A New Polymer Platform for the Future — Sorona<Superscript>®</Superscript> from Corn Derived 1,3-Propanediol

Responding to environmental, sustainability, business, and market factors, DuPont has commercialized a new polymer platform, Sorona®, based on 1,3-propanediol. The physical and chemical property advantages over other polymers are described. The diol component of this polymer, 1,3-propanediol, has been demonstrated to be manufacturable via biological (fermentation) process from corn sugar. The economic, environmental, and process/product quality advantages of bio-PDO over conventional diols are discussed.     

EVALUATION OF NITRATE DATA IN THE OCKLAWAHA RIVER BASIN,FLORIDA (1953–2002)1

ABSTRACT: Nitrate levels in the Ocklawaha River Basin in north central Florida were reviewed over a 50‐year period. Data were obtained from the literature, U.S. Environmental Protection Agency (USEPA) STOrage and RETrieval (STORET), and U.S. Geological Survey (USGS) databases. The study objective was to determine whether nitrate concentrations are increasing and if so, whether this increase is linked to land use changes. Increasing nitrate levels were seen at 5 of the 14 stations, while other stations showed no trend or a decreasing trend. Median nitrate concentrations in the Ocklawaha River increased from 0.07 mg‐N/L to 0.78 mg‐N/L at sites downstream from the Silver River. Throughout the Rodman Reservoir, median nitrate concentrations decreased from 0.48 mg‐N/L to 0.01 mg‐N/L and increased to 0.04 mg‐N/L after the Kirkpatrick Dam. Flow and concentration relationships were correlated for five stations. At four of the five stations nitrate concentrations decreased in response to increasing flow, likely the result of dilution with nitrate poor water. Changes in land use over a 20‐ year period (1970 to 1990) also were monitored. Sources of nitrate have been linked by isotopic analysis to organic and inorganic fertilizers, which appear to be related to increased urbanization and an increase in lawns that require nutrient fertilization.     

Effects of Metal Mining and Milling on Boundary Waters of Yellowstone National Park, USA

/ Aquatic resources in Soda Butte Creek within Yellowstone National Park, USA, continue to be threatened by heavy metals from historical mining and milling activities that occurred upstream of the park's boundary. This includes the residue of gold, silver, and copper ore mining and processing in the early 1900s near Cooke City, Montana, just downstream of the creek's headwaters. Toxicity tests, using surrogate test species, and analyses of metals in water, sediments, and macroinvertebrate tissue were conducted from 1993 to 1995. Chronic toxicity to test species was greater in the spring than the fall and metal concentrations were elevated in the spring with copper exceeding water quality criteria in 1995. Tests with amphipods using pore water and whole sediment from the creek and copper concentrations in the tissue of macroinvertebrates and fish also suggest that copper is the metal of concern in the watershed. In order to understand current conditions in Soda Butte Creek, heavy metals, especially copper, must be considered important factors in the aquatic and riparian ecosystems within and along the creek extending into Yellowstone National Park.KEY WORDS: Mining; Metals; Toxicity; Biomonitoring; Copper; Yellowstone National Park     

Global and Regional Impacts of Stabilizing Atmospheric CO2

Among the key issues of concern to the Climate Convention is the stabilization of greenhouse gas concentrations and the minimization of impacts to global agriculture, natural ecosystems and economic development. The purpose of this paper is to couple these issues in consistent, integrated scenarios, using the IMAGE 2.0 model as an integrating tool. Scenarios of gradual stabilization of atmospheric CO₂ at 350 and 450 ppm are compared to a baseline of no policy action in which CO₂ concentration increases to 777 ppm. Under the stabilizaton scenarios substantially smaller areas of wheat and millet, as well as nature reserves, are threatened by climate change, especially in temperate regions. The amount of sea level rise is also reduced under the stabilization scenarios. However, climate continues to change under the stabilization scenarios and therefore some ‘residual’ climate impacts occur. Hence the integrated scenarios indicate that stabilizing greenhouse gas concentrations at or slightly above current levels will lessen impacts as compared to baseline levels, but not eliminate them. This revised version was published online in August 2006 with corrections to the Cover Date.     

