首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   269篇
  免费   1篇
  国内免费   2篇
安全科学   8篇
废物处理   22篇
环保管理   10篇
综合类   23篇
基础理论   52篇
污染及防治   104篇
评价与监测   34篇
社会与环境   16篇
灾害及防治   3篇
  2023年   6篇
  2022年   22篇
  2021年   19篇
  2020年   12篇
  2019年   11篇
  2018年   18篇
  2017年   23篇
  2016年   21篇
  2015年   9篇
  2014年   27篇
  2013年   30篇
  2012年   10篇
  2011年   13篇
  2010年   7篇
  2009年   9篇
  2008年   6篇
  2007年   7篇
  2006年   4篇
  2005年   5篇
  2004年   1篇
  2003年   4篇
  2002年   3篇
  2001年   1篇
  2000年   1篇
  1998年   1篇
  1994年   1篇
  1981年   1篇
排序方式: 共有272条查询结果,搜索用时 281 毫秒
71.

In addition to direct photolysis studies, in this work the second-order reaction rate constants of pesticides imidacloprid (IMD) and ametryn (AMT) with hydroxyl radicals (HO), singlet oxygen (1O2), and triplet excited states of chromophoric dissolved organic matter (3CDOM*) were determined by kinetic competition under sunlight. IMD and AMT exhibited low photolysis quantum yields: (1.23?±?0.07)?×?10–2 and (7.99?±?1.61)?×?10–3 mol Einstein?1, respectively. In contrast, reactions with HO radicals and 3CDOM* dominate their degradation, with 1O2 exhibiting rates three to five orders of magnitude lower. The values of kIMD,HO● and kAMT,HO● were (3.51?±?0.06)?×?109 and (4.97?±?0.37)?×?109 L mol?1 s?1, respectively, while different rate constants were obtained using anthraquinone-2-sulfonate (AQ2S) or 4-carboxybenzophenone (CBBP) as CDOM proxies. For IMD this difference was significant, with kIMD,3AQ2S*?=?(1.02?±?0.08)?×?109 L mol?1 s?1 and kIMD,3CBBP*?=?(3.17?±?0.14)?×?108 L mol?1 s?1; on the contrary, the values found for AMT are close, kAMT,3AQ2S*?=?(8.13?±?0.35)?×?108 L mol?1 s?1 and kAMT,3CBBP*?=?(7.75?±?0.80)?×?108 L mol?1 s?1. Based on these results, mathematical simulations performed with the APEX model for typical levels of water constituents (NO3?, NO2?, CO32?, TOC, pH) indicate that the half-lives of these pesticides should vary between 24.1 and 18.8 days in the waters of the Paranapanema River (São Paulo, Brazil), which can therefore be impacted by intensive agricultural activity in the region.

  相似文献   
72.
Environmental Science and Pollution Research - One of the most widely used antibiotics is amoxicillin (AMX), which is the most widely used in humans and animals, but it is discharged metabolically...  相似文献   
73.
Environmental Science and Pollution Research - Pesticides have been used to kill pests such as insects, fungi, rodents, and unwanted plants. Since these compounds are potentially toxic to the...  相似文献   
74.
Environmental Science and Pollution Research - Lentinus crinitus bioaccumulates lithium in mycelia, but bioaccumulation may be affected by pH of the culture medium. Lithium is used in clinical...  相似文献   
75.
Environmental Science and Pollution Research - In this work, Ag-doped ZnO nanoparticles (NPs) were synthesized by a simple green method using a toxic agent-free route for photocatalytic purposes,...  相似文献   
76.
Invasion by alien species is one of the most critical factors affecting global biodiversity, leading to homogenization and species loss worldwide. Jackfruit (Artocarpus heterophyllus Lam., Moraceae) is one of the most conspicuous invasive plants in Brazil. We studied jackfruit invasion in the Atlantic Forest in Ilha Grande State Park, located on an island (Ilha Grande), by assessing jackfruit distribution and density along 23 trails (90 km). Presence or absence was verified in a total of 857 plots. Data showed that jackfruit is spread all over Ilha Grande, and that plant density varied significantly along and between trails. Jackfruit was registered as the dominant tree species on some of the trails. Control by park managers is an urgent need in order to ensure the conservation of local biodiversity. A decision key for jackfruit management according to jackfruit density, age class and slope is provided.  相似文献   
77.
