Management of domoic acid monitoring in shellfish from the Catalan coast

Monitoring of amnesic shellfish poisoning (ASP) toxins in shellfish from the Catalan coast started in 2001. No ASP toxins were detected in any of the analyses performed before 2008. On 22 January 2008, domoic acid (DA) was detected in Donax trunculus (0.5 mg?kg^?1) and confirmed by rapid resolution liquid chromatography–tandem mass spectrometry (0.6 mg?kg^?1). A total of 974 shellfish samples were analyzed from January 2008 to December 2011, covering all the Catalan production areas and the most important marketed species. DA was detected in 23.8 % of the samples and was recorded every month in all areas and all species, except Ostrea edulis, although the percentage of samples with DA and DA content varied widely among samples. DA exceeded the regulatory level of 20 mg?kg^?1 twice: in Callista chione sampled on February 2008 and in D. trunculus sampled on April 2010. DA content in Bolinus brandaris appeared constant and close to 4.5 mg?kg^?1 for months in 2009. Mytilus galloprovincialis, Crassostrea gigas, and Ruditapes sp. presented very low concentrations of DA in the Ebro Delta bays, despite 113 alert situations according to Pseudo-nitzschia spp. abundances and the high number of shellfish samples analyzed. The origin of DA in Catalan shellfish remains unknown.     

Protective action of zinc against lead poisoning in tilapia Oreochromis niloticus

The accumulation of lead (Pb) in tilapias Oreochromis niloticus, acclimatized in cement tanks, and fed once a day with pellets of commercial food with lead nitrate, was investigated by square wave anodic stripping voltammetry (SWV). The head (including head bones, proteins, and brain) was the main target of lead uptake by tilapias, with a small amount in muscle tissue. A high concentration of Pb was found in feces which indicated low absorption by the organism when fed with high Pb concentration. The protective effects of zinc (Zn) against the Pb poisoning, the accumulation of Pb in the heads of the fishes of 107.8?±?3.1?mg?kg^?1 and in the viscera of 57.1?±?2.9?mg?kg^?1 with consequent decrease of calcium (Ca) concentration, were observed. In spite of the experimental time of 16 months and higher Pb concentration in the dietary food of 320?mg?kg^?1, no death of tilapias was observed due to the protective action of Zn.     

Implementation of a marine reserve has a rapid but short-lived effect on recreational angler use

Changes in human behavior are a precursor to measurable impacts of no-take marine reserves. We investigated changes in recreational fishing site selection in response to the 2005 announcement of enforcement in a marine reserve in the Gulf of California, Mexico. We used a novel data set of daily self-reported boating destinations from emergency rescue logbooks for a recreational angling community from 2000 to 2008. Because the reserve system has no experimental control, we modeled the data two ways to test for robustness to model specification. We tested for changes in human fishing behavior with regression and fit a fleet-level discrete choice model to project a. counterfactual scenario. The counterfactual is the statistically constructed ex post expectation of the human behavior we would have observed if the reserve never existed. We included month and year fixed effects in our models to account for seasonal and interannual fluctuations in fishing behavior and catch rates. We detected a decrease in reserve use compared to the counterfactual, indicating that the reserve rapidly experienced a decrease in visitation. However, the reserve's effect to reduce trips diminished with time. These results indicate that the reserve is unlikely to meet its ecological goals without institutional changes that enhance compliance. This illustrates the value of human use data to understanding the processes underlying marine reserve function. We suggest that managers should consider human use with the same frequency, rigor, and tools as they do fishery stocks. Marine reserves directly affect people, and understanding human behavioral responses to marine reserves is an important step in marine reserve management.     

A compilation of field surveys on gaseous elemental mercury (GEM) from contrasting environmental settings in Europe,South America,South Africa and China: separating fads from facts

Mercury is transported globally in the atmosphere mostly in gaseous elemental form (GEM, \( {\text{Hg}}_{\text{gas}}^{0} \) ), but still few worldwide studies taking into account different and contrasted environmental settings are available in a single publication. This work presents and discusses data from Argentina, Bolivia, Bosnia and Herzegovina, Brazil, Chile, China, Croatia, Finland, Italy, Russia, South Africa, Spain, Slovenia and Venezuela. We classified the information in four groups: (1) mining districts where this contaminant poses or has posed a risk for human populations and/or ecosystems; (2) cities, where the concentration of atmospheric mercury could be higher than normal due to the burning of fossil fuels and industrial activities; (3) areas with natural emissions from volcanoes; and (4) pristine areas where no anthropogenic influence was apparent. All the surveys were performed using portable LUMEX RA-915 series atomic absorption spectrometers. The results for cities fall within a low GEM concentration range that rarely exceeds 30 ng m^?3, that is, 6.6 times lower than the restrictive ATSDR threshold (200 ng m^?3) for chronic exposure to this pollutant. We also observed this behavior in the former mercury mining districts, where few data were above 200 ng m^?3. We noted that high concentrations of GEM are localized phenomena that fade away in short distances. However, this does not imply that they do not pose a risk for those working in close proximity to the source. This is the case of the artisanal gold miners that heat the Au–Hg amalgam to vaporize mercury. In this respect, while GEM can be truly regarded as a hazard, because of possible physical–chemical transformations into other species, it is only under these localized conditions, implying exposure to high GEM concentrations, which it becomes a direct risk for humans.     