Individual and species recognition in centrarchid fishes: evidence and hypotheses

Summary We conducted laboratory experiments to determine if juveniles of three species of centrarchid fishes displayed abilities for species or individual recognition. In one experiment we reared rock bass (Ambloplites rupestris) in social isolation and in social groups. Both the isolated and group-reared fish spent significantly more time close to conspecifics than to heterospecifics. These results suggest that species recognition in rock bass is controlled by a closed genetic program and that social experience is not necessary. A second set of experiments was conducted to determine if year-old blue-gill (Lepomis macrochirus), pumpkinseed (L. gibbosus), and rock bass juveniles could discriminate between familiar and unfamiliar conspecifics. Bluegill spent significantly more time with familiar conspecifics than with unfamiliar conspecifics, while the other two species displayed no such trend. Bluegill spent significantly more time with familiar conspecifics than did either of the other two species. We postulate that these interspecific differences in recognition abilities may be related to differences in habitat and group parameters among the species.     

Geographic Analysis of California Condor Sighting Data

Observation and habitat data were compiled and analyzed in conjunction with recovery planning for the endangered California Condor ( Gymnogyps californianus ). A geographic information system (GIS) was used to provide a quantitative inventory of recent historical Condor habitats, to measure the association of Condor activity patterns and mapped habitat variables, and to examine spatio-temporal changes in the range of the species during its decline. Only five percent of the study area within the historic range is now used for urban or cultivated agricultural purposes. Observations of Condor feeding perching, and nesting were nonrandomly associated with mapped land cover, in agreement with life history information for the species. The precipitous decline in numbers of Condors in this century produced only a small reduction in the limits of the observed species' range, as individual birds continued to forage over most of the range. Some critical risk factors such as shooting and lead poisoning are difficult to map and have not been included in the database. Besides the applications demonstrated in this case study, GIS can be a valuable tool for recovery planning, in the design of stratified sampling schemes, or for extrapolation of habitat models over unsurveyed regions. We conclude with recommendations from this case study regarding when to consider using GIS and the importance of pilot studies and sensitivity analysis.     

Patterns of litter disappearance in a northern hardwood forest invaded by exotic earthworms.

A field study was conducted to evaluate the effects of exotic earthworm invasions on the rates of leaf litter disappearance in a northern hardwood forest in southcentral New York, USA. Specifically, we assessed whether differences in litter quality and the species composition of exotic earthworm communities affected leaf litter disappearance rates. Two forest sites with contrasting communities of exotic earthworms were selected, and disappearance rates of sugar maple and red oak litter were estimated in litter boxes in adjacent earthworm-free, transition, and earthworm-invaded plots within each site. After 540 days in the field, 1.7-3 times more litter remained in the reference plots than in the earthworm-invaded plots. In the earthworm-invaded plots, rates of disappearance of sugar maple litter were higher than for oak litter during the first year, but by the end of the experiment, the amount of sugar maple and oak litter remaining in the earthworm-invaded plots was identical within each site. The composition of the earthworm communities significantly affected the patterns of litter disappearance. In the site dominated by the anecic earthworm Lumbricus terrestris and the endogeic Aporrectodea tuberculata, the percentage of litter remaining after 540 days (approximately 17%) was significantly less than at the site dominated by L. rubellus and Octolasion tyrtaeum (approximately 27%). This difference may be attributed to the differences in feeding behavior of the two litter-feeding species: L. terrestris buries entire leaves in vertical burrows, whereas L. rubellus usually feeds on litter at the soil surface, leaving behind leaf petioles and veins. Our results showed that earthworms not only accelerate litter disappearance rates, but also may reduce the differences in decomposition rates that result from different litter qualities at later stages of decay. Similarly, our results indicate that earthworm effects on decomposition vary with earthworm community composition. Furthermore, because earthworm invasion can involve a predictable shift in community structure along invasion fronts or through time, the community dynamics of invasion are important in predicting the spatial and temporal effects of earthworm invasion on litter decomposition, especially at later stages of decay.