Recent Changes in Soil Total Phosphorus in the Everglades: Water Conservation Area 3

We assessed recent changes in the distribution of soil total phosphorus (TP) in Water Conservation Area 3 (WCA-3) of the Everglades. Soil cores were collected in 1992 and 2003 at 176 sites. To reflect hydrologic boundaries within the system, WCA-3 was divided into three zones (3AN, 3AS, and 3B). Total P was mapped on both a mass (TPm) and a volumetric basis (TPv) to determine if spatial distributions varied depending on the choice of units. Interpolated maps for both years showed that the highest levels of TPm were located in 3AN and in boundary areas of all zones that received surface water inputs of P from canals. Increases in TPm were greatest in central 3AN in an area adjacent to the Miami Canal that received inputs from a water control structure. Interpolated maps for TPv illustrated that a hotspot present in 1992 had disappeared by 2003. The highest levels of TPv in 2003 were located in northwestern 3AN, a region of WCA-3 that has been chronically overdrained and burned in 1999. From 1992 to 2003, increases in TPm were observed for 53% of the area of WCA-3, while only 16% of WCA-3 exhibited increases in TPv. In 1992, approximately 21% of WCA-3 had TPm concentrations in the 0–10 cm layer >500 mg kg⁻¹, indicating P enrichment beyond historic levels. Eleven years later, 30% of the area of WCA-3 had TPm >500 mg kg⁻¹. This indicated that during this period, the area of WCA-3 with enriched TPm concentrations increased about one % year⁻¹.     

Determination of some heavy metal levels in soft drinks on the Ghanaian market using atomic absorption spectrometry method

Twenty-three soft drink samples (i.e., four pineapple-based fruit drinks, eight citrus-based fruit juices, one soya-based drink, three cola carbonated drinks, one apple-based fruit drink, and six cocktail fruit drinks) were randomly purchased from retail outlets in an urban market in Accra and analyzed for the concentrations of iron, cobalt, cadmium, zinc, lead, and copper using flame atomic absorption spectrometry. The mean concentration of iron and cadmium were 0.723?±?0.448 mg/L and 0.032?±?0.012 mg/L, respectively. The mean cobalt concentration was 0.071?±?0.049 mg/L, while the mean Zn concentration in the samples was 0.060?±?0.097 mg/L. The mean concentrations of Pb and Cu in the fruit juice samples were 0.178?±?0.091 mg/L and 0.053?±?0.063 mg/L respectively. About 78 % of the samples exceeded the United States Environmental Protection Agency (USEPA) maximum contaminant level of 0.3 mg/L prescribed for iron, whereas all the samples exceeded the USEPA maximum contaminant level of 0.005 mg/L prescribed for cadmium. About 91 % of the samples exceeded the EU maximum contaminant level prescribed for lead insoft drinks.     

Motivations underpinning honeybee management practices: A Q methodology study with UK beekeepers

Beekeepers are central to pollinator health. For policymakers and beekeeping organisations to develop widely accepted strategies to sustain honeybee populations alongside wild pollinators, a structured understanding of beekeeper motivations is essential. UK beekeepers are increasing in number, with diverse management styles despite calls for coordinated practice to manage honeybee health. Our Q methodology study in Cornwall, UK, indicated five beekeeping perspectives; conventional hobbyists, natural beekeepers, black bee farmers, new-conventional hobbyists and pragmatic bee farmers. Motivations can be shared across perspectives but trade-offs (notably between economic, social responsibility and ideological motivations) result in differing practices, some of which counter ‘official’ UK advice and may have implications for pollinator health and competition. Honeybee conservation emerged as a key motivator behind non-conventional practices, but wild pollinator conservation was not prioritised by most beekeepers in practice. Q methodology has the potential to facilitate non-hierarchical collaboration and conceptualisation of sustainable beekeeping, moving towards co-production of knowledge to influence policy.Supplementary InformationThe online version contains supplementary material available at 10.1007/s13280-022-01736-w.     

Emissions of Chlorinated Organics from Two Municipal Incinerators in Ontario

In this paper the results of sampling for trace chlorinated organics at two municipal refuse incinerators in Ontario are presented. The information may be of Interest to individuals concerned with the assessment of PCDD/PCDF (polychlorinated dibenzo-p-dioxin/polychlorinated dibenzofuran) emissions from incineration of refuse and their impact on the energyfrom- waste program. PCDDs, PCDFs, PCBs (polychlorinated biphenyls), CBs (chlorobenzenes) and CPs (chlorophenols) were quantified in all process streams including refuse, ash and stack emissions. Manual sorting of refuse and collection of ash samples were carried out simultaneously with three 24-hour continuous stack sampling tests at each plant. The results suggested that the total output of PCDDs and PCDFs varied proportionately with their input at both incinerators. However, the input of PCDDs/PCDFs could not account for their total output. The chemistry of PCDDs/PCDFs in the input and output streams were different in that only heptachlorinated and octachlorinated species were present in significant quantities in the refuse while lower chlorinated species were predominant in stack emissions and ash streams. There was no correspondence between the Input of PCBs/CBs/CPs and the output of PCDDs/PCDFs. The output of PCDDs/PCDFs, however, varied Inversely with the total output of PCBs/CBs/CPs, suggesting that the latter compounds could have been partially responsible for the formation of PCDDs and PCDFs. The PCDF emissions were also affected by combustion conditions; they were higher in magnitude and consisted of predominantly tetrachlorinated and pentachlorinated species at the plant where the combustion temperatures were lower.     

