Pesticide uses and transfers in urbanised catchments

An investigation on herbicide uses in two semi-urban catchments was performed simultaneously with sampling campaigns at six stations inside both watersheds from April to July 1998. Urban uses of herbicides exceeded agricultural uses, and transfer coefficients were also higher in urban areas. Therefore, the most used product in urban areas (diuron) was by far the most contaminating product. Householders accounted for 30% of all uses. The highest measured diuron concentration in water surface was 8.7 microg l(-1) due to its use on impervious surfaces. Compared to EEC standards for drinking water production (0.1 microg l(-1)), it is clear that suburban uses of herbicides may severely endanger drinking water production from river water.     

Sources and evolution of anthropogenic lead in dated sediments from Lake Clair, Québec, Canada

Two sediments cores were collected from the deepest part of Lake Clair (Québec, Canada) to assess the historical sources of Pb additions to the lake. The cores were collected by divers by carefully inserting a Plexiglas tube into the sediments. To determine the stratigraphic ages of the sediments, (210)Pb and (137)Cs activities were counted by gamma-ray spectroscopy. Lead concentrations and isotopic ratios were performed by inductively coupled plasma-mass spectrometry (ICP-MS), following digestion of the samples with a mixture of HF, HNO(3), and HClO(4) acids and Pb separation by anion-exchange chromatography. Starting at the middle of the 19th century, Pb content of the sediments increased until 1975. The maximum Pb enrichment factor of 35 times (relative to the natural background) was found in sediments deposited in 1975. At this time, excess Pb flux was estimated to be about 0.03 g m(-2) yr(-1). Before 1872, the Pb isotopic ratios were relatively stable (mean (206)Pb/(207)Pb = 1.20 +/- 0.01), reflecting the natural Pb background. Between 1872 and 1894, the source of anthropogenic Pb was highly radiogenic as shown by the Pb isotopic signatures of the sediments (mean (206)Pb/(207)Pb = 1.22 +/- 0.01), possibly reflecting deforestation and agricultural developments in the St.-Lawrence Valley. Between 1894 and 1937, widespread use of industrial and domestic charcoals may explain the isotopic composition of Pb accumulated in the sediments (mean (206)Pb/(207)Pb = 1.19 +/- 0.01). From 1937 to 1975, Pb isotopic compositions became less radiogenic ((206)Pb/(207)Pb from 1.18 to 1.17) even though elemental Pb abundance reached extremely high values (623 mg kg(-1)). This isotopic shift reflects increased use of alkyl-lead in gasoline. For sediments accumulated between 1967 and 1996, the U.S. contribution to anthropogenic Pb accumulated in Lake Clair sediments amounted to between 30 and 63%.     

A methodology to estimate the denitrifying capacity of a riparian wetland

Numerous studies have shown that riparian wetlands can play an important role in reducing nitrate concentrations before the ground water discharges into streams. Denitrification has been identified as an important process for this removal. Several approaches have been proposed to predict the denitrifying removal capacity of a riparian wetland, but no widely used tool exists to precisely quantify this capacity at the landscape scale. We propose such a methodology based on modeling the spatial variation of soil-water interactions in the entire riparian wetland. Mean values of denitrification enzyme activity (DEA) within three soil-denitrifying classes were 604, 212, and 24 ng N g(-1) h(-1) for Classes 3, 2, and 1, respectively. The study area, having a ground surface of about 15000 m2, was underlain by an aquifer with a calculated volume of 60000 m3, less than 10000 m3 of which corresponded to active denitrifying horizons (Classes 2 and 3). By volume, approximately 30% of Class 3 and 70% of Class 2 were interacting with ground water. The denitrifying removal capacity of our wetland was calculated to be about 1.8 kg N m(-2) yr(-1). The calculated denitrifying capacity of our site was less than expected. This is due to the fact that not all ground water interacts with the horizons having the highest denitrifying capacity. Thus, we show that whatever the system is, specific local pedological and hydrogeological conditions and their interactions are paramount in controlling the denitrification process.     

