COLD WATER PATCHES IN WARM STREAMS: PHYSICOCHEMICAL CHARACTERISTICS AND THE INFLUENCE OF SHADING1

ABSTRACT: Discrete cold water patches within the surface waters of summer warm streams afford potential thermal refuge for cold water fishes during periods of heat stress. This analysis focused on reach scale heterogeneity in water temperatures as influenced by local influx of cooler subsurface waters. Using field thermal probes and recording thermistors, we identified and characterized cold water patches (at least 3°C colder than ambient streamflow temperatures) potentially serving as thermal refugia for cold water fishes. Among 37 study sites within alluvial valleys of the Grande Ronde basin in northeastern Oregon, we identified cold water patches associated with side channels, alcoves, lateral seeps, and floodplain spring brooks. These types differed with regard to within floodplain position, area, spatial thermal range, substrate, and availability of cover for fish. Experimental shading cooled daily maximum temperatures of surface waters within cold water patches 2 to 4°C, indicating a strong influence of riparian vegetation on the expression of cold water patch thermal characteristics. Strong vertical temperature gradients associated with heating of surface layers of cold water patches exposed to solar radiation, superimposed upon vertical gradients in dissolved oxygen, can partially restrict suitable refuge volumes for stream salmonids within cold water patches.     

Industrial facility deactivation: A proactive approach for reducing costs and liabilities

For both private corporations and military branches, downsizing and consolidation are becoming more commonplace. A range of environmental concerns must be addressed to effectively implement a consolidation program. A facility deactivation program can often become a minefield for an organization. Responsible personnel are typically inexperienced with the process, and this can lead to costly mistakes. This article provides insight into this topic based on experience gained with a multifacility program and related environmental issues. It emphasizes the importance of detailed, up-front, proactive project planning; a solid program management system; and accurate identification of project objectives and deliverables.     

PESTICIDES AND PESTICIDE DEGRADATION PRODUCTS IN STORMWATER RUNOFF: SACRAMENTO RWER BASIN,CALIFORNIA1

ABSTRACT: Pesticides in stormwater runoff, within the Sacramento River Basin, California, were assessed during a storm that occurred in January 1994. Two organophosphate insecticides (diazinon and methidathion), two carbamate pesticides (molinate and carbofuran), and one triazine herbicide (simazine) were detected. Organophosphate pesticide concentrations increased with the rising stage of the hydrographs; peak concentrations were measured near peak discharge. Diazinon oxon, a toxic degradation product of diazinon, made up approximately 1 to 3 percent of the diazinon load. The Feather River was the principal source of organophosphate pesticides to the Sacramento River during this storm. The concentrations of molinate and carbofuran, pesticides applied to rice fields during May and June, were relatively constant during and after the storm. Their presence in surface water was attributed to the flooding and subsequent drainage, as a management practice to degrade rice stubble prior to the next planting. A photo-degradation product of molinate, 4-keto molinate, was in all samples where molinate was detected and made up approximately 50 percent of the total molinate load. Simazine, a herbicide used in orchards and to control weeds along the roadways, was detected in the storm runoff, but it was not possible to differentiate the two sources of that pesticide to the Sacramento River.     

Workplace deviance,organizational citizenship behavior,and business unit performance: the bad apples do spoil the whole barrel

The influences of organizational citizenship behavior (OCB) and workplace deviant behavior (WDB) on business unit performance were investigated using data from branches of a fast food organization. Data included measures of WDB and OCB obtained from staff, ratings of performance provided by supervisors, and objective measures of performance. It was found that WDB was negatively and significantly associated with business unit performance measured both subjectively and objectively. OCB, however, failed to contribute to the prediction of business unit performance beyond the level that was achieved by WDB. It appeared, therefore, that the presence of deviant employees among business units impinges upon the performance of the business unit as a whole, whereas OCBs had comparatively little effect. Copyright © 2004 John Wiley & Sons, Ltd.     

Lessons after Bhopal: CSB a catalyst for change

The Bhopal tragedy was a defining moment in the history of the chemical industry. On December 3, 1984, a runaway reaction within a methyl isocyanate storage tank at the Union Carbide India Limited pesticide plant released a toxic gas cloud that killed thousands and injured hundreds of thousands. After Bhopal, industrial chemical plants became a major public concern. Both the public and the chemical industry realized the necessity of improving chemical process safety.

