An approach and preliminary model of integrating ecological and economic constraints of environmental quality in the Guayas River estuary, Ecuador

We describe conceptual and simulation models of land use within the intertidal zone of the Guayas River estuary to quantify the contribution of mangrove wetlands to maintaining environmental quality of a tropical estuary. The goal of this exercise is to demonstrate the important consideration of ecological constraints in determining economic and management decisions; and how modeling can be used to quantify impacts of land use such as loss of mangrove wetlands on environmental quality. Our conceptual model treats solar energy, river flow, and tides as forcing functions that control the properties of estuarine ecosystems, but also describes market forces and cultural policies as constraints on properties of socioeconomic systems. The controversy of coastal resource management in Ecuador centers around the relative impacts of shrimp pond construction and management as negative feedbacks to the environmental quality of the Guayas River estuary. Unique oceanographic processes and land use changes contribute to complex issues of water and habitat quality in this tropical estuary, the largest estuarine complex on the Pacific coast of South America. A dynamic box model was developed for the estuary and calibrated with data collected from a 14 month survey of water quality parameters throughout the estuary. Scenarios included conversion of mangroves to shrimp ponds in three regions of the estuary, and the construction of a dam by varying three different rates of river discharge at 100, 50 and 10% of 1989 base flow. Good water quality is maintained by the low residence time of water in the estuary (11 d) because of seasonally high river flow and tidal exchange. With a 90% reduction of mangrove forests in the estuary caused by shrimp pond construction, total nitrogen concentrations increased 5 fold. However, as river discharge decreased to 10%, the same construction caused a 60 fold increase in nitrogen concentrations to 250 μM. Increases in nitrogen concentrations were higher in the upper estuary region, with much less change in the lower estuary. Thus the sensitivity of environmental quality to changes in land use in the intertidal and upland zone are linked to the hydrography of the estuary and is site specific. In the future, the combinations of these ecological models together with economic analyses of the goods and services of mangroves may provide better techniques to evaluate the economic impacts of specific coastal zone management decisions.     

Geological characterization and environmental implications of the placement of the Morelia Dump, Michoacán, Central Mexico

The landfill of Morelia, the capital city of the state of Michoacán in central-western Mexico, is located 12 km west of the city and has operated since 1997 without a structure engineered and designed to control the generation in situ of biogas and leachates. A geological evaluation of the landfill site is presented in this paper. The results indicate that the site lacks ideal impermeable subsurface strata. The subsurface strata consist of highly fractured basaltic lava flows (east-west fault and fracture system trend) and sand-size cineritic material with high permeability and porosity. Geochemical analysis of groundwater from Morelia's municipal aquifer shows a high concentration of heavy metals (Cd, Pb, As) exceeding the Mexican environmental regulations, along with the presence of some organic pollutants (phenols). Analyses of samples of the landfill's permanent leachate ponds show very high concentrations of the same contaminants. Samples were taken from the leachate pond and from nearby water-wells during the rainy season (summer 1997) and the dry season (spring 1997, 1998, and 1999). In all cases, the concentration of contaminants registered exceeded the standards for drinking water of the World Health Organization (American Public Health Association, American Water Works Association, and Water Pollution Control Federation, 2000). Some metal contaminants could be leaching directly from the landfill.     

Nitrate toxicity to aquatic animals: a review with new data for freshwater invertebrates

Published data on nitrate (NO3-) toxicity to freshwater and marine animals are reviewed. New data on nitrate toxicity to the freshwater invertebrates Eulimnogammarus toletanus, Echinogammarus echinosetosus and Hydropsyche exocellata are also presented. The main toxic action of nitrate is due to the conversion of oxygen-carrying pigments to forms that are incapable of carrying oxygen. Nitrate toxicity to aquatic animals increases with increasing nitrate concentrations and exposure times. In contrast, nitrate toxicity may decrease with increasing body size, water salinity, and environmental adaptation. Freshwater animals appear to be more sensitive to nitrate than marine animals. A nitrate concentration of 10 mg NO3-N/l (USA federal maximum level for drinking water) can adversely affect, at least during long-term exposures, freshwater invertebrates (E. toletanus, E. echinosetosus, Cheumatopsyche pettiti, Hydropsyche occidentalis), fishes (Oncorhynchus mykiss, Oncorhynchus tshawytscha, Salmo clarki), and amphibians (Pseudacris triseriata, Rana pipiens, Rana temporaria, Bufo bufo). Safe levels below this nitrate concentration are recommended to protect sensitive freshwater animals from nitrate pollution. Furthermore, a maximum level of 2 mg NO3-N/l would be appropriate for protecting the most sensitive freshwater species. In the case of marine animals, a maximum level of 20 mg NO3-N/l may in general be acceptable. However, early developmental stages of some marine invertebrates, that are well adapted to low nitrate concentrations, may be so susceptible to nitrate as sensitive freshwater invertebrates.     

Contribution of Spanish-American silver mines (1570-1820) to the present high mercury concentrations in the global environment: a review

In this review I evaluate the contribution of Spanish-American silver mines during the period 1570-1820 (a Spanish colonial period of 250 years) to the present high mercury concentrations in the global environment. The evaluation is based upon the following bibliographic information: (1) total amount of mercury consumed in Spanish-American silver mines between 1570 and 1820; (2) percentage of the total amount of mercury consumed in Spanish-American silver mines that may have been emitted to the atmosphere; (3) global natural input of mercury to the atmosphere; (4) worldwide anthropogenic emissions of mercury to the atmosphere; (5) residence time of mercury in the atmosphere; and (6) capacity of mercury to be deposited in the sediments of aquatic systems. From all this information, and owing to the relatively long time that has passed since Spanish-American silver mines were operational, I conclude that most of the mercury lost during the refining of silver via the patio amalgamation process is now sequestered into the sediments of aquatic systems, mainly in marine sediments. The high mercury concentrations now being reported in the global environment essentially are a consequence of the huge pollution caused by human activities during the past 20th century.     

