Comparison of batch leaching tests and influence of pH on the release of metals from construction and demolition wastes

Construction and demolition wastes are suitable for use in road construction. However, leaching characterization of recycled materials is required to determine their pollutant potential and the consequence of their application in different scenarios. The motivation of this paper is derived from the increasing use of different leaching test methods. In Europe, the confusion resulting from the wide variety of tests used to evaluate environmental properties of construction materials implies that an evaluation of the current practices and the attempt to consolidate the approaches are required.Two equilibrium-based leaching tests (the Dutch test and the European standard) were conducted to assess the environmental impact of four recycled aggregates. Three natural limestone aggregates were used as controls. Both tests measure the potential release of hazardous elements under extreme conditions using different leaching parameters (L/S ratio, pH value and contact time). The results proved that pH is the most relevant factor on the assessment of the differences between leaching methods due to its strong control on the pollutant release.To classify the materials according to their environmental effects, the concentration limit values of the metals imposed by Council Decision 2003/33/EC were used as a reference. The comparison allowed the classification of the recycled aggregates as inert wastes, with the exception of the MR-2 aggregate, which was classified as non-hazardous material.     

Environmental psychology with a Latin American taste

This paper describes and analyzes the actual and potential contributions of Latin American environmental psychology (EP) to the study of environment–behaviour interactions. Latin America is a richly socoi- and bio-diverse region; the multitude of problems caused by threats to its diversity requires especial conceptual and methodological approaches for studying and solving those problems. Latin American environmental psychologists have contributed ideas and studies according to the specificities (indigenous psychologies) of their nations. These specificities include Latin American traditions of collective participation, holistic worldviews, emotional attachment to places and other individuals, biospheric attitudes and preference for diversity, among others, in addition to the cultural traditions inherited from Europe. These traditions are considered in EP studies conducted by Latin American authors, which are described and commented upon. The importance of formative programs for a professionalizing environmental psychology in the area is discussed. Finally, this paper envisions the future of EP in Latin America. Such a forecast includes our vision of how environmental psychologists in the region could contribute to the general development of a universal environmental psychology.     

Phylogeography of the European stalked barnacle (Pollicipes pollicipes): identification of glacial refugia

The alternation of glacial and interglacial events during the Pleistocene has produced changes in species distribution ranges leading to bottlenecks and alterations of patterns of gene flow. The European stalked barnacle, Pollicipes pollicipes, is a sessile pedunculate cirripede that inhabits the rocky intertidal frame, from Senegal to the northwestern coast of France. In this work, we have analyzed a fragment of the mitochondrial gene cytochrome c oxidase subunit I for 569 individuals of P. pollicipes in order to investigate whether the shifts in climatic conditions that occurred during the Pleistocene influenced the current pattern of distribution of genetic variation of P. pollicipes. A pre-last glacial maximum pattern of demographic expansion was found, in concordance with many other North Atlantic marine species. On the other hand, three potential glacial refugia were identified: North African coasts, northwestern Iberian Peninsula and English Channel/Brittany.     

Factors influencing lead sorption-desorption at variable added metal concentrations in Rhodoxeralfs

The response of ten soils of the lithic Rhodoxeralf type to the supply of lead at concentrations of 500, 1000, 2000, 3000, 4000, 5000 and 6000 mg kg-1 was examined in batch sorption-desorption tests. Lead availability in the soils was found to depend on its partitioning between the soil solution and the solid phase as reflected in adsorption isotherms. The isotherms, of the H type, were consistent with a high affinity of the sorbent for the metal, with which it forms stable inner-sphere complexes on the soil surface. Sorption-desorption tests revealed that some properties of the soils such as their pH (mean=8) and high contents in clays (particularly in kaolinite) and crystalline iron oxides significantly influence Pb sorption, the effect being especially marked at high added metal concentrations. Added lead is largely retained by crystalline iron oxides and the soil clay fraction; the pH of the soil favours the release of variably-charged sites from both. The extent of Pb desorption was small, particularly at the lowest added levels (500 and 1000 mg kg-1). Desorption increased with increasing added Pb concentration and exceeded 50% at 5000 and 6000 mg kg-1; this suggests that Pb is present not only as inner-sphere complexes, but also as outer-sphere complexes and, partly, as precipitates. The desorption isotherms consist of three segments that exhibit significant differences depending on the added Pb concentration, namely: 500-1000, 2000-4000 and 5000-6000 mg kg-1.     

Land Management Versus Natural Factors in Land Instability: Some Examples in Northern Spain

The objective of this work is to test a hypothesis formulated on the basis of former results which considers that there might be a “global geomorphic change,” due to activities related to land management and not determined by climate change, which could be causing an acceleration of geomorphic processes. Possible relationships between some geomorphic processes related to land instability (landslides or sediment generation) and potential triggering factors are analyzed in study areas in northern Spain. The analysis is based on landslide inventories covering different periods, as well as the determination of sedimentation rates. Temporal landslide and sedimentation rate trends are compared with different indicators of human activities (land-use change, logging, forest fires) and with potential natural triggers (rainfall, seismicity). The possible influence of the road network in the distribution of landslides is also analyzed. Results obtained show that there is a general increase of both landslide and sedimentation rates with time that cannot be explained satisfactorily by observed rainfall trends and even less by seismicity. Land-use change appears to be by far the main factor leading to land instability, with some changes producing up to a 12-fold increase of landslide rate. A relationship between road network and the spatial distribution of landslides has also been observed. These results do confirm the existence of an acceleration of geomorphic processes in the region, and also suggest that climate-related factors play a limited role in the changes observed.