Using Instream Water Temperature Forecasts for Fisheries Management: An Application in the Pacific Northwest1

Huang, Biao, Christian Langpap, and Richard M. Adams, 2011. Using Instream Water Temperature Forecasts for Fisheries Management: An Application in the Pacific Northwest. Journal of the American Water Resources Association (JAWRA) 47(4):861‐876. DOI: 10.1111/j.1752‐1688.2011.00562.x Abstract: Water temperature is an important factor affecting aquatic life within the stream environment. Cold water species, such as salmonids, are particularly susceptible to elevated water temperatures. This paper examines the potential usefulness of short‐term (7 to 10 days) water temperature forecasts for salmonid management. Forecasts may be valuable if they allow the water resource manager to make better water allocation decisions. This study considers two applications: water releases from Lewiston Dam for management of adult Chinook salmon (Oncorhynchus tshawytscha) in the Klamath River and leasing water from agriculture for management of steelhead trout (Oncorhynchus mykiss) in the John Day River. We incorporate biophysical models and water temperature distribution data into a Bayesian framework to simulate changes in fish populations and the corresponding opportunity cost of water under different levels of temperature forecast reliability. Simulation results indicate that use of the forecasts results in increased fish production and that marginal costs decline as forecast reliability increases, suggesting that provision and use of such stream temperature forecasts would have potential value to society.     

No evidence for effect of soil compaction on the degradation and impact of isoproturon

Soil is damaged by several threats and, among them, chemical contamination by pesticides and compaction. However, the effect of compaction on the fate of pesticides in soil, and the impact of pesticides on soil biological functioning are unknown. Therefore, we studied the effect of soil compaction on the degradation of the herbicide isoproturon, and the impact of this herbicide on an enzyme activity (β-glucosidase) involved in the C soil cycle. Undisturbed soil samples were prepared at different bulk densities, treated with isoproturon then incubated at 18°C in darkness for 63 days. The results showed that soil compaction did not modify significantly the degradation of isoproturon, neither the formation rates nor the nature of its metabolites. Moreover, compaction did not modify the impact of isoproturon on β-glucosidase activity. To our knowledge, these are the first results concerning the interactions between soil compaction and the degradation and impact of a pesticide.     

One-Pot Reaction of Waste PET to Flame Retardant Polyurethane Foam,via Deep Eutectic Solvents-Based Conversion Technology

Depolymerization of polyethylene terephthalate (PET) is a promising technology for producing recycled monomers. Using a deep eutectic solvent (DES)-based catalyst, the PET glycolysis process produces bis-(2-hydroxyethylene terephthalate) (BHET). This recycled monomer reacts with isocyanate and forms polyurethane foam (PUF). The DES-based one-pot reaction is advantageous because it is a low-energy process that requires relatively lower temperatures and reduced reaction times. In this study, choline chloride/urea, zinc chloride/urea, and zinc acetate/urea based DESs were adopted as DES catalysts for glycolysis. Subsequently, the conversion of PET, BHET yield, and OH values were evaluated. Both filtered and unfiltered reaction mixtures were used as polyols for PUF polymerization after characterization of the acid and hydroxyl values of the polyols, as well as the NCO (–N=C=O) value of isocyanate. In the case of unfiltered reaction mixtures, PUF was obtained via a one-pot reaction, which exhibited higher thermal stability than PUF made from the filtered polyols. This outcome indicated that oligomeric BHET containing many aromatic moieties in unfiltered polyols contributes to the thermal stability of PUF. This environmentally friendly and relatively simple process is an economical approach for upcycling waste PET.

     

Evaluation of uptake of the cytostatic methotrexate in Elliptio complanata mussels by LC–MS/MS

Environmental Science and Pollution Research - Aquatic organisms are continuously exposed to emerging contaminants coming from urban effluents of wastewater treatment plants. The contamination of...     

Is risk analysis a useful tool for improving process safety?