Previous studies in the Douro River estuary, based on occasional sampling, showed the presence of several estrogenic disrupting chemicals (EDCs). In sequence, we hypothesized that such type of pollution was more likely an enduring issue than an occasional phenomenon, and that it may even affect recreational beaches in each side of the estuarine mouth. Thus to conclude about the continuous influx of EDCs, water samples were taken twice a day, once per a week, from March to May of 2009, at four sites within the estuary and at two sites in the coastline. After solid-phase extraction, the extracts were prepared for GC-MS analysis of 11 reference EDCs. These embraced natural and pharmaceutical estrogens (17β-estradiol, estrone and 17α-ethynylestradiol) and xenoestrogenic industrial pollutants (4-octylphenol, 4-nonylphenol, and their mono and diethoxylates and bisphenol A). Data showed the ubiquitous presence of potentially hazardous amounts of natural estrogens (particularly of estradiol, ca 5.5?ng?L?1) and persistent organic pollutants such as nonylphenol mono (up to 550?ng?L?1) and diethoxylate (up to 2000?ng?L?1). It was concluded that the targeted area is continuously polluted by the assayed EDCs, and as a consequence, conditions exist for endocrine disturbance in the biota by chronic exposure to EDCs.  相似文献   
78.
Previous studies indicate that when predation risk is uniform across habitats, foragers concentrate their exploitation in fewer patches. Although uniform predation risk may seem rare in nature, some scenarios might cause it. Testing all scenarios in a single experiment is unfeasible; therefore, we developed a model that points whether concentration of exploitation in specific habitats due to uniform risk requires parameter values similar to what is found in literature. This model was based on Brown’s (Behav Ecol Sociobiol 22:37–47, 1988) fitness function but rescaled to multiple habitats and predators, including uniform risk predators. Deriving function’s maximum allowed comparisons with giving-up density studies. Results showed that uniform predation risk had a u-shaped effect in habitat exploitation, causing a concentration of habitat exploitation at probabilities of survival from 0.2 to 0.8. However, the length of this interval and degree of concentration depended on the value of safety to forager fitness. Heterogeneous, nonuniform, predation risk decreases habitat exploitation where it was higher, therefore suppressing the effect of uniform risk on prey behavior. Time spent in the focal habitat and metabolic costs reduced the detectability of habitat concentration, while total time did not. We also found that uniform risk reduced accuracy of heterogeneous risk measurements. Future studies should aim to control all possible predators, as even the mild ones can induce complex behavior.  相似文献   
79.
Finding solutions for complex environmental, economic and social issues in organisations relies on coordinated actions among several social actors that are involved in the sustainable development web and demands that they learn new business methods. In this scenario, which involves multiple social actors, relationships, contexts and interests, social learning has emerged as a hybrid approach to resolving complex environmental and social problems. Such an approach marks a different situation for organisations whose focus is not only on supporting such problem resolution but also on transforming such crises into opportunities to generate sustainable products and services. Thus, this study discusses how one of the largest companies in Latin America’s chemical segment formed a network with 23 social actors and is socially learning to deal with the dialectic between return on investments for its shareholders and benefits for its stakeholders. Research was conducted based on Boje’s narrative analysis. The data was built through interviews, informal conversations, textual and audio-visual documents and non-participant observation. This paper discusses the concept and describes the social learning process for sustainability (in this case, for sustainable agriculture) from the viewpoint of a for-profit organisation. In this manner, this study contributes to strengthening the connection between social learning and sustainability.  相似文献   
80.
The Canary Islands have a long coastline with varying levels of exposure to severe sea conditions. Frequent states of alert and emergency in some parts of their coastline are commonly related to the occurrence of extreme wave conditions. Among the phenomena directly driven by the waves when reaching the shore are the wave run-up and overtopping. Both the study of the flood level, including its variability, and the associated risks are key tools in the planning and management of coastal zones. The aim of this research is to examine the probability of occurrence of run-up events capable of exceeding different topographical levels, for estimating the risk level associated with flooding of the different areas in which the Boca Barranco Beach can be divided, in terms of their nature and use. This beach is located on the island of Gran Canaria, Spain, and is part of the site of scientific interest of Jinámar. A large wave dataset is used as input to a high-resolution numerical model for propagating offshore wave conditions to shallow waters in the study area. Furthermore, the morphology of the study area is reproduced by combining different bathymetric databases. Finally, the probability of occurrence of different levels of run-up and the corresponding levels of consequences are assigned, to assess the flood risk in the different areas of the beach, which are presented in a risk map of flooding in the study area.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号