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511.
Use of flue gas desulphurisation (FGD) waste and rejected fly ash in waste stabilization/solidification systems 总被引:1,自引:0,他引:1
Stabilization/solidification (S/S) processes have been used as the final treatment step for hazardous wastes prior to land disposal. Fly ash is a by-product of coal-fired power generation; a significant proportion of this material is low-grade, reject material (rFA) that is unsuitable as a cement replacement due to its high carbon content and large particle size (>45 microm). Flue gas desulphurization (FGD) sludge is a by-product from the air pollution control systems used in coal-fired power plants. The objective of this work was to investigate the performance of S/S waste binder systems containing these two waste materials (rFA and FGD). Strength tests show that cement-based waste forms with rFA and FGD replacement were suitable for disposal in landfills. The addition of an appropriate quantity of Ca(OH)2 and FGD reduces the deleterious effect of heavy metals on strength development. Results of TCLP testing and the progressive TCLP test show that cement-rFA-Ca(OH)2 systems with a range of FGD additions can form an effective S/S binder. The Leachability Index indicates that cement-based waste forms with rFA replacement were effective in reducing the mobility of heavy metals. 相似文献
512.
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515.
Y.G. Zhang H.S. Wang G. Somesfalean Z.Y. Wang X.T. Lou S.H. Wu Z.G. Zhang Y.K. Qin 《Atmospheric environment (Oxford, England : 1994)》2010,44(34):4266-4271
A gas monitoring system based on broadband absorption spectroscopic techniques in the ultraviolet region is described and tested. The system was employed in real-time continuous concentration measurements of sulfur dioxide (SO2) and nitric oxide (NO) from a 220-ton h?1 circulating fluidized bed (CFB) boiler in Shandong province, China. The emission coefficients (per kg of coal and per kWh of electricity) and the total emission of the two pollutant gases were evaluated. The measurement results showed that the emission concentrations of SO2 and NO from the CFB boiler fluctuated in the range of 750–1300 mg m?3 and 100–220 mg m?3, respectively. Compared with the specified emission standards of air pollutants from thermal power plants in China, the values were generally higher for SO2 and lower for NO. The relatively high emission concentrations of SO2 were found to mainly depend on the sulfur content of the fuel and the poor desulfurization efficiency. This study indicates that the broadband UV spectroscopy system is suitable for industrial emission monitoring and pollution control. 相似文献
516.
C.A. Alves C. Gonçalves C.A. Pio F. Mirante A. Caseiro L. Tarelho M.C. Freitas D.X. Viegas 《Atmospheric environment (Oxford, England : 1994)》2010,44(25):3024-3033
Gaseous and particulate samples from the smoke from prescribed burnings of a shrub-dominated forest with some pine trees in Lousã Mountain, Portugal, in May 2008, have been collected. From the gas phase Fourier transform infrared (FTIR) measurements, an average modified combustion efficiency of 0.99 was obtained, suggesting a very strong predominance of flaming combustion. Gaseous compounds whose emissions are promoted in fresh plumes and during the flaming burning phase, such as CO2, acetylene and propene, produced emission factors higher than those proposed for savannah and tropical forest fires. Emission factors of species that are favoured by the smouldering phase (e.g. CO and CH4) were below the values reported in the literature for biomass burning in other ecosystems. The chemical composition of fine (PM2.5) and coarse (PM2.5–10) particles was achieved using ion chromatography (water-soluble ions), instrumental neutron activation analysis (trace elements) and a thermal–optical transmission technique (organic carbon and elemental carbon). Approximately 50% of the particulate mass was carbonaceous in nature with a clear dominance of organic carbon. The organic carbon-to-elemental carbon ratios up to 300, or even higher, measured in the present study largely exceeded those reported for fires in savannah and tropical forests. More than 30 trace elements and ions have been determined in smoke aerosols, representing in total an average contribution of about 7% to the PM10 mass. 相似文献
517.