Arsenic partitioning among particle-size fractions of mine wastes and stream sediments from cinnabar mining districts

Tailings from abandoned mercury mines represent an important pollution source by metals and metalloids. Mercury mining in Asturias (north-western Spain) has been carried out since Roman times until the 1970s. Specific and non-specific arsenic minerals are present in the paragenesis of the Hg ore deposit. As a result of intensive mining operations, waste materials contain high concentrations of As, which can be geochemically dispersed throughout surrounding areas. Arsenic accumulation, mobility and availability in soils and sediments are strongly affected by the association of As with solid phases and granular size composition. The objective of this study was to examine phase associations of As in the fine grain size subsamples of mine wastes (La Soterraña mine site) and stream sediments heavily affected by acid mine drainage (Los Rueldos mine site). An arsenic-selective sequential procedure, which categorizes As content into seven phase associations, was applied. In spite of a higher As accumulation in the finest particle-size subsamples, As fractionation did not seem to depend on grain size since similar distribution profiles were obtained for the studied granulometric fractions. The presence of As was relatively low in the most mobile forms in both sites. As was predominantly linked to short-range ordered Fe oxyhydroxides, coprecipitated with Fe and partially with Al oxyhydroxides and associated with structural material in mine waste samples. As incorporated into short-range ordered Fe oxyhydroxides was the predominant fraction at sediment samples, representing more than 80 % of total As.     

Influence of construction and demolition waste management on the environmental impact of buildings

The purpose of this study is to quantify comparable environmental impacts within a Life Cycle Analysis (LCA) perspective, for buildings in which the first (Materials) and last (End of Life) life cycle stages are adjusted to several waste/material management options. Unlike most LCAs, the approach is “top-down” rather than “bottom-up”, which usually involves large amounts of data and the use of specific software applications. This approach is considered appropriate for a limited but expedient LCA designed to compare the environmental impacts of different life cycle options.Present results, based on real buildings measurements and demolition contractor activities, show that shallow, superficial, selective demolition may not result in reduced environmental impacts. Calculations actually show an increase (generally less than 5%) in most impact categories for the Materials and End of Life stages because of extra transportation needs. However, core material separation in demolition operations and its recycling and/or reuse does bring environmental benefits. A reduction of around 77% has been estimated in the climate change impact category, 57% in acidification potential and 81% in the summer smog impact (for the life cycle stages referred).     

Detailed characterization of solute transport in a heterogeneous field soil

There is a necessity for improved physical understanding of solute transport processes in heterogeneous soil systems. In situ nondestructive techniques like time domain reflectometry (TDR) and fiber optic miniprobes (FOMPs) permit the collection of unique measurements of solute transport processes in soils for the purposes of model development and validation. This study examined the application of TDR and FOMPs to measure solute transport at various points laterally and at two depths in a heterogeneous clay-loam soil. A miscible displacement experiment was performed at a constant irrigation flux to examine the applicability of these probes to field soils. In their first application to a field soil, the FOMPs were successfully calibrated and performed well in measuring solute breakthrough curves. Two flow regimes were identified in the soil profile, the first where lateral spreading of the solute occurred in the surface horizon, followed by convergence into preferential flow pathways in the second transport zone. The measured transport response was heterogeneous with at least two identifiable vertical flow phases. It was demonstrated using transfer function modeling and data from a corresponding laboratory study that the FOMPs were measuring the slower phase, while the TDR probes captured a composite of the fast and slow phases. The combination of these two techniques may be a means to separate solute transport phases in heterogeneous media and relate laboratory column results to field studies.     

Untreated abandoned mercury mining works in a scenic area of Asturias (Spain)

Mercury mining was a large and thriving industry during the last century in Asturias (NW Spain). At Bra?alamosa, mining activity introduced significant quantities of wastes in spoil heaps located close to the mining operations. In these mining wastes, in addition to mercury, high concentrations of other potentially dangerous elements like As have been found. As a consequence, pollution and dereliction of the local environment occurred. This paper focuses on the environmental impact of these old mining operations and describes a preliminary assessment of the extent of contamination. This includes analytical data from systematic sampling of soils, stream sediments, wastes from spoil heaps, water and herbaceous plants in areas affected by mining activities. The potential risk that spoil materials imply for human health and the environment is documented on the basis of the application of EPA Risk Assessment methodology.     

Vegetation dynamics in impounded marshes along the Indian River Lagoon,Florida, USA

Data are presented on the vegetation dynamics of two impounded marshes along the Indian River Lagoon, in east-central Florida, USA. Vegetation in one of the marshes (IRC 12) was totally eliminated by overflooding and by hypersaline conditions (salinities over 100 ppt) that developed there in 1979 after the culvert connecting the marsh with the lagoon was closed. Over 20% recovery of the herbaceous halophytesSalicornia virginica, S. bigelovii, andBatis maritima was observed at that site after the culvert was reopened in 1982, but total cover in the marsh remains well below the original 75%. No recovery of mangroves was observed at this site. The second site (SLC 24), while remaining isolated from the lagoon during much of the study, did not suffer the complete elimination of vegetation experienced at the first site. At this location, mangroves increased in cover and frequency with a concomitant decrease in herbaceous halophytes. Considerable damage to the vegetation was evident at IRC 12 when the impoundment was closed and flooded for mosquito control in 1986. Although the damage was temporary, its occurrence emphasizes the need of planning and constant monitoring and adjustment of management details as conditions within particular marshes change. Storms and hurricanes may be important in promoting a replacement of black mangroves by red mangroves in closed impoundments because the former cannot tolerate pneumatophore submergence for long periods of time. University of Florida-IFAS Journal Series R-00521.