Effects of plant densities and management of purple nutsedge on sugarcane yield and effect of growth stages and main way of herbicides contact and absorption on the control of tubers

Field experiments carried out with Cyperus rotundus L. at low (58-246), medium (318-773), and high (675-1198 shoots/m2) densities showed sugarcane yield reductions of 13.5, 29.3, and 45.2%, respectively in relation to the control. In the second field experiment, the integration of a mechanic method with two sequences of plowing and disking operations in the dry season, and complementary applications of trifloxysulfuron-sodium + ametrine and sulfentrazone (rainy season) was studied. Average of the chain connected to original shoot showed 92, 95, and 65% of reduction with trifloxysulfuron-sodium + ametrine and surfactant, at the application stages "early," preflowering, and full flowering, respectively.     

Precipitation of aragonite by calcitic bivalves in Mg-enriched marine waters

To understand the relative importance of biological versus physicochemical control over biomineralization, we have tested if the chemical composition of the medium (i.e., the Mg/Ca ratio) can change the mineralogy of mollusk shells. The shells of mollusks are made of calcite and/or aragonite, which are by far the most common CaCO₃ polymorphs. Several species of bivalves with predominantly calcitic shells have been cultivated in artificial seawater with a Mg/Ca molar ratio within the range of 8.3–9.2, well above the present value for seawater (5.2). Four out of six species used (the scallop Chlamys varia, the oyster Ostrea edulis, the saddle oyster Anomia ephippium and the mussel Mytilus edulis) survived long enough to secrete significant amounts of calcium carbonate. The deposits (sometimes extensive) formed on the interior shell surfaces were predominantly aragonitic. Three individuals of C. varia also increased their length by adding new shell at the margin. Contrary to the internal shell deposits, these margins were high-Mg calcite. This implies that the marginal mantle is able to exert a more strict control on the secreted mineral phase than the mantle facing the internal shell surface. This is the first report on an in vivo experimentally forced switch in bivalve shell mineralogy, from calcite to aragonite due to a change in water chemistry.     

Understanding the distribution of cattle production systems in the South American Chaco

ABSTRACT

Impacts of cattle production vary among different production systems, but data on their distribution is scarce for most world regions. In this work, we combine datasets on cattle vaccination locations and land cover in a regression framework to define and map major cattle production systems in the Argentinean Dry Chaco. We also explore how cattle occurrence relates to spatial determinants. Results indicate that the region harbors about 5.5 million heads. Cattle density was mainly described by the share of pasture (69.9%), cropland (28.1%) and aridity (23.8%). We identified 12-major cattle production systems: six cow-calf, three whole-cycle, and three fattening systems. Of these, four systems had high woodland cover (>85%). Data generated is available in a website. Understanding the distribution of cattle production systems is important to assess the environmental impacts of beef production at broad scales. Integrating vaccination data with land-cover information provides a promising avenue to identify livestock systems.     

Preparation of jet engine range fuel from biomass pyrolysis oil through hydrogenation and its comparison with aviation kerosene

The Bio-oil was produced from the pyrolysis of agricultural wastes (Eucalyptus sawdust) and discarded soybean frying oil. The temperature of the pyrolysis system was initiated at 28°C and increased to 850°C. Atmospheric distillation of crude bio-oil was performed and a fraction at a temperature range 160–240°C (pyrolysis oil) was separated and subjected to GC-MS, ¹H-NMR, TGA and FTIR analysis to identify the different properties and compounds present in pyrolysis oil. It was noticed that there was an abundance of oxygen and nitrogen containing compounds as well as other reactive species in pyrolysis oil. To reduce the amount of these species, the pyrolysis oil was subjected to hydrogenation in the presence of NiMo as a catalyst. After hydrogenation, the atmospheric distillation of hydrogenated bio-oil was performed and another fraction at temperature range 160–240°C (hydrogenated bio-oil) was separated and analyzed by the same techniques. It was noticed that during hydrogenation, more than 60% oxygenated and other reactive species were converted into hydrocarbons. Hydrogenated bio-oil showed very similar physico-chemical properties such as distillation curve, density, viscosity, freezing point, flash point, the presence of hydrocarbons and enthalpy of combustion as aviation kerosene also known as QAV-1.     

Assessing the extent and nature of wildlife trade on the dark web

Use of the internet as a trade platform has resulted in a shift in the illegal wildlife trade. Increased scrutiny of illegal wildlife trade has led to concerns that online trade of wildlife will move onto the dark web. To provide a baseline of illegal wildlife trade on the dark web, we downloaded and archived 9852 items (individual posts) from the dark web, then searched these based on a list of 121 keywords associated with illegal online wildlife trade, including 30 keywords associated with illegally traded elephant ivory on the surface web. Results were compared with items known to be illegally traded on the dark web, specifically cannabis, cocaine, and heroin, to compare the extent of the trade. Of these 121 keywords, 4 resulted in hits, of which only one was potentially linked to illegal wildlife trade. This sole case was the sale and discussion of Echinopsis pachanoi (San Pedro cactus), which has hallucinogenic properties. This negligible level of activity related to the illegal trade of wildlife on the dark web relative to the open and increasing trade on the surface web may indicate a lack of successful enforcement against illegal wildlife trade on the surface web.