Gudelis A Druteikiene R Luksiene B Gvozdaite R Nielsen SP Hou X Mazeika J Petrosius R 《Journal of environmental radioactivity》2010,101(6):464-467
Two RBMK-1500 reactor units operated in Lithuania in the 1987-2004 period (one of them was stopped for decommissioning in 2004). This study presents a preliminary investigation of surface deposition density levels of 55Fe and 63Ni in moss samples collected in the close vicinity of the Ignalina NPP. Non-destructive analysis by the HPGe gamma-spectrometry was followed by radiochemical separation. Radiochemical analysis was based on anion-exchange and extraction chromatography. 55Fe and 63Ni activities were measured by liquid scintillation counting (LSC). The results indicate that the deposition values of 55Fe are generally higher than those of 60Co and 63Ni. 相似文献
518.
Praveen Linga Rajnish Kumar Ju Dong Lee John Ripmeester Peter Englezos 《International Journal of Greenhouse Gas Control》2010,4(4):630-637
A new apparatus employing a modular, mechanically agitated gas-inducing crystallizer is used to demonstrate the capture of CO2 via hydrate crystallization. The crystallizer enhances the contact of hydrate forming gases with water and thus the rate of hydrate crystallization increases. Flue gas (CO2/N2) and fuel gas (CO2/H2) mixtures were used to represent post- and precombustion capture. A comparison between the rates of hydrate formation in different crystallizers is presented by defining a metric called the normalized rate of hydrate formation. The gas uptake and the separation efficiency for the fuel and flue gas mixtures were found to be greater compared to the results obtained in a smaller scale stirred tank reactor (Kumar et al., 2009c, Linga et al., 2008). The gas uptake and CO2 recovery for flue gas mixture in the presence of THF obtained in this work was higher than that reported in the literature with tetra-n-butyl ammonium bromide and tetra-n-butyl ammonium fluoride (Fan et al., 2009, Li et al., 2009). Although hydrate crystallization is able to capture CO2, the power required for mechanical agitation was found to be very significant. If the hydrate process is to be used industrially then hydrate crystallization must be carried out without mechanical agitation. 相似文献
519.
Agricultural ammonia emissions inventory and spatial distribution in the North China Plain 总被引:7,自引:0,他引:7
Y. Zhang A.J. Dore X.J. Liu W.Q. Ma J.N. Cape 《Environmental pollution (Barking, Essex : 1987)》2010,158(2):490-501
An agricultural ammonia (NH3) emission inventory in the North China Plain (NCP) on a prefecture level for the year 2004, and a 5 × 5 km2 resolution spatial distribution map, has been calculated for the first time. The census database from China's statistics datasets, and emission factors re-calculated by the RAINS model supported total emissions of 3071 kt NH3-N yr−1 for the NCP, accounting for 27% of the total emissions in China. NH3 emission from mineral fertilizer application contributed 1620 kt NH3-N yr−1, 54% of the total emission, while livestock emissions accounted for the remaining 46% of the total emissions, including 7%, 27%, 7% and 5% from cattle, pigs, sheep and goats, and poultry, respectively. A high-resolution spatial NH3 emissions map was developed based on 1 × 1 km land use database and aggregated to a 5 × 5 km grid resolution. The highest emission density value was 198 kg N ha−1 yr−1. 相似文献
520.
The effect of soil organic matter on fate of polycyclic aromatic hydrocarbons in soil: A microcosm study 总被引:1,自引:0,他引:1
Y. Yang N. Zhang D.Y. Zhang X.Q. Li 《Environmental pollution (Barking, Essex : 1987)》2010,158(5):1768-1774
A microcosm study was conducted to address the influences of air-soil partition and sequestration on the fate of polycyclic aromatic hydrocarbons (PAHs) in soil. Sterilized and unsterilized soils with soil organic carbon (SOC) content ranging from 0.23 to 7.06% were incubated in a chamber with six PAHs supplied through air. After 100 d of incubation when the system approached pseudo-steady state, the PAHs concentrations in the unsterilized soils still correlated with SOC significantly, while the association did not exist for those sterilized. The lower degradation rate in the soil with higher SOC was likely the major reason for the association between SOC and PAHs concentrations, while the decreased surface porosity likely suppressed such correlation for the sterilized samples. The results indicated that the sequestration was likely the major mechanism for the accumulation of PAHs in soils, while both of the soil porosity and PAHs properties had observed influences. 相似文献