Fenton oxidation of 2,4- and 2,6-dinitrotoluene and acetone inhibition

The performances and kinetic parameters of Fenton oxidation of 2,4- and 2,6-dinitrotoluene (DNT) in water-acetone mixtures and explosive contaminated soil washing-out solutions were investigated at a laboratory scale. The experimental results show that acetone can be a significant hydroxyl radical scavenger and result in serious inhibition of Fenton oxidation of 2,4- and 2,6-DNT. Although no serious inhibition was found in contaminated soil washing-out solutions, longer reaction time was needed to remove 2,4- and 2,6-DNT completely, mainly due to the competition of hydroxyl radicals. Fenton oxidation of 2,4- and 2,6-DNT fit well with the first-order kinetics and the presence of acetone also reduced DNT’s degradation kinetics. Based on the comparison and matching of retention time and ultraviolet (UV) spectra between high performance liquid chromatography (HPLC) and standards, the following reaction pathway for 2,4-DNT primary degradation was proposed: 2,4-DNT → 2,4-dinitro-benzaldehyde → 2,4-dinitrobenzoic acid → 1,3-dinitrobenzene → 3-nitrophenol.     

Turbulent kinetic energy budgets in a model canopy: comparisons between LES and wind-tunnel experiments

A comparative study of turbulence in a wind-tunnel model canopy is performed, using Large eddy simulation (LES) and experimental data from PIV and hot-wire anemometry measurements. The model canopy is composed of thin cylindrical stalks. In the LES, these are represented using a plant-scale approach, while the scale-dependent Lagrangian dynamic model is used as subgrid-scale model. LES predictions of turbulence statistics and energy spectra are found to be in good agreement with the experimental data. Turbulent kinetic energy (TKE) budgets from the LES simulation are analyzed to provide more information absent in the measurements. Results confirm that sloshing motions at the low levels of the canopy are mainly driven by pressure fluctuations. A difference between the energy flux obtained from the energy spectrum and the SGS dissipation rate is observed, consistent with a spectral bypass mechanism in which the real spectral flux due to cascade is smaller than that implied by the energy-spectrum level, due to direct drain by the canopy.     

Current status and challenges of remediating petroleum‐derived PAHs in soils: Nigeria as a case study for developing countries

Polycyclic aromatic hydrocarbons (PAHs) are among the world's most significant environmental organic contaminants because of their carcinogenic properties. PAHs are widely distributed globally as a result of releases from numerous natural and anthropogenic activities. Consequently, several PAH monitoring studies have been conducted and remediation approaches explored. This article aims to provide the current status of PAH distribution in Nigeria's oil and gas industrial region in relation to the technologies adopted for PAH remediation. Ideally, the findings will provide insight into the challenges in managing organic contaminants derived from petroleum exploration activities in developing countries with Nigeria as a case study.     

Bioaerosols concentrations in working areas in biomethanization facilities

This study sought to fill the gap in information about the type and the concentration of bioaerosols present in the air of biomethanization facilities (BF). Evaluation of bioaerosol composition and concentration was achieved in two biomethanization facilities located in Eastern Canada, during summer and winter. In order to have a thorough understanding of the studied environment, the methodology combined culture of bacteria and molds, qualitiative polymerase chain reaction (qPCR) for specific microorganisms, endotoxin quantification, and next-generation sequencing (NGS) for bacterial diversity. Results revealed that workers in biomethanization facilities are exposed to bioaerosols and pathogenic microorganisms similar to those found in composting plants. However, human exposure levels to bioaerosols are lower in BF than in composting plants. Despite these differences, use of personal protective equipment is recommended to lower the risks of health problems.

Implications: Biomethanization is a new technology used in eastern Canada for waste management. In the next few years, it is expected that there will be an expansion of facilities in response of tight governmental regulations. Workers in biomethanization facilities are exposed to various amounts of bioaerosols composed of some harmful microorganisms. Therefore, monitoring this occupational exposure could be an interesting tool for improving worker’s health.     

Benefit‐Cost Analysis of Integrated Water Resource Management: Accounting for Interdependence in the Yakima Basin Integrated Plan

Integrated water resource management (IWRM) requires accounting for many interrelated facets of water systems, water uses and stakeholders, and water management activities. The consequence is that project analysis must account for the nonseparability among the component parts of IWRM plans. This article presents a benefit‐cost (B‐C) analysis of a set of projects included in the Yakima Basin Integrated Plan proposed for the Yakima Basin in south‐central Washington State. The analysis accounts for interdependence among proposed water storage projects and between water storage and water market development in the context of historical and more adverse projected future climate scenarios. Focusing on irrigation benefits from storage, we show that the value of a given proposed storage project is lower when other proposed storage projects in the basin are implemented, and when water markets are functioning effectively. We find that none of the water storage projects satisfy a B‐C criterion, and that assuring proposed instream flow augmentation is less expensive by purchasing senior diversion rights than relying on new storage to provide it.     

Land use and land cover in a transitioning militarized landscape

The repurposing of military lands is common in many parts of the world and presents a variety of conservation opportunities. This study examines land cover at Big Oaks National Wildlife Refuge, Indiana (U.S.A.) as it transitioned from military proving ground to wildlife refuge from 1985 to 2013. We use remote sensing, semi-structured interviews, and a review of planning and management documents to examine this transition. Limited change in land cover composition and distribution are detected, despite changes in use and management. This landscape similarity relates to similarities in land management practices, and the impact of landscape history on current management practices. The findings suggest that military use and conservation objectives at this site yield similar land covers and are not necessarily in contrast to each other. As military base closures continue, the potential to maintain and expand conservation opportunities on these lands will likely grow in importance.     

