Welsh soils and their dispersal from derelict mine sites

In west and north Wales silver was mined extensively between 1750 and 1900, where it was frequently present as its sulphide form, argentite, whilst also occurring as a guest element in galena and sphalerite. Determination of the silver content of a range of soil types from areas devoid of mines by flameless atomic absorption spectrometry established normal background levels. Soils derived from black shales, or rich in organic matter were inherently richer in silver than the sandstone or limestone derived soils examined. Soils once exposed to contamination from the mining activities of the 19th Century can still be identified as they show elevated levels of silver. Fluvially derived contamination is confined to valley floodplains, but aerial transportation of mine spoil wastes enhance metal levels around derelict mine sites. Spoil analysed from areas of different geology contained a range of silver values reflecting variations in ore type, grain size and technique of ore extraction.     

Growth and population structure of Lepidochitona cinereus (Mollusca: Polyplacophora) infected with Minchinia chitonis (Protozoa: Sporozoa) at Easthaven,Scotland

Growth and population structure of Lepidochitona cinereus was studied at Easthaven in Scotland. Length was isometrically related to height and breadth, while tissue dry weight was negatively allometric. Length-shell weight relationships were variable with the time of year. Periods of differential growth were associated with the onset of growth in spring and gonad development in July. The use of growth-check lines to age individuals is described. Population structure and growth was investigated using a combination of winter growth-check line and length-frequency analyses. Infection with the protozoan Minchinia chitonis is shown to cause enhanced growth and deviation from the normal growth curve. Individuals survived for a maximum of 5 winters and length-frequency data could be interpreted only after growth-check line analysis due to extensive overlap of year-class size ranges. Year-class success was variable, and the present population was dominated by older year-classes.     

An assessment of attraction toward affirmative action organizations: investigating the role of individual differences

Our study investigated applicant characteristics in response to organizations incorporating an affirmative action policy (AAP) statement in recruitment material. Study participants (N = 217; White upper‐level management students) randomly received recruitment material containing one of three statements (e.g., affirmative action, equal employment opportunity (EEO), or no statement regarding affirmative action or EEO) and were asked to evaluate the attractiveness of the organization publicizing the designated policy. Results indicated that individuals responded negatively to AAPs in recruitment material because of prejudice attitudes, the perceived unfairness of such programs (which we relate to equity sensitivity), or in an attempt to protect their own self‐interest (which we relate to general self‐efficacy). Additionally, individuals' equity sensitivity and general self‐efficacy both moderated the relationship between racial prejudice and organizational attractiveness. Specifically, the negative relationships between participants' prejudice attitudes and the attractiveness of organizations publicizing an affirmative action policy were stronger for benevolents (persons tolerant of situations where they are under‐rewarded) and for persons low in self‐efficacy. Implications of our findings for organizational recruitment practices are discussed. Copyright © 2006 John Wiley & Sons, Ltd.     

Human exposure to PCDD/Fs in the UK: the development of a modelling approach to give historical and future perspectives

In order to assess the long-term impact of persistent organic contaminants such as polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) it is important to be able to quantify historical exposure. An understanding of past exposure is not only important to place our current body burdens in perspective, but is useful in assessing our potential future exposure. Unfortunately, very few direct measurements of our main source of exposure (i.e., food) over the past decades are available. This study attempts to reconstruct the historical exposure of the UK population to PCDD/Fs using a combination of emission estimates, information on environmental temporal trends derived from sediment cores and archived materials, and environmental/human fate modelling. Predicted adipose and blood lipid concentrations for a typical cross section of the population are derived over time (1920-2000), which is compared with measured data. The approach has been tested with two PCDDs and two PCDFs and showed encouraging agreement with measured data. Certain parts of the modelling methodology have been highlighted where there is still poor understanding of the processes governing fate and behaviour. These areas are discussed and recommendations for future improvements are made. The paper thus represents an initial modelling approach which defines both the historical (1920-present) and future (present-2020) fate of PCDD/Fs in the UK population.