Exhaled NH3 and excreted Nh4+ in children in unpolluted or urban environments

Exhaled ammonia (NH3ex) was measured by chemiluminescence in a group of healthy children (n = 20) and in two groups of asthmatic children, one (Group 1) residing in a National Park in the mountains (n = 68) and other (Group 2) in an urban area (n = 52). We also determined urinary ammonia, nitrates, urea, sodium and potassium normalized to osmolarity. Unlike exhaled nitric oxide (NOex), NH3ex was not specific to asthma as the children in Group 2 and the controls exhaled more ammonia that did the children in Group 1 (14.3 +/- 10.2 and 14.8 +/- 10.3 vs. 5.6 +/- 4.7 ppb; P < .001, respectively). In the urban environment, all children, including the healthy controls, excreted more ammonia (P < .001) and potassium (P < .001) but less urea (P < .02) than did the children residing in the National Park. These manifestations of moderate metabolic acidosis would favor excretion of ammonia at the expense of urea. In the children residing in the National Park, positive correlations were observed between NH3ex and urinary ammonia, and nitrates, age and morphological parameters. The relationship with the morphological parameters is a reflection of the normal physiological formation of NH3ex. In the children residing in the urban area, the other endogenous source of NH3ex was attributed to a slight disturbance in acid-base balance. In conclusion, the measurement of NH3ex appeared of limited interest, although the higher urinary urea/NH4+ ratio in Group 1 (P < .0001), especially in the treated children, appeared to be linked to the lack of atmospheric pollutants in the National Park. Further experimentation is in progress to confirm these findings.     

Down syndrome maternal serum marker screening after 18 weeks' gestation

Women having access to prenatal care late in pregnancy may still wish to benefit from maternal serum screening for Down syndrome. Therefore, we established reference values for α-feto protein (AFP) and free β-human chorionic gonadotrophin (β-hCG), and assessed the diagnostic value of maternal serum marker screening at 18–35 weeks' gestation based upon a series of 4072 sera from unaffected pregnancies and 118 sera from pregnant women with fetuses affected by Down syndrome. Using a 1/250 risk cut-off, a detection rate of 72.9% (95% CI = 71.5–74.3%) was achieved with a false-positive rate of 7.51% (95% CI = 6.71–8.3%). This was not significantly different from the percentages observed in our 14–17 weeks routine screening (50 596 patients): 71.9% (95% CI = 71.5–72.3%) and 6.48% (95% CI = 6.28–6.68%), respectively. Detection and screen-positive rates were, respectively, 51.3% (95% CI = 35.6–67.0%) and 5.95% (95% CI = 5.12–6.68%) in women aunder 35 years of age, and 84.8% (95% CI = 76.9–92.7%) and 24% (95% CI = 20.7–27.3%) in women aged 35 years and over. In conclusion, maternal serum marker screening is feasible at 18 weeks' gestation and later, which may be of interest in selected cases. Copyright © 2002 John Wiley & Sons, Ltd.     

In vitro biodegradation of Arabian Light 250 by a marine mixed culture using fertilizers as nitrogen and phosphorous sources

The improved in vitro bioremediation of Arabian Light crude oil in synthetic sea water by a mixed culture of bacteria is reported. Effects of fish meal, meat meal 80 % proteins and sophorolipids on the biodegradation were evaluated during a three-week incubation using GC/FID and GC/MS analysis of the remaining oil. Fish meal and more particularly meat meal 80 % proteins used at 0,5 mg.ml⁻¹ involve no nitrogen and phosphorous limits when used as sole source of nutrients. Biodegradation processes in the first four days of the incubation supplemented with sophrolipids are accelerated two fold over controls.     

Exploring simulated driving performance among varsity male soccer players

Background: It is documented that male athletes display riskier behaviors while driving (as well as in life in general) than female athletes and nonathletes. However, the literature has reported that athletes show better driving ability than nonathletes. This paradox between behaviors and abilities motivated the present study to further understand the collision risk of varsity athletes.

Objective: The current study estimates the performance differences between varsity male soccer players and male undergraduate nonathletes on (1) a driving task and (2) three perceptual–cognitive tasks (associated with collision risk prediction; i.e., Useful Field of View [UFOV] test).

Methods: Thirty-five male undergraduate students (15 varsity soccer players, 20 undergraduate nonathletes) took part in this study. Driving performance was assessed during 14?min of urban commuting using a driving simulator. While completing the simulated driving task and UFOV test, the physiological responses were monitored using an electrocardiograph (ECG) to document heart rate variability (HRV).

Results: Varsity soccer players showed more risky behaviors at the wheel compared to their nonathlete student peers. Varsity soccer players spent more time over the speed limit, committed more driving errors, and adopted fewer safe and legal behaviors. However, no difference was observed between both groups on driving skill variables (i.e., vehicle control, vehicle mobility, ecodriving). For subtests 1 and 2 of the UFOV (i.e., processing speed, divided attention), both groups performed identically (i.e., 17?ms). The nonathlete group tended to perform better on the selective attention task (i.e., subtest 3 of UFOV test; 63.2?±?6.2?ms vs. 87.2?±?10.7?ms, respectively; this difference was not significant, P = .76).