Comparing land change from shale gas infrastructure development in neighboring Utica and Marcellus regions, 2006–2015

The emergent patterns of land change resulting from the development of shale oil and gas infrastructure is a result of many small decisions and interactions. This research focuses on the land change associated with the development of shale oil and gas infrastructure in the Marcellus and Utica shale formations in two geographically proximate and physically similar counties, Carroll County, OH, and Washington County, PA. Land-cover data used to measure feature-scale change were digitized from aerial photography and then used to update National Land Cover Dataset data used in the calculation of forest fragmentation for the entire study areas. The amount and pattern of land change was very similar between the two counties even though they are drawing oil and gas from different shale formations. Less than 1% of the total forest for each county was lost but the fragmentation impacts are amplified by the pattern of infrastructure on the landscape.     

Characteristics of deforestation in the Democratic People’s Republic of Korea (North Korea) between the 1980s and 2000s

There has been a significant lack of land cover change studies in relation to deforestation in the Democratic People’s Republic of Korea (North Korea). The purpose of this study is to characterize deforestation in North Korea through land cover change trajectory and spatial analysis. We used three 30-m gridded land cover data sets for North Korea representing the conditions of the late 1980s, 1990s, and 2000s, respectively, as well as a digital elevation model. We examined the land cover trajectories during the two decades, i.e., which land cover became which at the pixel level. In addition, we calculated topographic characteristics of deforested pixels. Major findings from the study are summarized as follows: (1) net forest loss in North Korea was negligible in the latter decade compared to the former (>5000 km²), whereas other land cover changes were still active; (2) as a result of deforestation, forest land cover became mostly agricultural, particularly in the latter decade (95 %); (3) expansion of agricultural land cover continued during the time, increasing by >42 %; and (4) elevation and slope of deforested areas decreased slightly in the latter decade. The key contribution of the study is that it has demonstrated which land cover became which at the 30-m pixel level, complementing existing studies that examined overall forest stock in North Korea.     

Air Pollution Concentrations of PM2.5, PM10 and NO2 at Ambient and Kerbsite and Their Correlation in Metro City – Mumbai

Ambient concentrations of PM_2.5 and PM₁₀ are of concern with respect to effects on human health and environment. Increased levels of mortality and morbidity have been associated with respirable particulate air pollution. In India, it is not yet mandatory to monitor PM_2.5 levels therefore very limited information is available on PM_2.5 levels. To understand the fine particle pollution and also correlate with PM₁₀ which are monitored regularly in compliance with ambient air quality standards. This study was carried out to monitor PM_2.5, PM₁₀, and NO₂ for about one year in a residential cum commercial area of Mumbai city with a view to understand their correlation. The average PM_2.5 concentration at ambient and Kerbsite was 43 and 69 μg/m³. The correlation coefficients between PM_2.5 and PM₁₀ at ambient and Kerbsite were 0.83 and 0.85 respectively thus indicating that most of the PM_2.5 and PM₁₀ are from similar sources. TSP, PM₁₀ levels exceeded Central Pollution Control Board(CPCB) standard during winter season. PM_2.5 levels also exceeded 24 hourly average USEPA standard during winter season indicating unhealthy air quality.     

Northern Rivers Ecosystem Initiative: Nutrients and Dissolved Oxygen – Issues and Impacts

Anthropogenic inputs of nitrogen (N), phosphorus (P) and oxygen-consuming material to aquatic ecosystems can change nutrient dynamics, deplete oxygen, and change abundance and diversity of aquatic plants and animals. The Northern Rivers Ecosystem Initiative required a research and assessment program to establish the contribution of pulp mill and sewage discharges to eutrophication and depressions in dissolved oxygen (DO) in the Athabasca and Wapiti rivers of northern Alberta, Canada and examine the adequacy of existing guidelines for protecting these systems. Analysis of long-term data showed that total N (TN) and total P (TP) concentrations in exposed river reaches exceeded concentrations in reference reaches by ≤ 2 times for the Athabasca River, and by 9.6 (TP) and 2.6 (TN) times for the Wapiti River. Results from nutrient limitation experiments conducted in situ and in mesocosms showed that benthic algal production was nutrient sufficient downstream of pulp mill discharges but constrained in upper river reaches by insufficient P (Athabasca River) or N + P (Wapiti River). Dissolved oxygen (DO) concentrations in both rivers declined during winter such that median concentrations in the Athabasca River 945 km downstream of the headwaters were approximately 8 mg L⁻¹ in mid-February. Although water column DO rarely approached the guideline of 6.5 mg L⁻¹, DO studies undertaken in the Wapiti River showed that pore water DO often failed to meet this guideline and could not be predicted from water column DO. Results from this integrated program of monitoring and experimentation have improved understanding of the interactions between nutrients, DO and aquatic ecosystem productivity and resulted in recommendations for revisions to nutrient and DO guidelines for these northern rivers.The Canadian Crown reserves the right to retain a non-exclusive, royalty free licence in and to any copyright.