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611.
Oscar Pindado Rosa Ma Pérez Susana García Miguel Sánchez Pilar Galán Marta Fernández 《Atmospheric environment (Oxford, England : 1994)》2009,43(17):2796-2803
The results from a year-long study of the organic composition of PM2.5 aerosol collected in a rural area influenced by a highway of Spain are reported. The lack of prior information related to the organic composition of PM2.5 aerosol in Spain, concretely in rural areas, led definition of the goals of this study. As a result, this work has been able to characterize the main organic components of atmospheric aerosols, including several compounds of SOA, and has conducted a multivariate analysis in order to assign sources of particulate matter. A total of 89 samples were taken between April 2004 and April 2005 using a high-volume sampler. Features and abundance of n-alkanes, polycyclic aromatic hydrocarbons (PAHs), alcohols and acids were separately determined using gas chromatography/mass spectrometry and high performance liquid chromatography analysis. The Σn-alkane and ΣPAHs ranged from 3 to 81 ng m?3 and 0.1 to 6 ng m?3 respectively, with higher concentrations during colder months. Ambient concentrations of Σalcohols and Σacids ranged from 21 to 184 ng m?3 and 39 to 733 ng m?3, respectively. Also, several components of secondary organic aerosol have been quantified, confirming the biogenic contribution to ambient aerosol. In addition, factor analysis was used to reveal origin of organic compounds associated to particulate matter. Eight factors were extracted accounting more than 83% of the variability in the original data. These factors were assigned to a typical high pollution episode by anthropogenic particles, crustal material, plant waxes, fossil fuel combustion, temperature, microbiological emissions, SOA and dispersion of pollutants by wind action. Finally, a cluster analysis was used to compare the organic composition between the four seasons. 相似文献
612.
Gabriel Ibarra-Berastegi Jon Sáenz Agustín Ezcurra Unai Ganzedo Javier Díaz de Argandoña Iñigo Errasti Alejandro Fernandez-Ferrero Josué Polanco-Martínez 《Atmospheric environment (Oxford, England : 1994)》2009,43(25):3829-3836
In Bilbao (Spain), an air quality network measures sulphur dioxide levels at 4 locations. The objective of this paper is to develop a practical methodology to identify redundant sensors and evaluate a network's capability to correctly follow and represent SO2 fields in Bilbao, in the frame of a continuous network optimization process.The methodology is developed and tested at this particular location, but it is general enough to be useable at other places as well, since it is not tied neither to the particular geographical characteristics of the place nor to the phenomenology of the air quality over the area.To assess the spatial variability of SO2 measured at 4 locations in the area, three different techniques have been used: Self-Organizing Maps (SOMs), cluster analysis (CA) and Principal Component Analysis (PCA). The results show that the three techniques yield the same results, but the information obtained via PCA can be helpful not only for that purpose but also to throw light on the major mechanisms involved. This might be used in future network optimization stages. The main advantage of cluster analysis and SOMs is that they provide readily interpretable results. All the calculations have been carried out using the freely available software R. 相似文献
613.
Juan G. Navea Shihe Xu Charles O. Stanier Mark A. Young Vicki H. Grassian 《Atmospheric environment (Oxford, England : 1994)》2009,43(26):4060-4069
We have carried out kinetic studies to characterize the heterogeneous decay of octamethylcyclotetrasiloxane (D4) and decamethylcyclopentasiloxane (D5) in the presence of representative mineral dust aerosol in order to obtain a better understanding of the atmospheric fate of these siloxanes. The heterogeneous chemistry of D4 and D5 with various mineral dusts was studied in an environmental aerosol reaction chamber using FTIR absorption spectroscopy to monitor the reaction. The apparent heterogeneous uptake coefficient, γapp, for D4 and D5 with various mineral dusts was measured under dry conditions and as a function of relative humidity (RH). In addition, the effect of initial D4 and D5 concentration on the rate and yield of the reaction was examined. The uptake coefficient, γapp, for D4 and D5 was similar for the most reactive aerosols tested, with kaolinite ≈hematite > silica. Limited uptake onto carbon black and calcite surfaces was observed for either siloxane. Reaction with hematite and kaolinite resulted in multilayer coverages, suggesting extensive polymerization of D4 and D5 on the aerosol surface. 相似文献
614.
