Environmental monitoring of carbaryl applied in urban areas to control the glassy-winged sharpshooter in California

Carbaryl insecticide was applied by ground spray to plants in urban areas to control a serious insect pest the glassy-winged sharpshooter, Homalodisca coagulata (Say), newly introduced inCalifornia. To assure there are no adverse impacts to human health and the environment from the carbaryl applications, carbaryl was monitored in tank mixtures, air, surface water, foliage and backyard fruits and vegetables.Results from the five urban areas – Porterville, Fresno, Rancho Cordova, Brentwood and Chico – showed there were no significanthuman exposures or impacts on the environment. Spray tank concentrations ranged from 0.1–0.32%. Carbaryl concentrationsin air ranged from none detected to 1.12 g m^-3, well below the interim health screening level in air of 51.7 g m^-3. There were three detections of carbaryl in surface water nearapplication sites: 0.125 ppb (parts per billion) from a water treatment basin; 6.94 ppb from a gold fish pond; and 1737 ppbin a rain runoff sample collected from a drain adjacent to a sprayed site. The foliar dislodgeable residues ranged from 1.54–7.12 g cm^-2, comparable to levels reported forsafe reentry of 2.4 to 5.6 g cm^-2 for citrus. Carbarylconcentrations in fruits and vegetables ranged from no detectableamounts to 7.56 ppm, which were below the U.S.EPA tolerance, allowable residue of 10 ppm.     

西印度洋地区海草生态系统

海草是海洋被子植物,广泛分布在温带和热带的海岸带水域,是地球上水生生态系统中最具生产力的生物之一.     

From Environmental Ethics to Nature Conservation Policy: Natura 2000 and the Burden of Proof

Natura 2000 is a network of natural sites whose aim is to preserve species and habitats of relevance in the European Union. The policy underlying Natura 2000 has faced widespread opposition from land users and received extensive support from environmentalists. This paper addresses the ethical framework for Natura 2000 and the probable moral assumptions of its main stakeholders. Arguments for and against Natura 2000 were analyzed and classified according to “strong” or “weak” versions of the three main theories of environmental ethics – anthropocentrism, biocentrism, and ecocentrism. Weak (intergenerational) anthropocentrism was found to underlie the Natura 2000 network itself and the positions of environmentalists, while strong (traditional) anthropocentrism pervaded the positions of economic developers. Land users seemed to fall somewhere between weak and strong anthropocentrism. The paper discusses the relation between ethics and different attitudes towards Natura 2000, highlighting some of the implications for the network’s ongoing implementation. It is shown that Natura 2000 achieves a strong reversal of the burden of proof from conservation to economic development and land use change under anthropocentrism. It is argued that the alleged theoretical divide between anthropocentrism and non-anthropocentrism in relation to the burden of proof does not seem to hold in practice. Finally, it is predicted that the weak versions of anthropocentrism, biocentrism, and ecocentrism, are likely to converge extensively in respect to nature conservation policy measures.“Charting the depths of law and policy disputes yield an understanding of ethical differences.” Paul B. Thompson (2002, p. 189).     

Sewage sludge effects on mesofauna and cork oak (Quercus suber L.) leaves decomposition in a Mediterranean forest firebreak

Effects of sewage sludge on litter mesofauna communities (Collembola and Acari) and cork oak (Quercus suber L.) leaf litter decomposition have been studied during 18 mo using litterbags in an in situ experimental forest firebreak in southeastern France. The sludge (2.74 t DM ha(-1) yr(-1)) was applied to fertilize and maintain a pasture created on the firebreak. Litterbag colonization had similar dynamics on both the control and fertilized plots and followed a typical Mediterranean pattern showing a greater abundance in spring and autumn and a lower abundance in summer. After 9 mo of litter colonization, Collembola and Acari, but mainly Oribatida, were more abundant on the sludge-fertilized plot. Leaf litter decomposition showed a similar pattern on both plots, but it was faster on the control plot. Furthermore, leaves from the fertilized plot were characterized by greater nitrogen content. Both chemical composition of leaves and sludges and the decomposition state of leaves have significantly affected the mesofauna community composition from each plot.     

CLFUG: A GIS‐scaleable model of pesticide fate in the soil–groundwater system based on clearance and fugacity paradigms

A model of pesticide transport through the soil profile based on clearance and fugacity paradigms is presented, and an example of its application in a GIS environment is shown. A validation of the model at the field plot scale is presented using data obtained at a crop in a semiarid irrigated agricultural basin which was treated with Lindane. The adequacy at the regional scale is tested by inspection of the model predictions and the measured concentrations of the pesticide obtained from a regional phreatimetric net. The clearance concept is used to obtain estimates of the volumes of some environmental phases. These are further used to solve the equations of thermodynamic equilibrium at equal fugacity and obtain concentration estimates. The model closely reproduces the observed percolation trends, and is consistent with the regional pattern of Lindane distribution in groundwater. An application of the model as unitary module for the simulation of non‐point pesticide sources in a raster GIS frame is shown. Its performance (run time, data needed, etc.) is comparable to that of other existing algorithms, and presents some advantages to planners and evaluators of environmental quality in that it incorporates an explicit 2‐D approach and allows the identification of polluted areas downslope with respect to those directly treated with the pesticides. Further, it can be implemented in a variety of GIS and spatial data processors.     

