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631.
Christian Brandt Rudi Van Eldik 《Atmospheric environment (Oxford, England : 1994)》1997,31(24):4247-4249
The iron(III)-catalyzed autoxidation of sulfur(IV)-oxides results in the formation of two different oxidation products of sulfur(IV): dithionate, S2O62−, and sulfate, SO42−. The yield of these reaction products depends on the experimental conditions. Under the studied conditions ([Fe(III)] : [SIV)] = 1:10, pH = 2–4) dithionate is the minor reaction product. The formation of dithionate is influenced by the initial pH but not by the initial O2 concentration. The presence of CO2+, Mn2+, and Ni2+ have no influence on the yield of dithionate, whereas in the presence of Cr3+ less and, in the presence of Cu2+, no dithionate is formed. 相似文献
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Alan H. Handyside Abeo McCollin Michael C. Summers Christian S. Ottolini 《黑龙江环境通报》2021,41(5):525-535
Preimplantation genetic testing for aneuploidy (PGT-A) by copy number analysis is now widely used to select euploid embryos for transfer. Whole or partial chromosome aneuploidy can arise in meiosis, predominantly female meiosis, or in the postzygotic, mitotic divisions during cleavage and blastocyst formation, resulting in chromosome mosaicism. Meiotic aneuploidies are almost always lethal, however, the clinical significance of mitotic aneuploidies detected by PGT-A is not fully understood and healthy live births have been reported following transfer of mosaic embryos. Here, we used single nucleotide polymorphism genotyping of both polar bodies and embryo samples to identify meiotic aneuploidies and compared copy number changes for meiotic and presumed mitotic aneuploidies in trophectoderm cells biopsied at the blastocyst stage and arrested embryos. PGT-A detected corresponding full copy number changes (≥70%) for 36/37 (97%) maternal meiotic aneuploidies. The number of presumed mitotic copy number changes detected exceeded those of meiotic origin. Although mainly in the mosaic range, some of these mitotic aneuploidies had copy number changes ≥70% and would have been identified as full aneuploidies. Interestingly, many arrested embryos had multiple mitotic aneuploidies across a broad range of copy number changes, which may have arisen through tripolar spindle and other mitotic abnormalities. 相似文献
633.
Christian A. Chisholm Fotini Vavelidis Mark A. Lovell Lawrence Sweetman Charles R. Roe Diane S. Roe Frank E. Frerman William G. Wilson 《黑龙江环境通报》2001,21(10):856-859
We report the occurrence of multiple acyl-CoA dehydrogenase deficiency (MADD) in two consecutive pregnancies in a young, Caucasian, non-consanguineous couple. In the first pregnancy, the maternal serum α-fetoprotein was elevated. A sonogram showed growth delay, cystic renal disease, and oligohydramnios; the parents decided to terminate the pregnancy. Postmortem examination confirmed the cystic renal disease and showed hepatic steatosis, raising the suspicion of a metabolic disorder. The diagnosis of MADD was made by immunoblot studies on cultured fibroblasts. In the subsequent pregnancy, a sonogram at 15 weeks' gestation showed an early growth delay but normal kidneys. The maternal serum and amniotic fluid concentrations of α-fetoprotein were elevated, and the amniotic fluid acylcarnitine profile was consistent with MADD. In vitro metabolic studies on cultured amniocytes confirmed the diagnosis. A follow-up sonogram showed cystic renal changes. These cases provide additional information regarding the evolution of renal changes in affected fetuses and show a relationship with elevated α-fetoprotein, which may be useful in counseling the couple at risk. MADD should be considered in the differential diagnosis of elevated α-fetoprotein and cystic renal disease. Early growth delay may be an additional feature. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
634.
Tsang‐Jung Chang Ming‐Hsi Hsu Wei‐Hsien Teng Chen‐Jia Huang 《Journal of the American Water Resources Association》2000,36(5):975-988
ABSTRACT: A distributed watershed model combining kinematic wave routing, 1‐D dynamic channel‐flow routing, and 2‐D diffusive overland‐flow routing has been developed to simulate flooding and inundation levels of large watersheds. The study watershed was linked to a GIS database and was divided into an upstream mountainous area and a downstream alluvial plain. A kinematic wave routing was adopted at the mountainous area to compute the discharge flowing into the alluvial plain. A 1‐D dynamic channel routing solving the St. Venant equations by the Preissmann method was performed for the main channel of the alluvial plain, whereas a 2‐D overland‐flow routing solving the diffusion wave equation with the Alternating Direction Explicit scheme was used for floodplains. The above two routings were connected by weir‐link discharge formula. The parameters in the model were calibrated and independently verified by single‐event storms. An example application of flooding/inundation analysis was conducted for the Taichung station and the Woozi depot (Taiwan High Speed Rail). Suggested inundation‐proofing measures ‐ including raising ground surface elevation of the station and depot and building a waterproofing exterior wall and their combination ‐ were investigated. It was concluded that building the waterproofing exterior wall had a strong tendency to decrease peak inundation depth. 相似文献
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Mohammed Rasheed Christian Wild Carin Jantzen Mohammed Badran 《Chemistry and Ecology》2006,22(1):13-20
In situ and laboratory incubation experiments in a fringing reef in the Gulf of Aqaba were performed to study degradation rates of particulate organic matter in reef sediments. Coral mucus, clam eggs, and zooxanthellae were used as model particulate organic compounds for these experiments. Aerobic and anaerobic mineralization rates were calculated by dissolved inorganic carbon (DIC) and O2 fluxes from the sediments under different particulate organic matter additions. Fast enhancement (approximately twofold) of O2 and DIC fluxes were found with the addition of coral mucus and clam eggs compared with control incubations without addition. Most of the degradation is believed to have occurred anaerobically rather than aerobically (DIC:O2 ratios were 4.3-28.1). Higher degradation rates of coral mucus and clam eggs were estimated in carbonate sediment than in silicate sediment (1.2-1.6-fold), which was attributed to the different physical and chemical properties of both sediments. Our study shows the significance of the reef sediment as a suitable site for microbial degradation of particulate organic material excreted from different reef community organisms. This may increase the regeneration of nutrients in the reef environment necessary to sustain high biological productivity. 相似文献
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