Juan M. González Benítez J. Neil Cape Mathew R. Heal Netty van Dijk Alberto Vidal Díez 《Atmospheric environment (Oxford, England : 1994)》2009,43(26):4087-4094
Water soluble organic nitrogen (WSON) compounds are ubiquitous in precipitation and in the planetary boundary layer, and therefore are a potential source of bioavailable reactive nitrogen. This paper examines weekly rain data over a period of 22 months from June 2005 to March 2007 collected in 2 types of rain collector (bulk deposition and “dry + wet” deposition) located in a semi-rural area 15 km southwest of Edinburgh, UK (N55°51′44″, W3°12′19″). Bulk deposition collectors are denoted in this paper as “standard rain gauges”, and they are the design used in the UK national network for monitoring precipitation composition. “Dry + wet” deposition collectors are flushing rain gauges and they are equipped with a rain detector (conductivity array), a spray nozzle, a 2-way valve and two independent bottles to collect funnel washings (dry deposition) and true wet deposition. On average, for the 27 weekly samples with 3 valid replicates for the 2 types of collectors, dissolved organic nitrogen (DON) represented 23% of the total dissolved nitrogen (TDN) in bulk deposition. Dry deposition of particles and gas on the funnel surface, rather than rain, contributed over half of all N-containing species (inorganic and organic). Some discrepancies were found between bulk rain gauges and flushing rain gauges, for deposition of both TDN and DON, suggesting biological conversion and loss of inorganic N in the flushing samplers. 相似文献
615.
Bustamante J Pacios F Díaz-Delgado R Aragonés D 《Journal of environmental management》2009,90(7):2219-2225
We have used Landsat-5 TM and Landsat-7 ETM+ images together with simultaneous ground-truth data at sample points in the Doñana marshes to predict water turbidity and depth from band reflectance using Generalized Additive Models. We have point samples for 12 different dates simultaneous with 7 Landsat-5 and 5 Landsat-7 overpasses. The best model for water turbidity in the marsh explained 38% of variance in ground-truth data and included as predictors band 3 (630–690 nm), band 5 (1550–1750 nm) and the ratio between bands 1 (450–520 nm) and 4 (760–900 nm). Water turbidity is easier to predict for water bodies like the Guadalquivir River and artificial ponds that are deep and not affected by bottom soil reflectance and aquatic vegetation. For the latter, a simple model using band 3 reflectance explains 78.6% of the variance. Water depth is easier to predict than turbidity. The best model for water depth in the marsh explains 78% of the variance and includes as predictors band 1, band 5, the ratio between band 2 (520–600 nm) and band 4, and bottom soil reflectance in band 4 in September, when the marsh is dry. The water turbidity and water depth models have been developed in order to reconstruct historical changes in Doñana wetlands during the last 30 years using the Landsat satellite images time series. 相似文献
616.
Costa EA Campos VP da Silva Filho LC Greven HA 《Journal of environmental management》2009,90(2):1060-1068
In recent years, growing interest has focused on determining the performance of materials and evaluating the service life of structures exposed to various environmental forces. In this context, the determination of the aggressive potential of marine salts on mortars used as external renders is critical. The present study aimed to evaluate the spatial distribution of marine salts relative to distance from the sea. This was done by monitoring the deposition rate of chlorides and sulfates in wet candle sensors, located at nine stations scattered around the Metropolitan Region of Salvador, state of Bahia, Brazil. The study also determined the effectiveness of water-soluble salts at penetrating three different types of mortars of varying cement content via deposition and diffusion. The methodology employed enabled an evaluation of the efficiency of the monitoring sensors' measurement of the aggressiveness potential of local marine aerosol, and determination of the comparative performance of the three mortars tested, from the standpoint of resistance to salt penetration. The type and amount of salts captured both in solution and in powder samples extracted from the mortars were determined by ion chromatography. The analysis of the various types of mortars tested indicated which types are more resistant to the aggressive potential of the region's marine aerosol and the distance from the shore where local buildings are liable to be most strongly affected. 相似文献
617.
There are two principal strategies for managing climate change risks: mitigation and adaptation. Until recently, mitigation
and adaptation have been considered separately in both climate change science and policy. Mitigation has been treated as an
issue for developed countries, which hold the greatest responsibility for climate change, while adaptation is seen as a priority
for the South, where mitigative capacity is low and vulnerability is high. This conceptual divide has hindered progress against
the achievement of the fundamental sustainable development challenges of climate change. Recent attention to exploring the
synergies between mitigation and adaptation suggests that an integrated approach could go some way to bridging the gap between
the development and adaptation priorities of the South and the need to achieve global engagement in mitigation. These issues
are explored through a case study analysis of climate change policy and practice in Bangladesh. Using the example of waste-to-compost
projects, a mitigation-adaptation-development nexus is demonstrated, as projects contribute to mitigation through reducing
methane emissions; adaptation through soil improvement in drought-prone areas; and sustainable development, because poverty
is exacerbated when climate change reduces the flows of ecosystem services. Further, linking adaptation to mitigation makes
mitigation action more relevant to policymakers in Bangladesh, increasing engagement in the international climate change agenda
in preparation for a post-Kyoto global strategy. This case study strengthens the argument that while combining mitigation
and adaptation is not a magic bullet for climate policy, synergies, particularly at the project level, can contribute to the
sustainable development goals of climate change and are worth exploring. 相似文献
618.