Life Cycle Analysis of Extruded Films Based on Poly(lactic acid)/Cellulose Nanocrystal/Limonene: A Comparative Study with ATBC Plasticized PLA/OMMT Systems

Life cycle analysis (LCA) of limonene plasticized poly(lactic acid) (PLA) films containing cellulose nanocrystals (CNC) extracted, by acid hydrolysis, from Phormium tenax leaf fibres, was assessed and compared with the results of acetyl tributyl citrate (ATBC) plasticized PLA films, having equivalent mechanical properties, containing organo-modified montmorillonite (OMMT). Eco-Indicator 99 tool has been adopted as the main method for life cycle assessment. Results indicated that, despite CNC are biobased fillers obtained by natural sources, the related chemical extraction leads to a large environmental footprint and a relatively relevant energy expense. LCA characterization of these films demonstrated that the environmental impact of PLA/limonene film reinforced with 1% in weight of CNC (PLA/CNC/limonene) is comparable to the environmental impact of polylactic acid films reinforced with OMMT and plasticized with a petroleum based plasticizer (ATBC) (PLA/OMTT/ATBC). A “cradle to gate” approach has been considered for both the film typologies.     

Management of sludge from fish ponds at the edge of the Itaparica Reservoir (Brazil): an alternative to improve agricultural production

Sludge generated in intensively managed tilapia fingerling breeding ponds near the Itaparica Dam in the semi-arid Brazilian northeastern region was tested as a soil conditioner to produce lettuce in an effort to mitigate the present environmental impact of the deposition of this sludge, thereby giving it a productive destiny. A greenhouse experiment was performed by mixing the sludge with a Haplic Planosol topsoil, a characteristic soil of the region, so that the sludge corresponded to 0, 25, 50, 75, and 100% of the mixture (substrate). The experiment was set up as a randomized block design with five blocks, each with three pots (5-kg substrate per pot) of the five sludge proportion treatments. One lettuce plant was transplanted into each pot, maintained under greenhouse conditions, and harvested 35 days after transplanting. Sludge, soil, and the substrates were evaluated for nutrient concentration and physical characteristics. Green and dry weights, stem diameter, and nitrogen, phosphorus, and potassium concentrations in the aboveground parts of the lettuce plants were determined. Sludge incorporation into the substrate improved its chemical and physical characteristics. The lettuce plants grew best in the substrate with 75% sludge, increasing its biomass production by 50% and more than doubling its nitrogen uptake.     

Managing Mediterranean soil resources under global change: expected trends and mitigation strategies

Regional Environmental Change - The soils of the Mediterranean Basin are the products of soil processes that have been governed by a unique convergence of highly differentiated natural and...     

Comparison of SOC estimates and uncertainties from aerosol chemical composition and gas phase data in Atlanta

In the Southeastern US, organic carbon (OC) comprises about 30% of the PM_2.5 mass. A large fraction of OC is estimated to be of secondary origin. Long-term estimates of SOC and uncertainties are necessary in the evaluation of air quality policy effectiveness and epidemiologic studies. Four methods to estimate secondary organic carbon (SOC) and respective uncertainties are compared utilizing PM_2.5 chemical composition and gas phase data available in Atlanta from 1999 to 2007. The elemental carbon (EC) tracer and the regression methods, which rely on the use of tracer species of primary and secondary OC formation, provided intermediate estimates of SOC as 30% of OC. The other two methods, chemical mass balance (CMB) and positive matrix factorization (PMF) solve mass balance equations to estimate primary and secondary fractions based on source profiles and statistically-derived common factors, respectively. CMB had the highest estimate of SOC (46% of OC) while PMF led to the lowest (26% of OC). The comparison of SOC uncertainties, estimated based on propagation of errors, led to the regression method having the lowest uncertainty among the four methods. We compared the estimates with the water soluble fraction of the OC, which has been suggested as a surrogate of SOC when biomass burning is negligible, and found a similar trend with SOC estimates from the regression method. The regression method also showed the strongest correlation with daily SOC estimates from CMB using molecular markers. The regression method shows advantages over the other methods in the calculation of a long-term series of SOC estimates.     

Monitoring of sources and atmospheric processes controlling air quality in an urban Mediterranean environment

Different monitoring parameters (PM mass concentrations, number–size distribution, black carbon, gaseous pollutants, and chemical composition, among others) are currently used in air quality studies. Urban aerosols are the result of several sources and atmospheric processes, which suggests that a single monitoring technique is insufficient to quantitatively evaluate all of them.This study assesses the suitability of a number of monitoring techniques (PM mass concentrations, number and size distribution of ultra-fine particles, levels of gaseous pollutants, and a complete chemical characterization of PM₁₀ and PM_2.5) by examining the response of those techniques to the different emission sources and/or atmospheric processes affecting an urban Mediterranean area (Barcelona, NE Spain).The results of this work reveal that the PM mass, the number concentration and the chemical composition give different, but complementary, information. Whereas the mineral matter, a key atmospheric aerosol component across the Mediterranean, is not properly quantitatively assessed by measuring sub-micrometric particles, the monitoring of the number concentration is indispensable to interpret the origin of specific aerosol episodes. Furthermore, the chemical composition yields very relevant information to deduce the causes of specific pollution episodes.The number concentration of ultra-fine particles in urban areas is strongly dependent upon vehicle exhaust emissions, which may cause adverse health impacts. Moreover, urban Mediterranean environments are favourable to produce nucleation-mode particles (<20 nm) with photochemical origin. In those cases, these particles are expected to be of high solubility and consequently their toxicity may differ from that of traffic-generated ultra-fine particles. Thus, the use of a single monitoring parameter to evaluate the health effects seems to be not enough.