Southwest climate gap: poverty and environmental justice in the US Southwest

This article examines the “climate gap” in the Southwest US (Arizona and New Mexico), referring to the “disproportionate and unequal implications of climate change and climate change mitigation” for “people of color and the poor” [Shonkoff, S.B., et al., 2011. The climate gap: environmental health and equity implications of climate change mitigation policies in California. Climatic Change, 109 (Suppl. 1), S485–S503]. The climate and poverty relationship is examined using multi-scaled analysis across three indicators of climate vulnerability, focusing on connections to health, food, and energy during the period 2010–2012. We provide an overview of climate-related social vulnerability in the Southwest based on available federal, state, and county-level census data. We then summarise the results from a stakeholder workshop and in-depth interviews about climate vulnerabilities with social service providers in southern Arizona. We identify a significant Southwest climate gap based on census data and interview findings about climate vulnerability especially relating to high levels of poverty, health disparities, and increasing costs for energy, water, and food. We find that grassroots and community organisations have mobilised to respond to climate and social vulnerability, yet resources for mitigation and adaptation are insufficient given the high level of need. Confronting a changing climate that is projected to be hotter, drier, and with the potential to reach new thresholds, we suggest that more research needs to be done to understand the social and spatial characteristics of climate risk and how low-income populations embody and experience climate risk, and adapt to a changing climate.     

Dicamba and 2,4-D residues following applicator cleanout: A potential point source to the environment and worker exposure

This paper presents a survey of pesticide residues in tanks following application and throughout the cleanout procedure as conducted by 46 volunteer operators across Colorado. While many pesticides were detected, this paper focuses on dicamba and 2,4-D, which were detected by liquid chromatography/tandem mass spectroscopy (LC-MS/MS). An exponential decrease in concentration was observed with sequential rinses, although this decrease may be more rapid for more water-soluble pesticides. More than 95% of the pesticide in the prerinse solution was removed by the end of the third rinse in all but three operator samples. Concentrations after three rinses were 0.41 ± 0.25 and 3.3 ± 1.1 mg/L for dicamba and 2,4-D, respectively. These concentrations suggest that the recommended practice of three rinses may not be adequate to eliminate off-target effects or point sources of pesticide waste, and that the recommended standard of personal protective equipment is essential to prevent worker exposure to the chemicals.

Implications:?This paper demonstrates that the waste generated during cleanout of pesticide application devices constitutes a potential source of pollution and worker exposure. In particular, while the first rinse of pesticide containers is often treated as hazardous waste and reapplied to crops, the remaining rinses are not. This work demonstrates that the wastewater generated in subsequent rinses can have high enough concentrations to impact worker health, cause off-target effects on crops, and potentially constitute a point source of pesticides. The practical implication is for improved recommendations and regulations regarding pesticide applicators and their cleanout process.     

Can juvenile corals be surveyed effectively using digital photography?: implications for rapid assessment techniques

Seasonal variations in the concentrations of groundwater with respect to arsenic, lead, cadmium and aluminium has been studied in Dhemaji district of Assam, India. The water samples were collected from 20 different sites in both dry and wet seasons. The metals were analysed by using atomic absorption spectrometer, Perkin Elmer AAnalyst 200 model. The concentrations of aluminium, lead and cadmium in groundwater were found to be significantly elevated. High concentrations of all the metals were recorded in the dry season than in the wet season. Univariate statistics along with skewness, kurtosis and confidence limit have been calculated for both the seasons to test the distribution normality for each metal. Statistical analyses of the data reveal non-uniform distribution of the metals in the area. The metal contamination of groundwater in the district follows the trend Al > Pb > Cd > As in both the seasons.     

Soil Organic Carbon (SOC) Equilibrium and Model Initialisation Methods: an Application to the Rothamsted Carbon (RothC) Model

Carbon (C) emissions from anthropogenic land use have accelerated climate change. To reduce C emissions, dynamic models can be used to assess the impact of human drivers on terrestrial C sequestration. Model accuracy requires correct initialisation, since incorrect initialisation can influence the results obtained. Therefore, we sought to improve the initialisation of a process-based SOC model, RothC, which can estimate the effect of climate and land-use change on SOC. The most common initialisation involves running the model until equilibrium (‘spin-up run’), when the SOC pools stabilise (method 1). However, this method does not always produce realistic results. At our experimental sites, the observed SOC was not at equilibrium after 10 years, suggesting that the commonly used spin-up initialisation method assuming equilibrium might be improved. In addition to method 1, we tested two alternative initialisations for RothC that involved adjusting the total or individual SOC pool equilibrium values by regulating the C input during the entire spin-up initialisation period (method 2) and initialising each SOC pool with recently measured SOC values obtained by SOC fractionation (method 3). Analysis of the simulation accuracy for each model initialisation, quantified using the root mean square error (RMSE), indicated that a variant of method 2 that involved adjusting the equilibrium total SOC to observed values (method 2-T) generally showed less variation in the individual SOC pools and total SOC. Furthermore, as total SOC is the sum of all SOC pools, and because total SOC data are more readily available than the individual SOC pool data, we conclude that method 2-T is best for initialising RothC.     

Plant growth rates and seed size: a re-evaluation

Small-seeded plant species are often reported to have high relative growth rate or RGR. However, because RGR declines as plants grow larger, small-seeded species could achieve higher RGR simply by virtue of their small size. In contrast, size-standardized growth rate or SGR factors out these size effects. Differences in SGR can thus only be due to differences in morphology, allocation, or physiology. We used nonlinear regression to calculate SGR for comparison with RGR for 10 groups of species spanning a wide range of life forms. We found that RGR was negatively correlated with seed mass in nearly all groups, but the relationship between SGR and seed mass was highly variable. We conclude that small-seeded species only sometimes possess additional adaptations for rapid growth over and above their general size advantage.