The fate and transport processes of a toxic chemical such as atrazine, an herbicide, in a reservoir are significantly influenced
by hydrodynamic regimes of the reservoir. The two-dimensional (2D) laterally-integrated hydrodynamics and mass transport model,
CE-QUAL-W2, was enhanced by incorporating a submodel for toxic contaminants and applied to Saylorville Reservoir, Iowa. The
submodel describes the physical, chemical, and biological processes and predicts unsteady vertical and longitudinal distributions
of a toxic chemical. The simulation results from the enhanced 2D reservoir model were validated by measured temperatures and
atrazine concentrations in the reservoir. Although a strong thermal stratification was not identified from both observed and
predicted water temperatures, the spatial variation of atrazine concentrations was largely affected by seasonal flow circulation
patterns in the reservoir. In particular, the results showed the effect of flow circulation on spatial distribution of atrazine
during summer months as the river flow formed an underflow within the reservoir and resulted in greater concentrations near
the surface of the reservoir. Atrazine concentrations in the reservoir peaked around the end of May and early June. A good
agreement between predicted and observed times and magnitudes of peak concentrations was obtained. The use of time-variable
decay rates of atrazine led to more accurate prediction of atrazine concentrations, while the use of a constant half-life
(60 days) over the entire period resulted in a 40% overestimation of peak concentrations. The results provide a better understanding
of the fate and transport of atrazine in the reservoir and information useful in the development of reservoir operation strategies
with respect to timing, amount, and depth of withdrawal. 相似文献
619.
Understanding how setting attributes influence the nature of the visitor experience is crucial to effective recreation management.
Highly influential attributes are useful indicators to monitor within a planning framework, such as Limits of Acceptable Change.
This study sought to identify the setting attributes perceived to have the most profound effect on the ability to have “a
real wilderness experience” and to assess the degree to which attribute importance varied with situational context and visitor
characteristics. To this end, exiting hikers were surveyed at moderate and very high use trailheads in Alpine Lakes Wilderness,
WA (USA), and Three Sisters Wilderness, OR (USA). They were asked about the degree to which encountering varying levels of
different setting attributes would add to or detract from their experience. Attributes with the largest range of effect on
experience, based on evaluations of different levels, were considered most important. The most influential attributes were
litter and several types of campsite interaction—people walking through camp and number of other groups camping close by.
The perceived importance of setting attributes did not vary much between wilderness locations with substantially different
use levels, suggesting that conclusions are robust and generalizable across wilderness areas. There also was little difference
in the perceptions of day and overnight visitors. In contrast, we found substantial variation in the perceived importance
of setting attributes with variation in wilderness experience, knowledge, attachment, and motivation. Our results validate
the emphasis of many wilderness management plans on indicators of social interaction, such as number of encounters. 相似文献
620.
The Effect of Water Harvesting Techniques on Runoff,Sedimentation, and Soil Properties 总被引:1,自引:0,他引:1
This study addressed the hydrological processes of runoff and sedimentation, soil moisture content, and properties under the
effect of different water harvesting techniques (treatments). The study was conducted at three sites, representing environmental
condition gradients, located in the southern part of the West Bank. For each treatment, the study evaluated soil chemical
and physical properties, soil moisture at 30 cm depth, surface runoff and sedimentation at each site. Results showed that
runoff is reduced by 65–85% and sedimentation by 58–69% in stone terraces and semi-circle bunds compared to the control at
the semi-humid site. In addition, stone terraces and contour ridges significantly reduced the amount of total runoff by 80%
and 73%, respectively, at the arid site. Soil moisture content was significantly increased by water harvesting techniques
compared to the control in all treatments at the three study sites. In addition, the difference between the control and the
water harvesting structures were higher in the arid and semi-arid areas than in the semi-humid area. Soil and water conservation,
via utilization of water harvesting structures, is an effective principle for reducing the negative impact of high runoff
intensity and subsequently increasing soil moisture storage from rainfall. Jessour systems in the valley and stone terraces
were effective in increasing soil moisture storage, prolonging the growing season for natural vegetation, and decreasing the
amount of supplemental irrigation required for growing fruit trees. 相似文献