Bhopal served as a wake-up call. To prevent the same event from occurring in the United States, many legislative and industrial changes were invoked—one of which was formation of the U.S. Chemical Safety and Hazard Investigation Board (CSB). The ultimate goal of CSB is to use the lessons learned and recommendations from its investigations to achieve positive change within the chemical industry—preventing incidents and saving lives.

Although it seems clear that the lessons learned at Bhopal have improved chemical plant safety, CSB investigations indicate that the systemic problems identified at Bhopal remain the underlying causes of many incidents. These include:

• Lack of awareness of reactive hazards.

• Lack of management of change.

• Inadequate plant design and maintenance.

• Ineffective employee training.

• Ineffective emergency preparedness and community notification.

• Lack of root cause incident investigations and communication of lessons learned.

The aim of this paper is to present common themes from recent cases investigated by CSB and to discuss how these issues might be best addressed in the future.

This paper has not been independently approved by the Board and is published for general informational purposes only. Any material in the paper that did not originate in a Board-approved report is solely the responsibility of the authors and does not represent an official finding, conclusion, or position of the Board.     

Assessment of ambient ozone effects on vegetation using snap bean as a bioindicator species

Tropospheric ozone is an air pollutant that is toxic to plants, causing visible injury to foliage and a reduction in growth and yield. The use of plant bioindicators is one approach to assess the ozone impacts in diverse geographical areas. The objective of this study was to evaluate snap bean (Phaseolus vulgaris L.) as a potential bioindicator species. Three snap bean genotypes known to exhibit a range of ozone sensitivity were grown in pots under charcoal-filtered (CF) or nonfiltered (NF) treatments in open-top chambers, or under ambient air (AA) conditions. Treatment effects on biomass were not significant at 56 days after planting (DAP), but midseason foliar injury increased in the NF and AA treatments relative to CF controls. An increase in ozone from 25 to 30 nL L(-1) in CF controls to approximately 50 nL L(-1) in the NF and AA treatments was found to suppress final pod dry weight per plant by 40 to 60% in the most sensitive genotype S156. The same treatments suppressed final pod dry weight by 20 to 30% in a moderately sensitive genotype Oregon-91, and by 10% or less in a tolerant genotype R123. An S156 to R123 yield ratio of approximately one was observed under CF conditions. The S156 to R123 yield ratio declined to 0.6 to 0.7 in the NF treatment and declined further to 0.4 to 0.5 in the AA treatment, suggesting that ozone impact was underestimated in the open-top chambers. The results suggest that a snap bean bioindicator system has the potential to detect ambient ozone effects at present-day ozone concentrations.     

Bioproduction of ferric sulfate used during heavy metals removal from sewage sludge

Toxic metals removal from wastewater sewage sludge can be achieved through microbial processes involving Acidithiobacillus ferrooxidans. The oxidation of ferrous ions by A. ferrooxidans, cultured in sewage sludge filtrate, was studied in both batch and continuous flow stirred tank reactors. Sewage sludge filtrate containing natural nutrients (phosphorus and nitrogen) was recovered as effluent following the dehydration of a primary and secondary sludge mixture. Batch and continuous flow stirred tank reactor tests demonstrated that A. ferrooxidans were able to grow and completely oxidize ferrous iron in a culture medium containing more than 80% (v v(-1)) sewage sludge filtrate with 10 g Fe(II) L(-1) added. Toxic levels were reached when total organic carbon in the sewage sludge filtrate exceeded 250 mg L(-1). The ferric iron solution produced in the sludge filtrate by A. ferrooxidans was used to solubilize heavy metals in primary and secondary sludge. The solubilization of Cu, Cr, and Zn yielded 71, 49, and 80%, respectively. This is comparable with the yield percentages obtained using a FeCl(3) solution. The cost of treating wastewater sewage sludge by bioproducing a ferric ion solution from sewage sludge is three times less expensive than the conventional method requiring a commercial ferric chloride solution.