To improve safety one has to know where risks are. For determining risks, hazards have to be identified and representative accident scenarios defined. This needs effort and technique. Man is quite limited in foresight without having experience and lessons from the past. For knowing the risk of an incidental, undesired event both its severity and probability has to be estimated. Then ways to reduce risk become clear. In a process plant risks are many and it is not possible to remove them all. One has to attribute priorities. Intuitive and qualitative methods can do much, but plant complexity may be large and communication on risk may become difficult without formal methodology. Quantitative risk analysis offers much, but has its weaknesses and drawbacks. The required effort is considerable, specialists are needed, and variability in answers is large. Yet, a model built to go along with the life of an installation and updated periodically may be very useful. This paper presents an overview of the demand, problems encountered, possible remedies, and an outlook on useful improvement and extension of risk analysis methodology, including decision making.     

WIND DRIVEN RAIN DISTRIBUTIONS AROUND STREET CANOPIES1

ABSTRACT: Wind driven raindrop tracking is used to investigate the microscale redistribution of wind driven rainfalls in street canopies by combining a Eulerian wind flow model and a Lagrangian raindrop tracking model. The former conducts large eddy simulations of the turbulent flows in street canopies, and the latter performs raindrop trajectory calculations by releasing a large number of raindrops into the computational domain. The wind speed model is verified with available wind tunnel measurement. Twenty sets of simulations are carried out for various building configurations and driving rain angles. The simulated results show that the trajectories of smaller raindrops are more slanting and more influenced by the multibuilding perturbed flow field. Impingement of raindrops on the building envelope increases from bottom to top. The height of the front building is a significant factor affecting wind driven rain redistribution. Distinct nonuniform spatial rainfall distributions are found for scenarios with high building configurations and low driving rain angles. The simulated results are further integrated to assess the effect of real raindrop size distributions by weighing the volumetric fraction of a range of drop sizes. There is about 10 percent variation in spatial extent of street canopies. An overall 5 to 17.4 percent increase of the rainfall amount in the upwind zone is observed.     

A new approach to quantitative assessment of reliability of passive systems

The objective of this paper is to show how probabilistic reliability can be assessed for complex systems in the absence of statistical data on their operating experience, based on performance evaluation of the dominant underlying physical processes. The approach is to distinguish between functional and performance probabilities when dealing with the quantification of the overall probability of a system to perform a given function in a given period of time (reliability). In the case of systems where sufficient statistical operating experience data are available, one can focus the quantitative evaluation entirely on the assessment of the functional probability for a given active item (e.g. a pump) by assuming that the specification, layout, construction and installation is such that the item is providing the assigned performance, e.g. in the form of generating the required flow rate. This is how traditional probabilistic safety assessments (PSAs) focus the reliability analysis for the various safety features on the calculation of values for the availability per demand. In contrast, for various systems relevant in advanced technical applications, such as passive safety features in innovative reactor designs, it is essential to evaluate both functional and performance probabilities explicitly and combine the two probabilities later on. This is of course due to the strong reliance of passive safety systems on inherent physical principles. In practice, this means that, for example, in case of a passive cooling system based on natural circulation of a given medium, one has to evaluate and to assess the probability to have a medium condition and a flow rate such that a cladding temperature, represented by a probability distribution, can be hold at a required level. A practical example of this method is given for the case of the reliability assessment of a residual passive heat removal system. General conclusions are drawn regarding reliability estimation of complex, interconnected systems in the absence of statistical performance data, such as for infrastructures.     

Positive psychology in education for sustainable development at a primary-education institution

The present global environmental crisis is demanding serious rather than superficial changes within the cultural assumptions of human-to-human and human-to-nature relationships. In this sense, education is one of the strongest tools to model our future and a key factor of cultural change. One of the principal aims of Education for Sustainable Development (ESD) is to develop cognitive and affective skills that affect people's values, such as empathy and critical thinking. Together with compromise and responsibility towards a group, it is possible to build new values and ways to interact with both people and the environment. In the present study we used positive psychology principles in creating teaching interventions to empower empathy and critical thinking through an ESD programme at a Chilean primary school. The results show that an intervention of this kind helps to harmoniously build reflective thinking and empathy within students. This enables them to achieve important changes in their disposition to make sound personal and environmental decisions, and prepares them to positively meet imposing present and future challenges.