Conclusion: Preventive driving measures should be enforced in this high-risk population to develop strategies for risk reduction in male team athletes.     

Vulnerability to the health effects of climate variability in rural southwestern Uganda

Vulnerability to the health impacts of climate change will be shaped by the existing burden of ill- health and is expected to be highest in poor and socio-economically marginalized populations. Sub-Saharan Africa, in particular, is considered a highly vulnerable region. This paper analyses the vulnerability and adaptive capacity of rural Bakiga communities in southwestern Uganda to climate-sensitive health risks. The objectives were threefold: i) identify key climate-sensitive, community-identified health priorities; ii) describe and characterize determinants of sensitivity to these health priorities at the individual, community and regional levels; and iii) assess the adaptive capacity of Bakiga. Data collection employed a combination of individual and key informant interviews, biographies, future storylines, and Photovoice. Three key health risks were identified by the study communities (malaria, food insecurity, and gastrointestinal illnesses) – all affected by local climatic and environmental conditions, livelihoods, land use changes, and socio-economic conditions. Adaptation within these communities is dependent on their capacity to reduce sensitivities to identified health challenges among the potential of increasing exposures. Crop diversification, reducing deforestation, expanding of livestock rearing, transfer of traditional knowledge, and access to affordable health services are among potential strategies identified. We demonstrate significant existing vulnerabilities to present day climate-related health risks and highlight the importance of non-climatic processes and local conditions in creating sensitivity to health risks. Our place-based understanding is useful to inform interventions or policies aimed to reduce exposure and sensitivity and support adaptive capacity as the conditions these communities face are consistent with many other sub-Saharan African countries.     

Decreased emission of nitrous oxide from delivery wards—case study in Sweden

The very potent greenhouse gas nitrous oxide (N₂O) is widely used as a mild anaesthetic for mothers in delivery work in Sweden. As a part of the Stockholm County Council environmental program it was decided in 2002 that the emissions should be drastically reduced. Different ways were theoretically evaluated, and catalytic splitting to nitrogen and oxygen gas (N₂ and O₂) was chosen for a demonstration installation. A Japanese commercial unit for treatment of mixed anaesthetic gases (Anesclean® from Showa Denko K.K.) was thoroughly modified and installed at the Karolinska University Hospital at Huddinge in Stockholm in 2004. The destruction of N₂O was optimised and studied for 2 years. Data from both collection and destruction are given in the article. Of the collected N₂O more than 95% was split to N₂ and O₂ in the very stable system. The overall emission decrease was mainly dependent on the share that could be collected in the specific exhaustion system as compared to the normal room ventilation. Life cycle assessment (LCA) and life cycle costing (LCC) were used to evaluate the actual environmental value and economical cost for the process. Important factors are pointed out.     

<Emphasis Type="Italic">Alexandrium catenella</Emphasis> (Dinophyceae), a toxic ribotype expanding in the NW Mediterranean Sea

The presence of the paralytic shellfish poisoning (PSP) dinoflagellate Alexandrium catenella in the north western (NW) Mediterranean Sea has been known since 1983. From this date on, the species has spread along the Spanish and Italian coastlines. Information concerning A. catenella isolates in the NW Mediterranean Sea was gained through phylogenetic studies. Twenty established toxic cultures of A. catenella taken from various NW Mediterranean Sea locations were analysed by nucleotide sequencing of the 5.8S rDNA and internal transcribed spacer regions. These rDNA ribosomal markers resulted useful in delineating the phylogenetic position of this species in the genus Alexandrium as well as in determining relationships between A. catenella isolates from different geographic areas. The phylogenetic position of the Mediterranean A. catenella ribotype, when compared to the “Alexandrium tamarense/catenella/fundyense species complex”, fits this species complex well. All the Mediterranean A. catenella isolates were constituted by only one genetic ribotype. By comparing the isolate sequences with those of other geographic areas, it revealed that the Mediterranean A. catenella ribotype was closely related to the A. catenella from Japan, Western Pacific Ocean. It was also evident that in temperate Japanese waters, a genetic variability was detected within A. catenella isolates; in fact, all strains resulted divergent showing as many as 15 mutational steps. The possibility that A. catenella has been recently introduced into the Mediterranean basin from temperate Asian areas is discussed.